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Cas Database |
| Name |
Aminoacetonitrile hydrochloride |
EINECS | 227-865-9 |
| CAS No. | 6011-14-9 | Density | N/A |
| PSA | 49.81000 | LogP | 0.97098 |
| Solubility | Soluble in water 20°C, 1000g/L. | Melting Point |
172-174 °C |
| Formula | C2H5ClN2 | Boiling Point | 164.2 °C at 760 mmHg |
| Molecular Weight | 92.5281 | Flash Point | 53.1 °C |
| Transport Information | UN 3439 | Appearance | White to off-white crystalline powder |
| Safety | 22-36/37 | Risk Codes | 20/21/22 |
| Molecular Structure |
|
Hazard Symbols | R22:Harmful if swallowed.; R36/37/38:Irritating to eyes, respiratory system and skin.; |
| Synonyms |
Acetonitrile,amino-, monohydrochloride (9CI);Glycinonitrile, monohydrochloride (8CI);2-Aminoacetonitrile hydrochloride;Aminoacetonitrile monohydrochloride;Glycinonitrile hydrochloride;a-Aminoacetonitrilehydrochloride; |
Article Data | 3 |
Aminoacetonitrile hydrochloride Synthetic route
Conditions
| Conditions | Yield |
|---|---|
| With hydrogenchloride at 20 - 30℃; for 2h; Temperature; | 82.8% |
Conditions
| Conditions | Yield |
|---|---|
| Stage #1: sodium cyanide; formaldehyd With ammonium hydroxide Stage #2: With hydrogenchloride |
- 85-44-9
phthalic anhydride
- 6011-14-9
2-aminoacetonitrile hydrochloride
- 3842-20-4
N-(cyanomethyl)phthalimide
Conditions
| Conditions | Yield |
|---|---|
| With triethylamine In chloroform for 6h; Heating; | 100% |
| With triethylamine In chloroform at 10℃; for 12.5h; Temperature; Reflux; | 98.6% |
| With triethylamine In chloroform for 18h; Reflux; | 75% |
- 13139-16-7
N-(t-butoxycarbonyl)-isoleucine
- 6011-14-9
2-aminoacetonitrile hydrochloride
Conditions
| Conditions | Yield |
|---|---|
| With benzotriazol-1-ol In DMF (N,N-dimethyl-formamide); water at 20℃; for 1h; | 100% |
- 55-22-1
pyridine-4-carboxylic acid
- 6011-14-9
2-aminoacetonitrile hydrochloride
- 1184796-18-6
N-(cyanomethyl)isonicotinamide
Conditions
| Conditions | Yield |
|---|---|
| With benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; N-ethyl-N,N-diisopropylamine In dichloromethane at 20℃; for 24h; | 99% |
| With benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; N-ethyl-N,N-diisopropylamine In dichloromethane at 20℃; for 24h; |
- 6011-14-9
2-aminoacetonitrile hydrochloride
- 148-53-8
3-methoxy-2-hydroxybenzaldehyde
- 1279019-01-0
(2-hydroxy-3-methoxybenzylideneamino)acetonitrile
Conditions
| Conditions | Yield |
|---|---|
| With sodium acetate In methanol at 20℃; for 2h; | 99% |
- 1679-18-1
4-Chlorophenylboronic acid
- 6011-14-9
2-aminoacetonitrile hydrochloride
- 140-53-4
p-chlorobenzyl cyanide
Conditions
| Conditions | Yield |
|---|---|
| With sodium nitrite In water; toluene at 50℃; for 24h; Schlenk technique; | 99% |
- 15224-05-2
ethyl 2-(allylthio)acetate
- 6011-14-9
2-aminoacetonitrile hydrochloride
Conditions
| Conditions | Yield |
|---|---|
| With meso-tetraphenylporphyrin iron(III) chloride; sodium nitrite In dichloromethane; water at 20℃; for 15h; Inert atmosphere; diastereoselective reaction; | 99% |
Conditions
| Conditions | Yield |
|---|---|
| Stage #1: 2-aminoacetonitrile hydrochloride With FeCl(tiprp); sodium nitrite In toluene at 55℃; Inert atmosphere; Flow reactor; Stage #2: N-benzyl-N-(4-methylphenyl)amine In toluene at 20℃; Inert atmosphere; | 99% |
Conditions
| Conditions | Yield |
|---|---|
| Stage #1: 2-aminoacetonitrile hydrochloride With FeCl(tiprp); sodium nitrite In toluene at 55℃; Inert atmosphere; Flow reactor; Stage #2: N-benzyl-3-methylaniline In toluene at 20℃; Inert atmosphere; | 99% |
Aminoacetonitrile hydrochloride Chemical Properties
IUPAC Name: 2-aminoacetonitrile hydrochloride
The MF of GLYCINONITRILE HYDROCHLORIDE(6011-14-9): C2H5ClN2
The MW of GLYCINONITRILE HYDROCHLORIDE(6011-14-9): 92.53
EINECS: 227-865-9
mp: 172-174°C
Sensitive: Hygroscopic
Flash Point: 53.1 °C
Enthalpy of Vaporization: 40.07 kJ/mol
Boiling Point: 164.2 °C at 760 mmHg
Vapour Pressure: 1.99 mmHg at 25°C
Categories: Pharmaceutical Intermediates;straight chain compounds
Synonyms: AMINO ACETONITRILE HCL;AMINOACETONITRILE HYDROCHLORIDE;Glycinonitrile hydrochloride;alpha-aminoacetonitrilehydrochloride;aminoacetonitrilemonohydrochloride;amino-acetonitrilmonohydrochloride;glycinonitrile,monohydrochloride;2-AminoacetonitrileHydrochloride
The Structure of GLYCINONITRILE HYDROCHLORIDE(6011-14-9):
The MF of GLYCINONITRILE HYDROCHLORIDE(6011-14-9): C2H5ClN2
The MW of GLYCINONITRILE HYDROCHLORIDE(6011-14-9): 92.53
EINECS: 227-865-9
mp: 172-174°C
Sensitive: Hygroscopic
Flash Point: 53.1 °C
Enthalpy of Vaporization: 40.07 kJ/mol
Boiling Point: 164.2 °C at 760 mmHg
Vapour Pressure: 1.99 mmHg at 25°C
Categories: Pharmaceutical Intermediates;straight chain compounds
Synonyms: AMINO ACETONITRILE HCL;AMINOACETONITRILE HYDROCHLORIDE;Glycinonitrile hydrochloride;alpha-aminoacetonitrilehydrochloride;aminoacetonitrilemonohydrochloride;amino-acetonitrilmonohydrochloride;glycinonitrile,monohydrochloride;2-AminoacetonitrileHydrochloride
The Structure of GLYCINONITRILE HYDROCHLORIDE(6011-14-9):
Aminoacetonitrile hydrochloride Uses
GLYCINONITRILE HYDROCHLORIDE(6011-14-9): is used as pharmaceutical intermediates, and organic synthetic materials.
Aminoacetonitrile hydrochloride Consensus Reports
Reported in EPA TSCA Inventory.
Aminoacetonitrile hydrochloride Safety Profile
An experimental teratogen. Experimental reproductive effects. When heated to decomposition it emits toxic fumes of NOx and HCl.
Risk Statements: 20/21/22
20/21/22: Harmful by inhalation, in contact with skin and if swallowed
Safety Statements: 22-36/37
22: Do not breathe dust
36/37: Wear suitable protective clothing and gloves
RIDADR: 3439
HazardClass: 6.1
PackingGroup: III
Risk Statements: 20/21/22
20/21/22: Harmful by inhalation, in contact with skin and if swallowed
Safety Statements: 22-36/37
22: Do not breathe dust
36/37: Wear suitable protective clothing and gloves
RIDADR: 3439
HazardClass: 6.1
PackingGroup: III
Aminoacetonitrile hydrochloride Specification
1. First Aid Measures
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Eyes:
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
2. Handling and Storage
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from moisture.
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Eyes:
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
2. Handling and Storage
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from moisture.
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
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Aminoacetonitrile hydrochloride
