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CAS No.: | 338-83-0 |
---|---|
Name: | Perfluorotripropylamine |
Article Data: | 12 |
Molecular Structure: | |
Formula: | C9F21N |
Molecular Weight: | 521.072 |
Synonyms: | 1-Propanamine,1,1,2,2,3,3,3-heptafluoro-N,N-bis(heptafluoropropyl)- (9CI);Tripropylamine,heneicosafluoro- (6CI,8CI);FTPA;Perfluamine;Perfluorotripropylamine;Tri(perfluoropropyl)amine;Tris(heptafluoropropyl)amine;Tris(perfluoropropyl)amine; |
EINECS: | 206-420-2 |
Density: | 1.741 g/cm3 |
Melting Point: | -52 °C |
Boiling Point: | 130 °C at 760 mmHg |
Flash Point: | 32.4 °C |
Appearance: | colorless, odorless, clear liquid |
Hazard Symbols: | Xi |
Risk Codes: | 36/37/38 |
Safety: | 26-36 |
PSA: | 3.24000 |
LogP: | 6.65960 |
Conditions | Yield |
---|---|
With fluorine; sodium fluoride In 1,1,2-Trichloro-1,2,2-trifluoroethane at 10℃; for 5h; | 72.5% |
With hydrogen fluoride at -4 - 19℃; Product distribution; Electrochemical fluorination. Var. temp., voltage, init conc. of amine, stirring effect investigated.; | |
With cobalt (III) fluoride at 300℃; |
tri-n-propylamine
A
Perfluorotripropylamine
B
N-(F-propyl)-2-(F-ethyl)-F-pyrrolidine
Conditions | Yield |
---|---|
With hydrogen fluoride at 3 - 6℃; for 52h; electrochemical fluorination; | A 20.1% B 2.1% |
perfluoropropylene
di-n-propylamine
A
Perfluorotripropylamine
B
N-(F-propyl)-2-(F-ethyl)-F-pyrrolidine
Conditions | Yield |
---|---|
With hydrogen fluoride 1.) ether, room temperature, overnight, 2.) electrochemical fluorination, 3-6 deg C, 52 h; Yield given. Multistep reaction. Yields of byproduct given; |
A
carbon tetrafluoride
B
freon-218
C
Hexafluoroethane
D
Perfluorotripropylamine
Conditions | Yield |
---|---|
With fluorine at 280 - 390℃; for 0.1h; Fluorination; Title compound not separated from byproducts; | |
With fluorine at 100 - 170℃; for 17h; Product distribution; Further Variations:; Temperatures; time; Fluorination; |
tri-n-propylamine
A
freon-218
B
Perfluorotripropylamine
C
F-(N-F-Fluoro,N,N-di-n-propylamine)
Conditions | Yield |
---|---|
With hydrogen fluoride Product distribution; Further Variations:; current density; Electrochemical reaction; |
Triallylamine
toluene
A
perfluoro-(N-propyl-3,4-dimethylpyrrolidine)
B
Perfluorotripropylamine
C
perfluoro-(N-propyl-3-methylpiperidine)
Conditions | Yield |
---|---|
With hydrogen fluoride Electrochemical reaction; Further byproducts. Title compound not separated from byproducts.; |
Conditions | Yield |
---|---|
In hydrogen fluoride HF (liquid); Electrochem. Process; electrofluorination, 4-8 V, 200 A/m2, Ni anode, Fe cathode; |
Conditions | Yield |
---|---|
pyrolysis at 660-670°C in graphite tube; | 82% |
pyrolysis at 660-670°C; | 73% |
pyrolysis at 660-670°C in presence of AlF3; | >99 |
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Molecular Structure:
Molecular Formula: C9F21N
Molecular Weight: 521.0695
IUPAC Name: 1,1,2,2,3,3,3-Heptafluoro-N,N-bis(1,1,2,2,3,3,3-heptafluoropropyl)propan-1-amine
Synonyms of Perfluamine (CAS NO.338-83-0): Perfluamine [INN:BAN] ; Perfluorotripropylamine ; EINECS 206-420-2 ; HSDB 7102 ; Heptafluoro-N,N-bis(heptafluoropropyl)-1-propanamine ; Perfluamina ; Perfluamina [Spanish] ; Perfluaminum ; Perfluaminum [Latin] ; 1-Propanamine, 1,1,2,2,3,3,3-heptafluoro-N,N-bis(heptafluoropropyl)- ; Heneicosafluorotripropylamine ; Perfluamine
CAS NO: 338-83-0
Index of Refraction: 1.269
Molar Refractivity: 50.59 cm3
Molar Volume: 299.1 cm3
Surface Tension: 13.3 dyne/cm
Density: 1.741 g/cm3
Flash Point: 32.4 °C
Enthalpy of Vaporization: 36.76 kJ/mol
Boiling Point: 130 °C at 760 mmHg
Vapour Pressure: 9.91 mmHg at 25°C
Perfluamine (CAS NO.338-83-0) is used as instruments of anti-corrosion transmission fluid, dielectric insulating fluid, electronic components, liquid leak detection device。
Hazard Codes of Perfluamine (CAS NO.338-83-0): Xi
Risk Statements: 36/37/38
R36/37/38: Irritating to eyes, respiratory system and skin.
Safety Statements: 26-36
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36: Wear suitable protective clothing.
Hazard Note: Irritant
TSCA: T