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| CAS No.: | 107-83-5 |
|---|---|
| Name: | 2-Methylpentane |
| Molecular Structure: | |
|
|
|
| Formula: | C6H14 |
| Molecular Weight: | 86.1772 |
| Synonyms: | 1,1-Dimethylbutane;Kyowasol C 600M;Kyowazol C 600;NSC 66496;Pentane, 2-methyl-; |
| EINECS: | 203-523-4 |
| Density: | 0.673 g/cm3 |
| Melting Point: | -154 °C |
| Boiling Point: | 59.6 °C at 760 mmHg |
| Flash Point: | ?10°F |
| Solubility: | Miscible with alcohol, ether, acetone and chloroform. Immiscible with water. |
| Appearance: | colourless liquid |
| Hazard Symbols: |
 F,  Xn,  N
|
| Risk Codes: | 11-38-51/53-65-67 |
| Safety: | 9-16-29-33-61-62 |
| Transport Information: | UN 1208 3/PG 2 |
| PSA: | 0.00000 |
| LogP: | 2.44250 |
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| Conditions | Yield |
|---|---|
| With hydrogen; K-10 montmorillonite; platinum In diethylene glycol dimethyl ether under 37503 Torr; for 16h; Reduction; | 98% |
| Multi-step reaction with 2 steps 1: diethyl ether; sodium; water 2: amyl alcohol; HI / 0 °C / man fuegt dann Eisessig und Zink hinzu View Scheme | |
| With hydrogen at 100℃; for 4h; |
| Conditions | Yield |
|---|---|
| With hydrogen; osmium(VIII) oxide at 100℃; under 37503 Torr; for 15h; or 100 to 180 deg C, different Os-catalysts and -concentrations; | A 37 % Turnov. B 63 % Turnov. |
| With hydrogen at 220℃; | |
| With 1.0%Pt-1.0%Ir/TiO2; hydrogen at 250℃; under 760.051 Torr; for 2h; Reagent/catalyst; | |
| With hydrogen at 300 - 350℃; under 22502.3 Torr; for 6h; Autoclave; | |
| With monometallic Ir/SiO2 at 280℃; under 15001.5 Torr; Reagent/catalyst; |
| Conditions | Yield |
|---|---|
| With 10 % platinum on carbon; hydrogen at 300℃; for 4h; | |
| With hydrogen at 100℃; for 1h; | |
| With 10 wt% platinum on carbon; hydrogen at 300℃; under 760.051 Torr; Gas phase; |
| Conditions | Yield |
|---|---|
| With hydrogen at 319.84℃; under 15001.5 Torr; for 2h; Temperature; Reagent/catalyst; | 76% |
| dealuminated Zeolite Y at 350℃; Product distribution; var. temp., mode of dealumination; influence of Si/Al ratios discussed; | |
| With SO4-ZrO2 at 199.84℃; Kinetics; Reagent/catalyst; Pressure; | |
| With Pt/SO42-/ZrO2 PSZ at 165℃; under 15001.5 Torr; for 3h; Flow reactor; | |
| With hydrogen at 26.84℃; under 15001.5 Torr; for 4h; Catalytic behavior; Reagent/catalyst; Pressure; Temperature; |
A
- 110-54-3
hexane
B
- 96-14-0
3-methylpentane
C
- 107-83-5
2-Methylpentane
D
- 591-78-6
n-hexan-2-one
E
- 589-38-8
n-hexan-3-one
F
- 124-38-9
carbon dioxide
| Conditions | Yield |
|---|---|
| With prereduced 3 wtpercent Pt modified Ir-ReOx supported on silica In decane; water at 189.84℃; under 3750.38 Torr; for 24h; Inert atmosphere; Autoclave; |
| Conditions | Yield |
|---|---|
| With sodium tetrahydroborate; [RuII(Cl)(4-isopropyltoluene)(μ-bpp)CoII(2,6-pyridinedicarboxylate)(H2O)] In methanol; ethanol Catalytic behavior; Inert atmosphere; | 9.8% |
| With hydrogen; palladium sulfide at 80℃; Kinetics; Rate constant; vapor phase reaction, atmospheric pressure, other temperatures, isomerization contribution, activation energy, other methylpentenes and 1-alkenes; benzene, toluene, xylene presence; | |
| With n-butyllithium; hydrogen; 2TiCl2 for 3h; Rate constant; with various titanium complexes, at various times; |
- 110-54-3
hexane
A
- 96-14-0
3-methylpentane
B
- 107-83-5
2-Methylpentane
C
- 75-83-2
2,2-Dimethylbutane
D
- 79-29-8
2,3-dimethylbutane
| Conditions | Yield |
|---|---|
| platinum at 250℃; Product distribution; Further Variations:; Catalysts; Temperatures; | A 22.1% B 34.8% C 12.9% D 9% |
| With hydrogen at 215℃; under 7500.75 Torr; Catalytic behavior; Kinetics; Reagent/catalyst; Temperature; Flow reactor; Overall yield = 62.1 %; | A n/a B n/a C 6.7% D 8% |
| Pt-Al2O3-Cl at 100 - 140℃; under 15001.2 Torr; Product distribution; |
| Conditions | Yield |
|---|---|
| Multi-step reaction with 2 steps 1: palladium 10% on activated carbon; hydrogen / 200 °C / 760.05 Torr / Gas phase 2: hydrogen; silica gel / 200 °C / 760.05 Torr / Gas phase View Scheme | |
| Multi-step reaction with 2 steps 1: ; hydrogen / 200 °C / 760.05 Torr / Gas phase 2: hydrogen; silica gel / 200 °C / 760.05 Torr / Gas phase View Scheme | |
| With hydrogen; silica gel at 200℃; under 760.051 Torr; Gas phase; |
| Conditions | Yield |
|---|---|
| With hydrogen; 5% platinum on alumina In water Product distribution; hydrogenolysis; either thermal heating or microwave irradiation; | |
| With hydrogen; rhenium catalyst at 149.9℃; Product distribution; effect of different catalysts, with different pretreatment, at different temp.; | |
| With hydrogen; platinum at 350℃; under 5 Torr; Mechanism; var. C6 saturated hydrocarbons, 13C-labelled also; var. catalysts; |
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Chemistry
The basic informtion about 2-Methylpentane (107-83-5) is:
IUPAC Name: 2-methylpentane
Synonyms: (ch3)2ch(ch2)2ch3 ; 1,1-dimethylbutane ; 2-methyl-pentan ; pentane , 2-methyl- ; 2-methylpentane ; methylpentane ; isohexane ; 2-methylpentane(iso-hexane)
MF: C6H14
MW: 86.18
EINECS: 203-523-4
Melting Point: -154 °C
Boiling Point: 62 °C(lit.)
Density: 0.66
Vapor Densit: 3 (vs air)
Vapor Pressure: 6.77 psi ( 37.7 °C)
Refractive Index: n20/D 1.371(lit.)
Flash Point: −10 °F
BRN: 1730735
Stability: Stable. Highly flammable. Gas/vapour mixtures explosive at some concentrations.
Following is the molecular structure of 2-Methylpentane (107-83-5) :
Uses
2-Methylpentane (107-83-5) can be used as chemical raw materials, rubber solvents, vegetable oil extraction solvent and so on.
Toxicity Data With Reference
Low toxicity.
Safety Profile
Hazard Codes:
F: Flammable.gif){kind=small}
Xn: Harmful.gif){kind=small}
N: Dangerous for the environment
Risk Statements:
R11: Highly flammable.
R38: Irritating to skin.
R51/53: Toxic to aquatic organisms and may cause long-term adverse effects in the aquatic environment.
R65: Harmful: may cause lung damage if swallowed.
R67: Vapours may cause drowsiness and dizziness.
Safety Statements:
S9: Keep container in a well-ventilated place.
S16: Keep away from sources of ignition.
S29: Do not empty into drains.
S33: Take precautionary measures against static discharges.
S61: Avoid release to the environment. Refer to special instructions / safety data sheets.
S62: If swallowed, do not induce vomitting; seek medical advice immediately and show this container or label.
RIDADR: UN 1208 3/PG 2
WGK Germany: 2
RTECS: SA2985000
HazardClass: 3
PackingGroup: II
Specification
2-Methylpentane (107-83-5) is a colourless liquid;Its general description watery liquid with a gasoline-like odor, floats on water. Produces an irritating vapor. In Air & Water its reactions highly flammable. Reactivity profile saturated aliphatic hydrocarbons, such as Isohexene , may be incompatible with strong oxidizing agents like nitric acid. Charring of the hydrocarbon may occur followed by ignition of unreacted hydrocarbon and other nearby combustibles. In other settings, aliphatic saturated hydrocarbons are mostly unreactive. They are not affected by aqueous solutions of acids, alkalis, most oxidizing agents, and most reducing agents. Health Hazard Inhalation causes irritation of respiratory tract, cough, mild depression, cardiac arrhythmias. Aspiration causes severe lung irritation, coughing, pulmonary edema; excitement followed by depression. Ingestion causes nausea, vomiting, swelling of abdomen, headache, depression.