Products Categories
| CAS No.: | 102-50-1 |
|---|---|
| Name: | 2-Methyl-4-methoxybenzenamine |
| Molecular Structure: | |
|
|
|
| Formula: | C8H11NO |
| Molecular Weight: | 137.181 |
| Synonyms: | p-Anisidine,2-methyl- (7CI,8CI);2-Amino-5-methoxytoluene;2-Methyl-4-(methyloxy)aniline;2-Methyl-4-anisidine;2-Methyl-4-methoxyaniline;2-Methyl-4-methoxybenzenamine;2-Methyl-p-anisidine;4-Methoxy-2-methylaniline;4-Methoxy-2-methylbenzenamine;4-Methoxy-o-toluidine;NSC 66563;[2-Methyl-4-(methyloxy)phenyl]amine; |
| EINECS: | 203-036-7 |
| Density: | 1.065 g/cm3 |
| Melting Point: | 13-14 °C(lit.) |
| Boiling Point: | 249.4 °C at 760 mmHg |
| Flash Point: | 113.5 °C |
| Solubility: | insoluble, |
| Appearance: | brick red crystals or liquid |
| Hazard Symbols: |
 Xi, Xn, T
|
| Risk Codes: | 36/37/38-40-45 |
| Safety: | 26-36/37/39-53-45 |
| PSA: | 35.25000 |
| LogP: | 2.16700 |
- 144851-82-1METHYL2-AMINO-3-FLUOROBENZOATE
- 483366-12-7(2S,4R)-1-Boc-2-cyano-4-hydroxypyrrolidine
- 173606-50-3BOC-10-AMINODECANOIC ACID
- 361456-36-2METHYL (R)-(+)-ISOCYANATO-3-PHENYLPROPI&
- 5156-58-1N-(1-Benzyl-4-pipperidinyl)-N-phenylpropanamide HCl
- 81281-59-67-Benzylideneaminotheophylline
- 50288-62-5threo-Phenyl-2-piperidyl acetamide
- 82993-81-5D-threo-Ritalinic acid hydrochloride
- 47087-37-6Z-D-Glu-OMe
- 1219080-61-1IMIDAZOLE-2-BORONIC ACID
| Conditions | Yield |
|---|---|
| With hydrogen; platinum(IV) oxide In isopropyl alcohol under 2327.2 Torr; | 98.5% |
| With sodium formate In ethanol at 85℃; for 1h; | 87% |
| With tetrahydroxydiboron; water at 80℃; for 8h; | 80% |
- 208399-66-0
4-methoxy-2-methylphenyl boronic acid
- 102-50-1
2-methyl-4-methoxyaniline
| Conditions | Yield |
|---|---|
| With sodium hydroxide; hydroxylamine-O-sulfonic acid In acetonitrile at 20℃; for 16h; | 89% |
- 27060-75-9
4-bromo-3-methylanisole
- 102-50-1
2-methyl-4-methoxyaniline
| Conditions | Yield |
|---|---|
| With ammonium sulfate; (R)-(-)-1-[(SP)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine; bis(tri-ortho-tolylphosphine)palladium(0); sodium t-butanolate In 1,4-dioxane at 100℃; for 6h; Inert atmosphere; Glovebox; | 80% |
| With ammonium hydroxide; copper(l) iodide; potassium carbonate; 4R-4-hydroxyproline In dimethyl sulfoxide at 70℃; for 36h; | 77% |
- 154876-10-5
1-(4-methoxy-2-methylphenyl)-1,2-hydrazinedicarboxylic acid bis(2,2,2-trichloroethyl) ester
- 102-50-1
2-methyl-4-methoxyaniline
| Conditions | Yield |
|---|---|
| With acetic acid; zinc for 0.75h; Ambient temperature; | 76% |
- 13334-71-9
1-chloro-4-methoxy-2-methylbenzene
- 102-50-1
2-methyl-4-methoxyaniline
| Conditions | Yield |
|---|---|
| With ammonium hydroxide; potassium phosphate; copper(l) iodide; N1,N2-bis(2,4,6-trimethoxyphenyl)oxalamide In water; dimethyl sulfoxide at 120℃; for 48h; Inert atmosphere; | 64% |
| With bis[chloro(1,2,3-trihapto-allylbenzene)palladium(II)]; N-[2-(di(1-adamantyl)phosphino)phenyl]morpholine; ammonia; sodium t-butanolate In 1,4-dioxane at 65℃; for 24h; Inert atmosphere; chemoselective reaction; | 52% |
- 31601-41-9
N-(4-methoxy-2-methylphenyl)acetamide
- 102-50-1
2-methyl-4-methoxyaniline
| Conditions | Yield |
|---|---|
| With hydrogenchloride |
| Conditions | Yield |
|---|---|
| With sulfuric acid at 25℃; durch wochenlange Einw.; |
- 100-17-4
para-methoxynitrobenzene
- 676-58-4
methylmagnesium chloride
A
- 5961-59-1
N-methyl-N-(4-methoxyphenyl)amine
B
- 102-50-1
2-methyl-4-methoxyaniline
| Conditions | Yield |
|---|---|
| With lithium aluminium tetrahydride; palladium on activated charcoal 1) THF, 20 min, -30 deg C, 2) 20 deg C, 2 h; Yield given. Multistep reaction. Yields of byproduct given; |
- 102-50-1
2-methyl-4-methoxyaniline
| Conditions | Yield |
|---|---|
| With hydrogenchloride |
- 7647-01-0
hydrogenchloride
- 75112-71-9
1-(4-methoxy-2-methyl-phenyl)-ethanone oxime
- 102-50-1
2-methyl-4-methoxyaniline
What can I do for you?
Get Best Price
Chemistry
MW: 137.18
EINECS: 203-036-7
2-METHYL-p-ANISIDINE(102-50-1),Its melting point is about 13-14 °C(lit.);boiling point is 248-249 °C(lit.);density is 1.065 g/mL at 25 °C(lit.) .Following is the molecular structure of 2-METHYL-p-ANISIDINE(102-50-1):
Uses
Toxicity Data With Reference
| 1. | otr-rat:emb 51,500 ng/plate | JJATDK JAT, Journal of Applied Toxicology. 1 (1981),190. |
RTECS :BZ6730000
Consensus Reports
Safety Profile
Suspected carcinogen with experimental carcinogenic and tumorigenic data. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx.
Other safty informations about 2-METHYL-p-ANISIDINE(102-50-1):
Hazard Codes: Xi,Xn,T (Irritant;Harmful;Toxic)
Risk Statements :
R36/37/38:Irritating to eyes, respiratory system and skin
R40:Limited evidence of a carcinogenic effect
R45 :May cause cancer
Safety Statements :
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection
S53:Avoid exposure - obtain special instruction before use
S45 :In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
RIDADR : 2810
WGK Germany : 3