Reference

A multifunctional metal-organic open framework with a bcu topology constructed from undecanuclear clusters

All Rights Reserved. A multifunctional metal-organic open framework with a bcu topology constructed from undecanuclear clusters. Fang, Qian-Rong; Zhu, Guang-Shan; Jin, Zhao; Xue, Ming; Wei, Xiao; Wang, De-Jun; Qiu, Shi-Lun (State Key Laboratory of Inorganic Synthesis & Preparative Chemistry, Jilin University, Changchun 130012, Peop. Rep. China). Angewandte Chemie, International Edition, 45(37), 6126-6130 (English) 2006 Wiley-VCH Verlag GmbH & Co. KGaA. CODEN: ACIEF5. ISSN: 1433-7851. DOCUMENT TYPE: Journal CA Section: 78 (Inorganic Chemicals and Reactions) Section cross-reference(s): 75, 76 A novel metal-org. 787-70-2 and 64-18-6 are cas registry numbers of chemicals which are used as reagents here. framework (MOF) constructed from cadmium carboxylate cluster secondary building units and formic acid bridging mols. is reported. This highly porous material, [Cd11(m4-HCOO)6(bpdc)9]×9DMF×6H2O (sic, H2bpdc = 4,4'-biphenyldicarboxylic acid), displays rare bcc. topol., as well as good sorption characteristics and optoelectronic properties. .

Two 2-D 36 tessellated metal-organic frameworks constructed from trimetallic clusters and dicarboxylate ditopic links

All Rights Reserved. Two 2-D 36 tessellated metal-organic frameworks constructed from trimetallic clusters and dicarboxylate ditopic links. He, Jianghua; Zhang, Yuetao; Yu, Jihong; Pan, Qinhe; Xu, Ruren (State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, Peop. Rep. China). Materials Research Bulletin, 41(5), 925-933 (English) 2006 Elsevier B.V. CODEN: MRBUAC. ISSN: 0025-5408. DOCUMENT TYPE: Journal CA Section: 78 (Inorganic Chemicals and Reactions) Section cross-reference(s): 73, 75 Two metal-org. framework compds., [Zn3(1,4-BDC)3(Py)2]×2(1,4-dioxane) (MOF-CJ6, 1,4-BDC = 1,4-benzenedicarboxylate) and [Cd3(bpdc)3(H2O)2] (MOF-CJ7, bpdc = 4,4'-biphenyldicarboxylate), were solvothermally synthesized and characterized by single crystal x-ray diffraction, x-ray powder diffraction, ICP, IR and photoluminescence spectroscopy analyses. MOF-CJ6 crystallizes in monoclinic, space group P2(1)/n with a 14.6886(14), b 9. 922730-44-7 and 787-70-2 which are cas registry numbers are also used here.6194(6), c 15.9161(16) ? and b 105.687(6)°. Its framework can be described as a 2-dimensional 36 tessellated net based on the assembly of trimeric Zn3(CO2)6 clusters and 1,4-benzenedicarboxylates ditopic links. The 2-dimensional nets can be further linked into a novel 3-dimensional supramol. hexagonal lattice (hex) network through p-p packing interaction. MOF-CJ7 crystallizes in trigonal, space group R-3 with a 14.1129(8), b 14.1129(8), c 20.1168(13) ? and g 120°. MOF-CJ7 exhibits analogous framework topol. with that of MOF-CJ6, consisting of trimeric Cd3(CO2)6 clusters and 4,4'-biphenyldicarboxylate links. .