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Cas Database |
| Name |
2-Furanol, tetrahydro- |
EINECS | N/A |
| CAS No. | 5371-52-8 | Density | 1.148g/cm3 |
| PSA | 29.46000 | LogP | 0.11520 |
| Solubility | N/A | Melting Point |
N/A |
| Formula | C4H8O2 | Boiling Point | 163.6°Cat760mmHg |
| Molecular Weight | 88.1063 | Flash Point | 75.1°C |
| Transport Information | N/A | Appearance | N/A |
| Safety | Risk Codes | N/A | |
| Molecular Structure |
|
Hazard Symbols | N/A |
| Synonyms |
Tetrahydro-2-furanol;oxolan-2-ol;2-Hydroxytetrahydrofuran; |
Article Data | 96 |
2-Furanol, tetrahydro- Synthetic route
| Conditions | Yield |
|---|---|
| HRh(CO)(PPh3)3 In para-xylene | 93% |
| Conditions | Yield |
|---|---|
| With triphenylphosphine; HRh(CO)(PPh3)3 In para-xylene | 93% |
| Conditions | Yield |
|---|---|
| With diisobutylaluminium hydride In toluene at -78℃; for 1h; Reduction; | 79% |
| With diisobutylaluminium hydride In diethyl ether; hexane at -78℃; for 3h; | 64% |
| With diisobutylaluminium hydride In toluene at -78℃; for 3h; | 52% |
| Conditions | Yield |
|---|---|
| With dihydrogen peroxide at 45℃; for 24h; | 76% |
| With hydrogenchloride at 0 - 20℃; | 67% |
| With hydrogenchloride; water at 0℃; for 0.5h; | 61% |
| Conditions | Yield |
|---|---|
| With hydrogen; montmorillonite-diphenylphosphinepalladium(II) under 760 Torr; for 30h; Ambient temperature; | A 72% B n/a |
| Conditions | Yield |
|---|---|
| With C36H40Cu2N6O2(2+) In acetone at -70℃; | 62% |
| With tert.-butylhydroperoxide; copper(l) chloride | |
| With 3,3-dimethyldioxirane In acetone at 25℃; Kinetics; | 96 % Chromat. |
| With [{Cu(II)(Me2NMePY2)}2(O2)](B(C6H5)4)2 In dichloromethane at -80℃; Product distribution; Kinetics; Further Variations:; Reagents; other substrates; |
| Conditions | Yield |
|---|---|
| With hydrogen In 1,4-dioxane; water at 139.84℃; under 60006 Torr; for 4h; | A 5% B 52% |
- 109-99-9
tetrahydrofuran
- 4676-82-8
2-hydroperoxytetrahydrofuran
- 107-13-1
acrylonitrile
A
- 5371-52-8
2-hydroxytetrahydrofuran
B
- 16237-62-0
2-(β-cyanoethyl)tetrahydrofuran
| Conditions | Yield |
|---|---|
| at 130℃; for 4h; Product distribution; Mechanism; He-atmosphere, other temperatures, times and initiators; | A n/a B 49% C n/a D n/a E n/a |
- 1191-99-7
2,3-dihydro-2H-furan
A
- 5371-52-8
2-hydroxytetrahydrofuran
B
- 453-20-3
3-Hydroxytetrahydrofuran
C
- 71780-57-9
tetrahydrofuran-2'-yl ether
| Conditions | Yield |
|---|---|
| With water; hydrogen In 1,4-dioxane at 139.84℃; under 60006 Torr; for 4h; | A 18% B 8% C 46% |
| With water; hydrogen; pyrographite In 1,4-dioxane at 139.84℃; under 60006 Torr; for 4h; | A 18% B 8% C 46% |
| Conditions | Yield |
|---|---|
| With cobalt(III) acetylacetonate; oxygen In ethyl acetate at 70℃; for 24h; Product distribution; various cyclic ethers; | A 9% B 30% |
| With tert.-butylhydroperoxide; water; copper(II) bis(trifluoromethanesulfonate) at 90℃; for 20h; Inert atmosphere; | A 21% B 7% |
| With dihydrogen peroxide In water at 66℃; for 4h; Temperature; Green chemistry; | A 6.85% B 16.65% |
2-Furanol, tetrahydro- Chemical Properties
IUPAC Name: Oxolan-2-ol
Synonyms of 2-Furanol, tetrahydro- (CAS NO.5371-52-8): Tetrahydro-2-furanol
CAS NO: 5371-52-8
Molecular Formula of 2-Furanol, tetrahydro- (CAS NO.5371-52-8): C4H8O2
Molecular Weight: 88.1051
Molecular Structure:
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ProductCategories: Miscellaneous Reagents
Polar Surface Area: 18.46 Å2
Index of Refraction: 1.475
Molar Refractivity: 21.64 cm3
Molar Volume: 76.7 cm3
Surface Tension: 38.7 dyne/cm
Density of 2-Furanol, tetrahydro- (CAS NO.5371-52-8): 1.148 g/cm3
Flash Point: 75.1 °C
Enthalpy of Vaporization: 46.6 kJ/mol
Boiling Point: 163.6 °C at 760 mmHg
Vapour Pressure: 0.697 mmHg at 25°C
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