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4-Chlorophenylhydrazine

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Name

4-Chlorophenylhydrazine

EINECS 214-029-3
CAS No. 1073-69-4 Density 1.32g/cm3
PSA 38.05000 LogP 2.39890
Solubility N/A Melting Point 85 °C
Formula C6H7ClN2 Boiling Point 265.3 °C at 760 mmHg
Molecular Weight 142.588 Flash Point 114.2 °C
Transport Information N/A Appearance white or off-white power
Safety Risk Codes R36/37/38
Molecular Structure Molecular Structure of 1073-69-4 (4-Chlorophenylhydrazine) Hazard Symbols Xi
Synonyms

Hydrazine,(p-chlorophenyl)- (6CI,7CI,8CI);(4-Chlorophenyl)hydrazine;(p-Chlorophenyl)hydrazine;1-(4-Chlorophenyl)hydrazine;4-Chlorophenylhydrazine;N-(4-Chlorophenyl)hydrazine;p-Chlorophenyl hydrazine;

Article Data 49

4-Chlorophenylhydrazine Synthetic route

106-47-8

4-chloro-aniline

1073-69-4

N-4-chlorophenylhydrazine

Conditions
ConditionsYield
With hydrazine hydro-chloride In ethylene glycol at 110℃; for 5h; Temperature; Reflux;92%
Stage #1: 4-chloro-aniline With hydrogenchloride; sodium nitrite In water for 2h;
Stage #2: With hydrogenchloride; sodium sulfite In water at 0 - 100℃; for 4h;
70.67%
Stage #1: 4-chloro-aniline With hydrogenchloride; acetic acid; sodium nitrite In water at 0 - 20℃;
Stage #2: With hydrogenchloride; tin(II) dichloride dihydrate In water
60%
106-47-8

4-chloro-aniline

71-36-3

butan-1-ol

1073-69-4

N-4-chlorophenylhydrazine

Conditions
ConditionsYield
With hydrogenchloride; sodium hydroxide; sodium hydrogen sulfate; sodium nitrite78%
673-41-6

p-chlorobenzenediazonium tetrafluoroborate

1073-69-4

N-4-chlorophenylhydrazine

Conditions
ConditionsYield
With borohydride exchange resin In methanol at 0℃;63%
With sodium perchlorate In water at 4℃; for 2h; electrolysis, pH=2.2;60%
113546-44-4

N-chloro-N'-phenyl-urea

furan-2,3,5(4H)-trione pyridine (1:1)

A

64-10-8

phenyl carbamate

B

108-90-7

chlorobenzene

C

1073-69-4

N-4-chlorophenylhydrazine

D

140-38-5

N-(4-chlorophenyl)urea

2028-74-2

p-chlorobenzenediazonium chloride

1073-69-4

N-4-chlorophenylhydrazine

Conditions
ConditionsYield
With sodium sulfite nachf. Erhitzen mit Salzsaeure;
at 70℃; Zufuegen von Zinkstaub, Eisessig und konz. Salzsaeure;
With tin(ll) chloride

[N'-(4-chloro-phenyl)-hydrazino]-triphenyl-phosphonium; chloride

1073-69-4

N-4-chlorophenylhydrazine

Conditions
ConditionsYield
With hydrogenchloride
7647-01-0

hydrogenchloride

6947-29-1

N’-(4-chlorophenyl)acetohydrazide

1073-69-4

N-4-chlorophenylhydrazine

potassium-4-chloro-benzene isodiazotate-(1)

potassium-4-chloro-benzene isodiazotate-(1)

1073-69-4

N-4-chlorophenylhydrazine

Conditions
ConditionsYield
With sodium hydroxide; sodium amalgam
sodium-<4-chloro-benzene-trans-diazoate>

sodium-<4-chloro-benzene-trans-diazoate>

1073-69-4

N-4-chlorophenylhydrazine

Conditions
ConditionsYield
With water Electrolysis;
51317-82-9

methyl 2-(4-chlorophenyl)hydrazinecarboxylate

A

67-56-1

methanol

B

1073-69-4

N-4-chlorophenylhydrazine

C

CO2

CO2

Conditions
ConditionsYield
With sodium hydroxide In 1,4-dioxane at 25℃; Rate constant;

4-Chlorophenylhydrazine Specification

The 4-Chlorophenylhydrazine is an organic compound with the formula C6H7ClN2. The IUPAC name of this chemical is (4-chlorophenyl)hydrazine. With the CAS registry number 1073-69-4, it is also named as Hydrazine, (4-chlorophenyl)-.

Physical properties about 4-Chlorophenylhydrazine are: (1)ACD/LogP: 2.24; (2)ACD/LogD (pH 5.5): 2.12; (3)ACD/LogD (pH 7.4): 2.24; (4)ACD/BCF (pH 5.5): 22.31; (5)ACD/BCF (pH 7.4): 29.56; (6)ACD/KOC (pH 5.5): 296.2; (7)ACD/KOC (pH 7.4): 392.46; (8)#H bond acceptors: 2; (9)#H bond donors: 3; (10)#Freely Rotating Bonds: 2; (11)Polar Surface Area: 6.48 Å2; (12)Index of Refraction: 1.655; (13)Molar Refractivity: 39.65 cm3; (14)Molar Volume: 108 cm3; (15)Polarizability: 15.72×10-24cm3; (16)Surface Tension: 52.8 dyne/cm; (17)Density: 1.32 g/cm3; (18)Flash Point: 114.2 °C; (19)Enthalpy of Vaporization: 50.32 kJ/mol; (20)Boiling Point: 265.3 °C at 760 mmHg; (21)Vapour Pressure: 0.00926 mmHg at 25°C.

Preparation: this chemical can be prepared by -chloro-benzenediazonium; tetrafluoroborate. This reaction will need reagent borohydride exchange resin and solvent methanol. The reaction temperature is 0 °C. The yield is about 63%.



Uses of 4-Chlorophenylhydrazine: it can be used to produce 3-(4-chloro-phenyl)-carbazic acid ethyl ester. It will need reagent pyridine and water .

You can still convert the following datas into molecular structure:
(1)SMILES: Clc1ccc(NN)cc1
(2)InChI: InChI=1/C6H7ClN2/c7-5-1-3-6(9-8)4-2-5/h1-4,9H,8H2
(3)InChIKey: XXNOGQJZAOXWAQ-UHFFFAOYAL
(4)Std. InChI: InChI=1S/C6H7ClN2/c7-5-1-3-6(9-8)4-2-5/h1-4,9H,8H2
(5)Std. InChIKey: XXNOGQJZAOXWAQ-UHFFFAOYSA-N

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