Name: GALLIUM(III) CHLORIDE
SKU: 13450-90-3

Products Categories

Pharmaceutical (59)
Others (25)
Organic Chemicals (21)
Reagent (7)
Basic Inorganic Chemicals (7)
Materials (5)
Plant Extract (1)

Basic Information

Molecular Structure:
CAS No.:	13450-90-3
Name:	GALLIUM(III) CHLORIDE
Article Data:	60

Formula:	GaCl₃
Molecular Weight:	176.082
Synonyms:	Gallium(III) chloride;Gallium chloride;Gallium trichloride;NSC 94002;Trichlorogallium;Gallium(3+) chloride;
EINECS:	236-610-0
Density:	2.47 g/mL at 25 °C(lit.)
Melting Point:	78 °C(lit.)
Boiling Point:	35 °C
Flash Point:	-26 °F
Solubility:	Soluble in water
Appearance:	white crystals or powder
Hazard Symbols:	C
Risk Codes:	14-34
Safety:	26-27-28-36/37/39-45
Transport Information:	UN 3260
PSA:	0.00000
LogP:	1.68770

Synthetic route

: 7440-55-3
gallium

: 7782-50-5
chlorine

: 13450-90-3
Gallium trichloride

Conditions

Conditions	Yield
In melt 5 mol% excess of gaseous chlorine passed through metal gallium melt;	99%
excess Cl2;;
mixt. heating (two-section glass tube, 200-250°C); vac. sublimation (water pump, ca. 250°C);

: 13886-65-2
gallium hydrogen dichloride

: 98127-35-6
1,2,4,5-tetrakis((trimethylsilyl)ethynyl)benzene

A: 950696-91-0
C6H2((CHC(Si(CH3)3))2GaCl(O(C2H5)2))2

B: 13450-90-3
Gallium trichloride

Conditions

Conditions	Yield
In hexane under Ar; soln. of HGaCl2 in n-hexane treated with soln. of (Me3SiC2)4C6H2 in n-hexane at room temp.; heated under reflux for 14 h; filtered; ppt. washed with n-hexane; treated with Et2O; filtered; filtrate concd.; cooled to -45°C; elem. anal.;	A 46% B n/a

...Expand

: gallium(III) oxide

: ammonium chloride

: 13450-90-3
Gallium trichloride

Conditions

Conditions	Yield
In neat (no solvent) heating up to 250 °C;;
In neat (no solvent) heating up to 250 °C;;

: gallium(III) oxide

: 7719-09-7
thionyl chloride

: 13450-90-3
Gallium trichloride

Conditions

Conditions	Yield
In neat (no solvent) 200°C;;
In neat (no solvent) 200°C;;

: gallium(III) oxide

: 10026-04-7, 53609-55-5
tetrachlorosilane

A: 13450-90-3
Gallium trichloride

B: 112926-00-8, 7631-86-9
silica gel

Conditions

Conditions	Yield
300-350°C in vac.; Two-fold vacuum sublimation with prior distilling off SiCl4.;

...Expand

: 7440-55-3
gallium

: 7783-90-6
silver(I) chloride

: 13450-90-3
Gallium trichloride

Conditions

Conditions	Yield
In neat (no solvent, solid phase) byproducts: Ag; oven (cf. Grabandt, de Lange, Mooyman, Chem. Phys. Lett. 160 (1989) 359) filled with a mixt. of gallium metal and AgCl, oven temp. between 700 to 900°C, inner ionization chamber kept at low temp.; not isolated, detected by photoelectron spectra;

: gallium arsenide

A: 13450-90-3
Gallium trichloride

B: 7784-34-1
arsenic trichloride

Conditions

Conditions	Yield
With Cl2 Kinetics; GaAs wafer, 25-150°C, pressure from 0.09 to 20 Torr of Cl2;

: 1445-79-0
trimethyl gallium

A: 13450-90-3
Gallium trichloride

B: 6917-81-3
dimethylchlorogallane

C: 6917-74-4
methylgallium dichloride

Conditions

Conditions	Yield
With HCl In neat (no solvent, gas phase)
With HCl In diethyl ether

...Expand

: 7440-55-3
gallium

: 13450-90-3
Gallium trichloride

Conditions

Conditions	Yield
With chlorine In neat (no solvent) Ar atmosphere; chlorination by 120°C; distn. (flow of chloridine), resublimation (flow of Ar);
With Cl2 200-250°C;
With Cl2 chlorination; sublimation;

: 7647-01-0
hydrogenchloride

: 7440-55-3
gallium

: 13450-90-3
Gallium trichloride

Conditions

Conditions	Yield
gentle heating;;
In neat (no solvent) Ga metal was dissolved in concd. HCl;

Raw Materials

Downstream Products

Country:
Business Type:
All

Lab/Research institutions

Trading Company

Manufacturers

Other
Certificate:
Manufacturer

Enterprise Authentication

ISO

GMP

FDA

HALAL

Display:default sort
Suppiers of more reward points first

New supplier

Total:98 Page 1 of 3 1 2 3 Next>>

Post a RFQ

Cas No.:

Product Name:

Quantity:

Email:

Company name:

Valid Period:

Detailed Requirements:

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

What can I do for you?
Get Best Price

Get Best Price for 13450-90-3

Consensus Reports

Reported in EPA TSCA Inventory. EPA Extremely Hazardous Substances List.

Specification

The Gallium trichloride with CAS registry number of 13450-90-3 is also known as Gallium trichloride. The IUPAC name and product name are the same. It belongs to product categories of Inorganics; Crystal Grade Inorganics; Catalysis and Inorganic Chemistry; Chemical Synthesis; Gallium Salts; GalliumMetal and Ceramic Science; Salts. Its EINECS registry number is 236-610-0. In addition, the formula is GaCl₃ and the molecular weight is 176.08. This chemical is a white crystals or powder and should be sealed in a ventilated, cool and dry place at room temperature. What's more, it is used as organic catalyst.

Physical properties about Gallium trichloride are:
(1)Exact Mass: 173.832139; (2)MonoIsotopic Mass: 173.832139; (3)Heavy Atom Count: 4; (4)Complexity: 8; (5)Covalently-Bonded Unit Count: 1;(6)#H bond acceptors: 0; (7)#H bond donors: 0; (8)#Freely Rotating Bonds: 0.

Preparation of Gallium trichloride:
It is prepared by reaction of gallium oxide with thionyl chloride. Firstly, the reaction mixture is heated to 200 °C until gallium oxide is chlorinated completely. Then the reaction mixture is cooled to -10 °C and distilled to remove the excess thionyl chloride. At last, product is refined by distillating at 220 °C.

Safety information of Gallium trichloride:
When you are using this chemical, please be cautious about it. As a chemical, it is extremely flammable and causes burns. It reacts violently with water and it is toxic to aquatic organisms that may cause long-term adverse effects in the aquatic environment. During using it, wear suitable protective clothing, gloves and eye/face protection. Keep away from sources of ignition and avoid release to the environment. After contact with skin, take off immediately all contaminated clothing, and wash immediately. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. If accident happens or you feel unwell seek medical advice immediately. What's more, do not empty into drains and take precautionary measures against static discharges.

You can still convert the following datas into molecular structure:
(1)SMILES:Cl[Ga](Cl)Cl;
(2)Std. InChI:InChI=1S/3ClH.Ga/h3*1H;/q;;;+3/p-3;
(3)Std. InChIKey:UPWPDUACHOATKO-UHFFFAOYSA-K;

The toxicity data of Gallium trichloride is as follows:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Source
dog	LD50	intravenous	41mg/kg (41mg/kg)	Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
mouse	LD50	intraperitoneal	36975ug/kg (36.975mg/kg)	Comptes Rendus Hebdomadaires des Seances, Academie des Sciences. Vol. 256, Pg. 1043, 1963.
rabbit	LD50	intravenous	43mg/kg (43mg/kg)	Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
rabbit	LD50	subcutaneous	245mg/kg (245mg/kg)	Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
rat	LCLo	inhalation	316mg/m³/3H (316mg/m³)	Journal of Pharmacology and Experimental Therapeutics. Vol. 95, Pg. 487, 1949.
rat	LD50	intravenous	47mg/kg (47mg/kg)	Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
rat	LD50	parenteral	1408mg/kg (1408mg/kg)	AJR, American Journal of Roentgenology. Vol. 142, Pg. 619, 1984.
rat	LD50	subcutaneous	306mg/kg (306mg/kg)	Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.