51594-59-3

Basic information

• Product Name: 2-Propen-1-one, 1-(4-fluorophenyl)-
• CAS NO: 51594-59-3
• Molecular Formula: C9H7FO
• Molecular Weight: 150.152
• Mol File: 51594-59-3.mol
• Article Data: 32

Chemical Properties

• CAS DataBase Reference: 2-Propen-1-one, 1-(4-fluorophenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propen-1-one, 1-(4-fluorophenyl)-(51594-59-3)
• EPA Substance Registry System: 2-Propen-1-one, 1-(4-fluorophenyl)-(51594-59-3)

Safety Data

• Hazardous Substances Data: 51594-59-3(Hazardous Substances Data)

Upstream product

• 456-03-1 1-(4-fluorophenyl)propan-1-one 
• 403-42-9 1-(4-fluorophenyl)ethanone 
• 67-68-5 dimethyl sulfoxide 
• 5724-03-8 1-(4-fluorophenyl)allyl alcohol 
• 75-11-6 diiodomethane 
• 41024-58-2 1-(4-fluorophenyl)-2-(phenylsulfonyl)-1-ethanone 
• 1474048-85-5 1-(4-fluorophenyl)-3-(phenylselanyl)propan-1-one 
• 403-29-2 2-bromo-4'-fluoroacetophenone 
• 50-00-0 formaldehyd 
• 63072-14-0 1-(4-fluorophenyl)-2-(triphenyl-λ⁵phosphanylidene)ethanone 
• 120302-61-6 Br^(1-)*C₂₆H₂₁FOP⁽¹⁺⁾ 
• 347-93-3 3-chloro-4'-fluoropropiophenone 
• 1826-67-1 vinyl magnesium bromide 
• 459-57-4 4-fluorobenzaldehyde 

Downstream Products

• 132427-78-2 3-((1,4a-dimethyl-7-(1-methylethyl)-1,2,3,4,4a,9,10,10a-octahydro-1-phenanthrenyl)methylamino)-1-(4-fluorophenyl)-1-propanone 
• 123184-01-0 1-(4-fluorophenyl)-1,4-hexanedione 
• 1256284-90-8 1-(4-fluorophenyl)-2-(9-methyl-2,3,4,9-tetrahydro-1H-carbazol-4-yl)ethanone 
• 1339838-72-0 1-(4'-fluorophenyl)-4,4,4-trifluoro-1-butanone 
• 1529771-21-8 4-chloro-4,4-difluoro-1-(4-fluorophenyl)butan-1-one 
• 1529771-31-0 4-bromo-4,4-difluoro-1-(4-fluorophenyl)butan-1-one 
• 1461703-52-5 C₂₇H₁₇F₂NO₂ 
• 1453222-75-7 C₂₅H₂₄FNO₃ 
• 1453222-76-8 C₂₅H₂₄FNO₃ 
• 1451253-19-2 C₂₅H₂₂FNO₃ 
• 123185-39-7 (4R,6R)-6-{2-[2-Cyclohexyl-5-(4-fluoro-phenyl)-pyrrol-1-yl]-ethyl}-4-hydroxy-tetrahydro-pyran-2-one 
• 104568-71-0 methyl 7-<2-(4-fluorophenyl)-5-(1-methylethyl)-1H-pyrrol-1-yl>-5-hydroxy-3-oxoheptanoate 
• 123185-37-5 (4R,6R)-6-{2-[2-(1-Ethyl-propyl)-5-(4-fluoro-phenyl)-pyrrol-1-yl]-ethyl}-4-hydroxy-tetrahydro-pyran-2-one 
• 123185-38-6 (4R,6R)-6-{2-[2-Cyclobutyl-5-(4-fluoro-phenyl)-pyrrol-1-yl]-ethyl}-4-hydroxy-tetrahydro-pyran-2-one 

Relevant articles and documents

Generation of α-Boryl Radicals and Their Conjugate Addition to Enones: Transition-Metal-Free Alkylation of gem-Diborylalkanes

A transition-metal-free method for the alkylation of gem-diborylalkanes with α,β-unsaturated ketones has been developed. It is demonstrated that the α-boryl radicals can be generated efficiently from gem-diborylalkanes with the aid of catechol and oxidants. The α-boryl radicals formed through such process can be engaged in conjugate addition reaction with α,β-unsaturated ketones. This transformation is a straightforward method for the synthesis of γ-borylketones.

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A visible light photoredox-promoted and nitrogen radical catalyzed [3 + 2] cyclization of vinylcyclopropanes and N-tosyl vinylaziridines with alkenes is developed. Key to the success of this process is the use of the readily tunable hydrazone as a nitrogen radical catalyst. Preliminary mechanism studies suggest that the photogenerated nitrogen radical undergoes reversible radical addition to the vinylcyclopropanes and N-tosyl vinylaziridines to enable their ring-opening C-C and C-N bond cleavage and ensuing cyclization with alkenes.

Copper-Catalyzed Asymmetric Hydrosilylation of β-Nitroethyl Aryl Ketones

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