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Cas Database |
| Name |
2-Piperidinemethanol |
EINECS | 222-333-2 |
| CAS No. | 3433-37-2 | Density | 0.951 g/cm3 |
| PSA | 32.26000 | LogP | 0.44960 |
| Solubility | Slightly soluble in water. | Melting Point |
68-70 °C(lit.) |
| Formula | C6H13NO | Boiling Point | 221.2 °C at 760 mmHg |
| Molecular Weight | 115.175 | Flash Point | 90.9 °C |
| Transport Information | N/A | Appearance | White to slightly brown solid |
| Safety | 26-36 | Risk Codes | 36/37/38 |
| Molecular Structure |
|
Hazard Symbols |
 Xi
|
| Synonyms |
2-Hydroxymethylpiperidine; |
Article Data | 25 |
2-Piperidinemethanol Synthetic route
- 127274-92-4
ethyl 6-oxopiperidine-2-carboxylate
- 3433-37-2
piperidin-2-ylmethanol
| Conditions | Yield |
|---|---|
| With lithium aluminium tetrahydride | 88% |
| Conditions | Yield |
|---|---|
| With ethanol; sodium | |
| With ethanol; nickel at 50℃; under 110326 - 147102 Torr; Hydrogenation; |
- 15862-72-3
ethyl pipecolate
- 3433-37-2
piperidin-2-ylmethanol
| Conditions | Yield |
|---|---|
| With lithium aluminium tetrahydride; diethyl ether |
- 94685-29-7
N-benzoyl-2-<(benzoyloxy)methyl>piperidine
A
- 92041-11-7
N-benzoyl-2-(hydroxymethyl)piperidine
B
- 3433-37-2
piperidin-2-ylmethanol
| Conditions | Yield |
|---|---|
| With lithium hydroxide In tetrahydrofuran; methanol other N,O-diacylated compounds, other reagents; |
| Conditions | Yield |
|---|---|
| With borane In tetrahydrofuran Ambient temperature; | |
| With lithium aluminium tetrahydride |
| Conditions | Yield |
|---|---|
| With hydrogenchloride; hydrogen; platinum(IV) oxide In ethanol under 41253.3 Torr; for 16h; | 100 % Spectr. |
- 35677-83-9, 41994-45-0, 43041-11-8, 90710-04-6
methyl pipecolinate
- 3433-37-2
piperidin-2-ylmethanol
| Conditions | Yield |
|---|---|
| With sodium tetrahydroborate; sodium hydrogencarbonate |
- 157634-00-9
tert-butyl 2-(hydroxymethyl)piperidine-1-carboxylate
- 3433-37-2
piperidin-2-ylmethanol
| Conditions | Yield |
|---|---|
| With hydrogenchloride In 1,4-dioxane; water at 0 - 20℃; for 2h; |
- 70-53-1
2,6-diaminohexanoic acid hydrochloride
A
- 110-89-4
piperidine
B
- 109-05-7, 3000-79-1
2-Methylpiperidin
C
- 3433-37-2
piperidin-2-ylmethanol
| Conditions | Yield |
|---|---|
| Multi-step reaction with 2 steps 1.1: sulfuric acid / water / 20 - 30 °C 1.2: 120 °C / 36228.6 Torr / Autoclave; Sealed tube 2.1: 5% active carbon-supported ruthenium / water / 7 h / 150 °C / 67506.8 Torr / pH 3.1 View Scheme |
- 25441-01-4
2,6-diamino-1-hexanol
A
- 110-89-4
piperidine
B
- 109-05-7, 3000-79-1
2-Methylpiperidin
C
- 3433-37-2
piperidin-2-ylmethanol
| Conditions | Yield |
|---|---|
| With 5% active carbon-supported ruthenium In water at 150℃; under 67506.8 Torr; for 7h; pH=3.1; |
2-Piperidinemethanol Chemical Properties
Molecular Structure of 2-(Hydroxymethyl)piperidine (CAS NO.3433-37-2):
.jpg)
IUPAC Name: Piperidin-2-ylmethanol
Canonical SMILES: C1CCNC(C1)CO
InChI: InChI=1S/C6H13NO/c8-5-6-3-1-2-4-7-6/h6-8H,1-5H2
InChIKey: PRAYXGYYVXRDDW-UHFFFAOYSA-N
Molecular Weight: 115.17352 [g/mol]
Molecular Formula: C6H13NO
XLogP3-AA: 0
H-Bond Donor: 2
H-Bond Acceptor: 2
EINECS: 222-333-2
Appearance: White to slightly brown solid
Melting Point: 68-70 °C(lit.)
Index of Refraction: 1.451
Molar Refractivity: 32.63 cm3
Molar Volume: 121 cm3
Surface Tension: 34.8 dyne/cm
Density: 0.951 g/cm3
Flash Point: 90.9 °C
Enthalpy of Vaporization: 53.21 kJ/mol
Boiling Point: 221.2 °C at 760 mmHg
Vapour Pressure: 0.0225 mmHg at 25 °C
Product Categories: Piperidine;Alkohols;Heterocyclic Compounds
2-Piperidinemethanol Safety Profile
Safety Information of 2-(Hydroxymethyl)piperidine (CAS NO.3433-37-2):
Hazard Codes: 
Xi
Risk Statements: 36/37/38
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 26-36
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36:Wear suitable protective clothing.
WGK Germany: 3
2-Piperidinemethanol Specification
2-(Hydroxymethyl)piperidine (CAS NO.3433-37-2), its Synonyms are 2-Hydroxymethylpiperidine ; 2-Piperidinylmethanol ; Piperidin-2-ylmethanol .
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