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192704-56-6

Basic Information
CAS No.: 192704-56-6
Name: Pregn-4-ene-7,21-dicarboxylicacid, 11,17-dihydroxy-3-oxo-, g-lactone, methyl ester, (7a,11a,17a)-
Article Data: 6
Cas Database
Molecular Structure:
Molecular Structure of 192704-56-6 (Pregn-4-ene-7,21-dicarboxylicacid, 11,17-dihydroxy-3-oxo-, g-lactone, methyl ester, (7a,11a,17a)-)
Formula: C24H32 O6
Molecular Weight: 416.514
Synonyms: 11a,17b-Dihydroxypregn-4-en-3-one 7a,21-dicarboxylic acid g-lactone methyl ester; 11a-Hydroxymexrenone
EINECS: N/A
Density: 1.27±0.1 g/cm3(Predicted)
Melting Point: N/A
Boiling Point: 604.5±55.0 °C(Predicted)
Flash Point: N/A
Solubility: N/A
Appearance: N/A
Hazard Symbols: N/A
Risk Codes: N/A
Safety:
Transport Information: N/A
PSA: 89.90000
LogP: 2.96400
Synthetic route
209253-72-5

9α,11α-epoxy-17β-hydroxypregn-4-en-3-one-7α,21-dicarboxylic acid γ-lactone

74-88-4

methyl iodide

192704-56-6

11β,17β-dihydroxy-7α-methoxycarbonyl-pregna-4-en-3-one-21-carboxylic acid, γ-lactone

Conditions
ConditionsYield
With potassium carbonate In acetone at 0 - 20℃;80%
With potassium carbonate at 0 - 20℃;4 g
192704-54-4

4'S(4'α),7'α-hexadecahydro-11'α-hydroxy-10'β,13'β-dimethyl-3',5,20'-trioxospiro[furan-2(3H),17'β-[4,7]metheno(17H)cyclopenta[a]phenanthrene]-5'β(2'H)-carbonitrile

124-41-4

sodium methylate

192704-56-6

11β,17β-dihydroxy-7α-methoxycarbonyl-pregna-4-en-3-one-21-carboxylic acid, γ-lactone

Conditions
ConditionsYield
Stage #1: 4'S(4'α),7'α-hexadecahydro-11'α-hydroxy-10'β,13'β-dimethyl-3',5,20'-trioxospiro[furan-2(3H),17'β-[4,7]metheno(17H)cyclopenta[a]phenanthrene]-5'β(2'H)-carbonitrile; sodium methylate for 20h; Heating / reflux;
Stage #2: With hydrogenchloride In methanol; water
78%
67-56-1

methanol

192704-54-4

4'S(4'α),7'α-hexadecahydro-11'α-hydroxy-10'β,13'β-dimethyl-3',5,20'-trioxospiro[furan-2(3H),17'β-[4,7]metheno(17H)cyclopenta[a]phenanthrene]-5'β(2'H)-carbonitrile

124-41-4

sodium methylate

192704-56-6

11β,17β-dihydroxy-7α-methoxycarbonyl-pregna-4-en-3-one-21-carboxylic acid, γ-lactone

Conditions
ConditionsYield
Heating / reflux;77%
With zinc(II) iodide

C24H29NO5

865-33-8

potassium methanolate

192704-56-6

11β,17β-dihydroxy-7α-methoxycarbonyl-pregna-4-en-3-one-21-carboxylic acid, γ-lactone

Conditions
ConditionsYield
In methanol at 62 - 115℃; Product distribution / selectivity;68%
With Methyl formate In methanol at 60 - 115℃; for 0.05 - 11.5h; Product distribution / selectivity;62.6%
192704-54-4

4'S(4'α),7'α-hexadecahydro-11'α-hydroxy-10'β,13'β-dimethyl-3',5,20'-trioxospiro[furan-2(3H),17'β-[4,7]metheno(17H)cyclopenta[a]phenanthrene]-5'β(2'H)-carbonitrile

865-33-8

potassium methanolate

192704-56-6

11β,17β-dihydroxy-7α-methoxycarbonyl-pregna-4-en-3-one-21-carboxylic acid, γ-lactone

Conditions
ConditionsYield
In methanol for 23.5h; Heating / reflux;2.98 g
Stage #1: 4'S(4'α),7'α-hexadecahydro-11'α-hydroxy-10'β,13'β-dimethyl-3',5,20'-trioxospiro[furan-2(3H),17'β-[4,7]metheno(17H)cyclopenta[a]phenanthrene]-5'β(2'H)-carbonitrile; potassium methanolate In methanol at 60℃; for 7.5h; Heating / reflux;
Stage #2: With hydrogenchloride In methanol; water for 0.25h;
25 - 27 g
41020-65-9

Mexrenone

192704-56-6

11β,17β-dihydroxy-7α-methoxycarbonyl-pregna-4-en-3-one-21-carboxylic acid, γ-lactone

Conditions
ConditionsYield
With Beuveria bassiana ATCC 7159 In water
With Absidia coerula ATCC 6647 In water
With Aspergillus niger ATCC 16888 In water
192704-56-6

11β,17β-dihydroxy-7α-methoxycarbonyl-pregna-4-en-3-one-21-carboxylic acid, γ-lactone

124-63-0

methanesulfonyl chloride

192704-58-8

methyl hydrogen 17α-hydroxy-11α-(methylsulfonyl)oxy-3-oxopregn-4-ene-7α,21-dicarboxylate, γ-lactone

Conditions
ConditionsYield
With triethylamine In dichloromethane at 10 - 15℃; for 2h; Reagent/catalyst; Temperature; Solvent; Inert atmosphere;97.7%
With triethylamine In dichloromethane at -5 - 5℃; for 1.5h;88%
With pyridine at 5 - 20℃; for 2h;85%
192704-56-6

11β,17β-dihydroxy-7α-methoxycarbonyl-pregna-4-en-3-one-21-carboxylic acid, γ-lactone

95716-70-4

17α-pregna-4,9(11)-diene-7α,21-dicarboxylic acid-17β-hydroxy-3-oxo-γ-lactone-7-methyl ester

Conditions
ConditionsYield
With hexafluoropropene-diethylamine adduct; diethyl-(pentafluoro-propenyl)-amine In chloroform at 30℃; for 30h; Solvent; Temperature; Reagent/catalyst;90%
Stage #1: 11β,17β-dihydroxy-7α-methoxycarbonyl-pregna-4-en-3-one-21-carboxylic acid, γ-lactone With methanesulfonyl chloride; triethylamine In dichloromethane at 5℃; for 1h;
Stage #2: With formic acid; potassium formate; acetic anhydride at 70 - 95℃; for 5 - 9h;
77%
With 1H-imidazole; sulfuryl dichloride In tetrahydrofuran at -10 - 20℃; for 1.5h;71%
192704-56-6

11β,17β-dihydroxy-7α-methoxycarbonyl-pregna-4-en-3-one-21-carboxylic acid, γ-lactone

A

3-oxo-17α-pregn-4-ene-7α,9:21,17-dicarbolactone

B

192704-70-4

7-methyl hydrogen 17α-hydroxy-3-oxopregna-4,11-diene-7α,21-dicarboxylate, γ-lactone

C

95716-70-4

17α-pregna-4,9(11)-diene-7α,21-dicarboxylic acid-17β-hydroxy-3-oxo-γ-lactone-7-methyl ester

Conditions
ConditionsYield
Stage #1: 11β,17β-dihydroxy-7α-methoxycarbonyl-pregna-4-en-3-one-21-carboxylic acid, γ-lactone With methanesulfonyl chloride; triethylamine In dichloromethane at 0℃; for 1.41667h;
Stage #2: With formic acid; potassium formate; acetic anhydride at 40 - 95℃; for 2h;
A 2.27 g
B 3.72 g
C 68.8%
Stage #1: 11β,17β-dihydroxy-7α-methoxycarbonyl-pregna-4-en-3-one-21-carboxylic acid, γ-lactone With sulfuryl dichloride In tetrahydrofuran at -70℃; for 0.5h;
Stage #2: With 1H-imidazole In tetrahydrofuran at -70 - 20℃; for 2h;
Stage #1: 11β,17β-dihydroxy-7α-methoxycarbonyl-pregna-4-en-3-one-21-carboxylic acid, γ-lactone With methanesulfonyl chloride; triethylamine In dichloromethane at -5 - 0℃; for 1.33333h;
Stage #2: With sodium acetate; acetic anhydride; acetic acid In dichloromethane at 55 - 135℃; for 1.5 - 2h;
192704-56-6

11β,17β-dihydroxy-7α-methoxycarbonyl-pregna-4-en-3-one-21-carboxylic acid, γ-lactone

192704-58-8

methyl hydrogen 17α-hydroxy-11α-(methylsulfonyl)oxy-3-oxopregn-4-ene-7α,21-dicarboxylate, γ-lactone

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95716-70-4
107724-20-9
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    192704-56-6

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    Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

    Xiamen Aeco Chemical Industrial Co., Ltd(same as Aecochem Corp.) An ISO 9001:2015 Certified Company Your Partner in China, a Professional chemical raw material supplier, our

  •  Aecochem Corp.

     China (Mainland)  |  Contact Details

    Business Type:Manufacturers

    Tel:+86-592 599 8717

    Address:No 611 Sishui Road,Huli

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  • 11-A-Hydroxy Canrenone Methyl Ester

  • Casno:

    192704-56-6

    11-A-Hydroxy Canrenone Methyl Ester

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0/

    11-A-Hydroxy Canrenone Methyl Ester supplierAppearance:Almost white to pale yellow crystalline powder Storage:Keep away of light,cool place Package:25kg/drum;200kg/drum Application:Eplerenone Transportation:Sea/air/courier

    Orchid Chemical was established in 2009; we are headquartered in Hangzhou, which is 200 km from China's biggest sea port, Shanghai. Orchid chemical is a joint-venture company, com

  •  ORCHID CHEMICAL SUPPLIES LTD

     China (Mainland)  |  Contact Details

    Business Type:Other

    Tel:+86-571-85395792

    Address:607, North Zhongshan Road, Hangzhou 310000 China

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  • 11α-hydroxymexrenone (A2)

  • Casno:

    192704-56-6

    11α-hydroxymexrenone (A2)

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0/

    KONING PHARMCHEM CO., LTD. has committed itself to a strategy of providing a unique service for companies involved in the manufacture of pharmaceuticals, healthcare products, food, cosmetics and other fine chemicals. Our products including but not li

    KONING PHARMCHEM CO., LTD. has committed itself to a strategy of providing a unique service for companies involved in the manufacture of pharmaceuticals, healthcare products, food,

  •  Koning Pharmchem Co., Ltd.

    China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:86-574-87369228

    Address:Lingqiao Road

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  • 11a-Hydroxy Mexrenone

  • Casno:

    192704-56-6

    11a-Hydroxy Mexrenone

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0/

    FINETECH INDUSTRY LIMITED is a LONDON based CRO company providing drug discovery & development services to worldwide clients. FINETECH INDUSTRY LIMITED supplies the 11a-Hydroxy Mexrenone, CAS:192704-56-6 with the most competitive price and the best q

    Finetech Industry Limited is a company in England,which specializing in developing, manufacturing and marketing fine organic compounds and intermediates for the fine chemical and p

  •  Finetech Industry Limited

    China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:86-27-87465837

    Address:wuhan

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  • 11-a-Hydroxy canrenone methyl ester,192704-56-6

  • Casno:

    192704-56-6

    11-a-Hydroxy canrenone methyl ester,192704-56-6

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0/

    instock with good quality and wholesale price Storage:Keep in a cool & dry place Package:Packing material and QTY as your request Application:Pharma;Industry;other application Transportation:Express or as your request Port:Any port of China

    Wuhan MoonZY Biological Technology Co.,Ltd (MoonzyBio)is located in Wuhan city,hubei province,China,we have a group of senior technical backbones, specialized in R & D and sales in

  •  Wuhan MoonZY Biological Technology Co.,Ltd

     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:13545198479

    Address:203,Building 3, International Enterprise Center, No. 1 Guanshan 2nd Road, East Lake New Technology Development Zone,

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  • 11-a-Hydroxy canrenone methyl ester CAS No.192704-56-6

  • Casno:

    192704-56-6

    11-a-Hydroxy canrenone methyl ester CAS No.192704-56-6

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0/

    Factory supply high purity low priceAppearance:solid or liquid Storage:sealed in cool and dry place Package:As customer's requested Application:Pharma Intermediate Transportation:by courier/air/sea Port:Any port in China

    Guangdong Juda Chemical Industrial Co.,Limited is a company specializing in APIs,pharmaceutical intermediates, electronic chemicals, plant extracts,fine chemicals and cosmetics raw

  •  Guangdong Juda Chemical Industrial Co.,Limited

    China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:+86 13510152023(whatsapp)

    Address:Guangzhou chemical city Tianhe District Guangzhou Guangdong China

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  • 11-A-Hydroxy Canrenone Methyl Ester

  • Casno:

    192704-56-6

    11-A-Hydroxy Canrenone Methyl Ester

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0/

    IKGCHEM is a leading manufacturer and supplier of chemical in China.As a Professional chemical raw material supplier,our products are produced in accordance with ISO 9001:2015 Quality Management System and ISO14001:6861 Environmental Management Syste

    IKGCHEM is a leading manufacturer and supplier of chemical in China.As a Professional chemical raw material supplier, our main products include the Pharma Chemical,Petro Chemical,

  •  Xiamen Ikg Chemical Co., Ltd.

     China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:+86 592-6102469

    Address:No.25 Binlang Road,Siming, Xiamen, China

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