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| CAS No.: | 584-12-3 |
|---|---|
| Name: | 2-Bromofuran |
| Molecular Structure: | |
|
|
|
| Formula: | C4H3BrO |
| Molecular Weight: | 146.971 |
| Synonyms: | alpha-Furyl bromide;2-Furyl bromide;Furan, 2-bromo-; |
| Density: | 1.662 g/cm3 |
| Melting Point: | 116 °C |
| Boiling Point: | 106.6 °C at 760mmHg |
| Flash Point: | 18.3 °C |
| Appearance: | light yellow liquid |
| Hazard Symbols: |
|
| Risk Codes: | 11-36/37/38 |
| Safety: | 3/7-9-16-33-37/39-26 |
| PSA: | 13.14000 |
| LogP: | 2.04210 |
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| Conditions | Yield |
|---|---|
| With bromine; ethyllithium In diethyl ether 1.) 25 deg C, 1 h, 2.) -80 deg C; | 83% |
| With 2,4,4,6-Tetrabromo-2,5-cyclohexadien-1-one for 0.0222222h; microwave irradiation; | 78% |
| With hexabromocyclopenta-1,3-diene In acetonitrile Heating; | 75% |
| Conditions | Yield |
|---|---|
| With copper In quinoline Heating; | 81% |
| With quinoline; copper at 210℃; | 75% |
| With quinoline; copper | |
| With water; mercury dichloride |
| Conditions | Yield |
|---|---|
| With bromine In N,N-dimethyl-formamide at 30 - 35℃; for 1.5h; | A 72% B 8% |
| With N-Bromosuccinimide; p-toluenesulfonic acid monohydrate In benzene |
| Conditions | Yield |
|---|---|
| With bromine In N-methyl-acetamide; (2S)-N-methyl-1-phenylpropan-2-amine hydrate | 23% |
| Conditions | Yield |
|---|---|
| With 1,4-dioxane anschliessend Erhitzen mit wss. Natronlauge und Natriumsulfit; |
| Conditions | Yield |
|---|---|
| With 1,4-dioxane Erhitzen des Reaktionsgemisches mit wss. Natronlauge und Natriumsulfit; |
- 584-12-3
2-bromofuran
| Conditions | Yield |
|---|---|
| With hydrogenchloride |
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Chemistry
The molecular structure of 2-Bromofuran (CAS No. 584-12-3):
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IUPAC Name: 2-Bromofuran
Molecular Formula: C4H3BrO
Molecular Weight: 146.97g/mol
Density: 1.662g/cm3
Boiling Point: 106.6°C at 760mmHg
Flash Point: 18.3°C
Index of Refraction: 1.505
Molar Refractivity: 26.24 cm3
Molar Volume: 88.4 cm3
Polarizability: 10.4×10-24 cm3
Surface Tension: 32.9 dyne/cm
Enthalpy of Vaporization: 33.12 kJ/mol
Vapour Pressure: 32.8 mmHg at 25 °C
XLogP3-AA: 2
H-Bond Acceptor: 1
Exact Mass: 145.936727
MonoIsotopic Mass: 145.936727
Topological Polar Surface Area: 13.1
Heavy Atom Count: 6
Canonical SMILES: C1=COC(=C1)Br
InChI: InChI=1S/C4H3BrO/c5-4-2-1-3-6-4/h1-3H
InChIKey: OYMCMWPHMPODNK-UHFFFAOYSA-N
Product Categories: Furan&Benzofuran; Furans, Benzofurans & Dihydrobenzofurans; Halides
Uses
2-Bromofuran (CAS No. 584-12-3) can be used in organic synthesis.
Safety Profile
Hazard Codes: 
Xi
Risk Statements: 11-36/37/38
R11: Highly flammable.
R36/37/38: Irritating to eyes, respiratory system and skin.
Safety Statements: 3/7-9-16-33-37/39-26
S9: Keep container in a well-ventilated place.
S16: Keep away from sources of ignition.
S33: Take precautionary measures against static discharges.
S37/39: Wear suitable gloves and eye/face protection.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
RIDADR: 1993
Hazard Note: Irritant
Specification
2-Bromofuran (CAS No. 584-12-3) is also named as 2-Furyl bromide ; alpha-Furyl bromide ; Furan, 2-bromo- . 2-Bromofuran (CAS No. 584-12-3) is colorless to light yellow liquid.