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584-12-3

Basic Information
CAS No.: 584-12-3
Name: 2-Bromofuran
Article Data: 22
Cas Database
Molecular Structure:
Molecular Structure of 584-12-3 (2-Bromofuran)
Formula: C4H3BrO
Molecular Weight: 146.971
Synonyms: alpha-Furyl bromide;2-Furyl bromide;Furan, 2-bromo-;
EINECS: N/A
Density: 1.662 g/cm3
Melting Point: 116 °C
Boiling Point: 106.6 °C at 760mmHg
Flash Point: 18.3 °C
Solubility: N/A
Appearance: light yellow liquid
Hazard Symbols:
Risk Codes: 11-36/37/38
Safety: 3/7-9-16-33-37/39-26
Transport Information: N/A
PSA: 13.14000
LogP: 2.04210
Synthetic route
584-12-3

2-bromofuran

Conditions
ConditionsYield
With bromine; ethyllithium In diethyl ether 1.) 25 deg C, 1 h, 2.) -80 deg C;83%
With 2,4,4,6-Tetrabromo-2,5-cyclohexadien-1-one for 0.0222222h; microwave irradiation;78%
With hexabromocyclopenta-1,3-diene In acetonitrile Heating;75%
585-70-6

5-bromo-furan-2-carboxylic acid

584-12-3

2-bromofuran

Conditions
ConditionsYield
With copper In quinoline Heating;81%
With quinoline; copper at 210℃;75%
With quinoline; copper
With water; mercury dichloride

A

584-12-3

2-bromofuran

B

32460-00-7

2,5-dibromofuran

Conditions
ConditionsYield
With bromine In N,N-dimethyl-formamide at 30 - 35℃; for 1.5h;A 72%
B 8%
With N-Bromosuccinimide; p-toluenesulfonic acid monohydrate In benzene
91-66-7

N,N-diethylaniline

584-12-3

2-bromofuran

Conditions
ConditionsYield
With bromine In N-methyl-acetamide; (2S)-N-methyl-1-phenylpropan-2-amine hydrate23%
123-91-1

1,4-dioxane

506-68-3

bromocyane

A

584-12-3

2-bromofuran

B

617-90-3

2-furancarbonitrile

506-68-3

bromocyane

584-12-3

2-bromofuran

Conditions
ConditionsYield
With 1,4-dioxane anschliessend Erhitzen mit wss. Natronlauge und Natriumsulfit;
506-68-3

bromocyane

A

584-12-3

2-bromofuran

B

617-90-3

2-furancarbonitrile

506-68-3

bromocyane

A

584-12-3

2-bromofuran

B

32460-00-7

2,5-dibromofuran

Conditions
ConditionsYield
With 1,4-dioxane Erhitzen des Reaktionsgemisches mit wss. Natronlauge und Natriumsulfit;
5-bromo-<2>furylmercury(1+) chloride

5-bromo-<2>furylmercury(1+) chloride

584-12-3

2-bromofuran

Conditions
ConditionsYield
With hydrogenchloride
585-70-6

5-bromo-furan-2-carboxylic acid

mercury (II)-chloride

mercury (II)-chloride

584-12-3

2-bromofuran

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    584-12-3

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Chemistry

The molecular structure of 2-Bromofuran (CAS No. 584-12-3):

IUPAC Name: 2-Bromofuran
Molecular Formula: C4H3BrO
Molecular Weight: 146.97g/mol
Density: 1.662g/cm3
Boiling Point: 106.6°C at 760mmHg
Flash Point: 18.3°C
Index of Refraction: 1.505
Molar Refractivity: 26.24 cm3
Molar Volume: 88.4 cm3
Polarizability: 10.4×10-24 cm3
Surface Tension: 32.9 dyne/cm 
Enthalpy of Vaporization: 33.12 kJ/mol
Vapour Pressure: 32.8 mmHg at 25 °C
XLogP3-AA: 2
H-Bond Acceptor: 1
Exact Mass: 145.936727
MonoIsotopic Mass: 145.936727
Topological Polar Surface Area: 13.1
Heavy Atom Count: 6 
Canonical SMILES: C1=COC(=C1)Br
InChI: InChI=1S/C4H3BrO/c5-4-2-1-3-6-4/h1-3H
InChIKey: OYMCMWPHMPODNK-UHFFFAOYSA-N
Product Categories: Furan&Benzofuran; Furans, Benzofurans & Dihydrobenzofurans; Halides

Uses

 2-Bromofuran (CAS No. 584-12-3) can be used in organic synthesis.

Safety Profile

Hazard Codes: IrritantXi  
Risk Statements: 11-36/37/38
R11: Highly flammable. 
R36/37/38: Irritating to eyes, respiratory system and skin.
Safety Statements: 3/7-9-16-33-37/39-26
S9: Keep container in a well-ventilated place. 
S16: Keep away from sources of ignition. 
S33: Take precautionary measures against static discharges. 
S37/39: Wear suitable gloves and eye/face protection. 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
RIDADR: 1993
Hazard Note: Irritant

Specification

 2-Bromofuran (CAS No. 584-12-3) is also named as 2-Furyl bromide ; alpha-Furyl bromide ; Furan, 2-bromo- . 2-Bromofuran (CAS No. 584-12-3) is colorless to light yellow liquid.