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Basic information

  • Name:
  • Diantimony trioxide

  • CAS No.:
  • 1309-64-4

  • Molecular Structure:
  • Formula:
  • Sb2O3
  • Molecular Weight:
  • 291.52
  • Deleted CAS:
  • 10042-99-6|12423-58-4|154396-41-5|178989-93-0|212793-41-4|97048-22-1|97048-23-2
  • Synonyms:
  • A 120 (corrosion inhibitor);AN 800;AP 50 (metal oxide);AT 3B;AT 3CN;Antimony Bloom100A;Antimony oxide;Antimonyoxide (SbO1.5);Antimony trioxide;Antimony white;Atox R;Atox S;C.I. 77052;Chemetron Fire Shield;Exitelite;F 45 (oxide);FSPO 405;FireShield H;Fireshield FSPO 405;Flame Cut 610R;Flameguard VF 59;HM 203P;KN (oxide);LS-FR;LSB 80;MSA(flame retardant);Nyacol A 1510LP;Patox A;Patox C;Patox H;Patox K;Patox L;Patox MK;Patox P;Patox S;Performax 401;Polysafe 100T;Pyroguard AN 800;Pyroguard AN 900;RAC 1;SHLB 80;Sanka Anchimonzol C;Stibital;TMS (flameretardant);Thermoguard B;Thermoguard S;Timonox RT;Timonox Red Star;Triox Blanc;Trutin 40;UF;Ultrafine II;White Star N;
  • EINECS:
  • 215-175-0
  • Density:
  • 5.20 g/cm3
  • Melting Point:
  • 656 ºC (subl.)
  • Boiling Point:
  • 1456 ºC
  • Solubility:
  • Slightly soluble in water: <0.1 g/100 mL at 20 ºC
  • Appearance:
  • white powder
  • Hazard Symbols:
  • HarmfulXn,IrritantXi
  • Risk Codes:
  • 40
  • Safety Description:
  • 22-36/37 Details
  • Transport Information:
  • UN 9201

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Chemistry

Molecular Structure:

Molecular Formula: O3Sb2
Molecular Weight: 291.5182
IUPAC Name: Oxo(oxostibanyloxy)stibane
Synonyms of Diantimony trioxide (CAS NO.1309-64-4): DI-Antimony trioxide ; Antimon(iii)oxide ; Antimony trioxide ; Antimony oxide ; Antimonous oxide ; Antimony(+3)oxide ; SB Oxide ; a1530
CAS NO: 873-74-5
Product Categories: Industrial/Fine Chemicals ; Inorganic Chemicals ; Flame retardant ; Flame retardants ; UVCBs-inorganic ; Inorganics ; A-B, Puriss p.a.Metal and Ceramic Science ; Analytical Reagents for General Use ; Puriss p.a. ; 51: Sb ; AntimonyMaterials Science ; AntimonyMetal and Ceramic Science ; Catalysis and Inorganic Chemistry ; Chemical Synthesis ; Nanomaterials ; Nanoparticles: Oxides, Nitrides, and Other CeramicsNanomaterials ; Nanopowders and Nanoparticle Dispersions ; Antimony ; Metal and Ceramic Science ; Oxides
Melting point: 655 °C 
Boiling Point: 1550 °C(lit.)
Density: 5.20
Flash Point: 1550°C subl.
Form: powder
Water Solubility: Slightly soluble. <0.1 g/100 mL at 20 ºC
Merck: 14,711
Stability: Stable.

Uses

  Diantimony trioxide (CAS NO.1309-64-4) is used as flame retardant for textiles, polymers, and coatings. It is also used as opacifying agent for glasses, ceramics and enamels. Besides it  is usde as pigment Diantimony white and  a catalyst in the production of POLYETHYLENE terephthalate.

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
dog LDLo intravenous 3mg/kg (3mg/kg)   "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." Vol. 4, Pg. 1289, 1935.
mammal (species unspecified) LD subcutaneous > 120mg/kg (120mg/kg)   Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 8(7), Pg. 25, 1964.
mouse LD50 intraperitoneal 172mg/kg (172mg/kg)   "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 23, 1982.
rabbit LDLo skin 2gm/kg (2000mg/kg)   National Technical Information Service. Vol. OTS0555447,
rabbit LDLo subcutaneous 2500ug/kg (2.5mg/kg)   "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." Vol. 4, Pg. 1289, 1935.
rat LD50 intraperitoneal 3250mg/kg (3250mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
rat LD50 oral > 34600mg/kg (34600mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

SKIN AND APPENDAGES (SKIN): HAIR: OTHER
National Technical Information Service. Vol. OTS0555447,
rat LD50 subcutaneous 7904mg/kg (7904mg/kg)   Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 38(1), Pg. 99, 1973.

Safety Profile

Hazard Codes of Diantimony trioxide (CAS NO.1309-64-4): HarmfulXn,Xi
Risk Statements: 40 
R40: Limited evidence of a carcinogenic effect.
Safety Statements: 22-36/37 
S22: Do not breathe dust. 
S36/37: Wear suitable protective clothing and gloves.
RIDADR: 1549
WGK Germany: 2
RTECS: CC5650000
Hazard Note: Irritant
HazardClass: 6.1
PackingGroup: III

Specification

 Diantimony trioxide (CAS NO.1309-64-4)  is the most important commercial compound of Diantimony. It is found in nature as the minerals VALENTINITE and senarmontite.

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