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Cas Database |
| Name |
Aluminium tri-sec-butoxide |
EINECS | 218-871-2 |
| CAS No. | 2269-22-9 | Density | 1.237 g/mL at 25 °C |
| PSA | 27.69000 | LogP | 3.79740 |
| Solubility | Decomposes in water | Melting Point |
N/A |
| Formula | C12H27AlO3 | Boiling Point | 40 °C |
| Molecular Weight | 246.326 | Flash Point | 82 °F |
| Transport Information | UN 1992 | Appearance | viscous colourless or pale yellow liquid |
| Safety | 45-43-36/37/39-26-16 | Risk Codes | 40-21/22-10 |
| Molecular Structure |
|
Hazard Symbols |
 Xi;  Xn
|
| Synonyms |
2-Butanol,aluminum salt (9CI);Aluminum sec-butoxide (6CI,7CI);sec-Butyl alcohol,aluminum salt (8CI);ASB (salt);ASBD;Aluminum 2-butoxide;Aluminumsec-butanolate;Aluminum sec-butylate;Aluminum tri(sec-butylate);Aluminumtri-sec-butoxide;Aluminum tris(sec-butoxide);Tri-sec-butoxyaluminum;Tris(2-butanolato)aluminum;Tris(2-butoxy)aluminum;Tris(sec-butoxy)aluminum;trisec-butoxyalumane;Aluminum tri-sec-butoxide; |
Article Data | 8 |
Aluminium tri-sec-butoxide Synthetic route
- 78-92-2, 15892-23-6
iso-butanol
- 2269-22-9
aluminum tri-sec-butoxide
| Conditions | Yield |
|---|---|
| unter Abdestillieren von Isopropylformiat; |
| Conditions | Yield |
|---|---|
| In neat (no solvent) treatment of the metal with alcohol in the presence of HgCl2 or I2 as catalysts; identified by elem. anal. for Al and by comparison of the constants withpublished data; |
| Conditions | Yield |
|---|---|
| In water addn. of water to Al(CH3CHOC2H5)3 (air), formation of hydroxide, addn. of formic acid and water, boiling and evapn., keeping at 60°C till complete evapn., drying (2 d over drierite); TGA, DTA; | 100% |
| Conditions | Yield |
|---|---|
| In ethanol at 0℃; | 97% |
- 1337458-59-9
1-(4,4-dimethyl-4,5-dihydrooxazol-2-yl)naphthalen-2-ol
- 2269-22-9
aluminum tri-sec-butoxide
| Conditions | Yield |
|---|---|
| In tetrahydrofuran at 20℃; for 1h; Inert atmosphere; Schlenk technique; | 95% |
- 201230-82-2
carbon monoxide
- 2269-22-9
aluminum tri-sec-butoxide
- 939-26-4
2-bromomethylnaphthyl bromide
- 91759-49-8
Naphthalen-2-yl-acetic acid sec-butyl ester
| Conditions | Yield |
|---|---|
| 1,5-hexadienerhodium(I)-chloride dimer In n-heptane at 75℃; for 14h; | 91% |
- 123-92-2
3-methyl-1-butyl acetate
- 2269-22-9
aluminum tri-sec-butoxide
- 25016-92-6
aluminium triisopentylate
| Conditions | Yield |
|---|---|
| In neat (no solvent) byproducts: sec-Bu-OAc; N2 atmosphere; exchange reaction (111°C); distn. of butyl ester; | 90% |
| Conditions | Yield |
|---|---|
| With Hg2Cl2 In butan-1-ol byproducts: H2; under N2; addn. of Mg turnings and Hg2Cl2 to stirred soln. of 2 equiv. of Al(O-sec-Bu)3 in sec-butanol, refluxed (7 d); evapn. (vac.), fractional distn. at 140-165°C/0.03 Torr, elem. anal.; | 86% |
Aluminium tri-sec-butoxide Specification
The Aluminium tri-sec-butoxide, with the CAS registry number 2269-22-9 and EINECS registry number 218-871-2, has the systematic name of trisec-butoxyalumane. And the molecular formula of this chemical is C12H27AlO3. It is a kind of viscous colourless or pale yellow liquid, and belongs to the following product categories: Organic-metal salt; Al (Alminum) Compounds; Classes of Metal Compounds; Typical Metal Compounds; Aluminum; Micro/Nanoelectronics; Solution Deposition Precursors. What's more, it is used as active catalyst, reducer of aldehydes and ketones, gelling agent of paint and ink, and water repellent substance of woof.
The physical properties of Aluminium tri-sec-butoxide are as following: (1)#H bond acceptors: 3; (2)#H bond donors: 0; (3)#Freely Rotating Bonds: 9; (4)Polar Surface Area: 27.69 Å2.
You should be cautious while dealing with this chemical. It is a kind of flammable chemical which is harmful in contact with skin and if swallowed. What's more, there's limited evidence of a carcinogenic effect. Therefore, you had better take the following instructions: Wear suitable protective clothing, gloves and eye/face protection, and in case of contacting with eyes, rinse immediately with plenty of water and seek medical advice; Keep away from sources of ignition - No smoking; In case of accident or if you feel unwell, seek medical advice immediately (show label where possible).
You can still convert the following datas into molecular structure:
(1)SMILES: CCC(C)O[Al](OC(C)CC)OC(C)CC
(2)InChI: InChI=1/3C4H9O.Al/c3*1-3-4(2)5;/h3*4H,3H2,1-2H3;/q3*-1;+3/rC12H27AlO3/c1-7-10(4)14-13(15-11(5)8-2)16-12(6)9-3/h10-12H,7-9H2,1-6H3
(3)InChIKey: WOZZOSDBXABUFO-DYGDCWSTAN
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