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Boron tribromide

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Name

Boron tribromide

EINECS 233-657-9
CAS No. 10294-33-4 Density 2.782 g/cm3
PSA 0.00000 LogP 2.15600
Solubility Reacts with water. Melting Point -46 °C(lit.)
Formula BBr3 Boiling Point 91.3 °C at 760 mmHg
Molecular Weight 250.523 Flash Point 30°F
Transport Information UN 3390 6.1/PG 1 Appearance clear to amber liquid with a pungent odour
Safety 9-26-28-36/37/39-45-23-33-16-62-61-60 Risk Codes 14-26/28-35-40-62-11-67-65-50/53
Molecular Structure Molecular Structure of 10294-33-4 (Boron tribromide) Hazard Symbols VeryT+, CorrosiveC, FlammableF, DangerousN
Synonyms

Boronbromide (BBr3) (8CI);Boron bromide;Boron(III) bromide;Tribromoborane;Tribromoboron;Borane, tribromo-;

Article Data 109

Boron tribromide Synthetic route

pentaborane(9)

14355-29-4

diboron tetrabromide

A

1-(dibromoboryl)pentaborane

B

10294-33-4

boron tribromide

C

13709-65-4

dibromoborane

Conditions
ConditionsYield
In neat (no solvent) Teflon-valve-equipped standard vacuum line or a nitrogen-filled glovebox;excess B5H9;pentaborane, B2Br4 separately condensed in the reactor, after 20 min at room temp., vessel cooled to -10 ° C,; over course of the following 10 h,all volatile material removed,reactor warmed to room temp.,all volatile material at room temp. were removed,BBr2B5H8 extd. with CH2Cl2, yield:80% on basis of amt. of B2Br4 employed, 86% on basis of unrecovered B5H9;A 80%
B n/a
C n/a

boron

7726-95-6

bromine

10294-33-4

boron tribromide

Conditions
ConditionsYield
boron is mixed with ca. 9 w % Mg, in H2 atmosphere;70%
In not given kept over liq. Hg for 48 h; distd. (vac., room temp.);57.6%
at red heat; in H2 atmosphere;40%
7637-07-2

boron trifluoride

7727-15-3

aluminium bromide

10294-33-4

boron tribromide

Conditions
ConditionsYield
with excess of BF3; addn. of Al to depress formation of Br2; addn. of Hg to get rid of Br2;70%
with excess of BF3; addn. of Al to depress formation of Br2; addn. of Hg to get rid of Br2;70%

BBr3*2(o-nitrotoluene)

10294-33-4

boron tribromide

Conditions
ConditionsYield
In neat (no solvent) byproducts: o-CH3C6H4NO2; decompn. reaction immediately;50%

BBr3*3C6H5NO2

10294-33-4

boron tribromide

Conditions
ConditionsYield
In neat (no solvent) byproducts: C6H5NO2; decompn. reaction immediately;50%
14355-29-4

diboron tetrabromide

353-54-8

tribromofluoromethane

A

12589-31-0

closo-B9Br9

B

7637-07-2

boron trifluoride

C

10294-33-4

boron tribromide

D

13965-73-6

diboron tetrafluoride

Conditions
ConditionsYield
B2Br4 and CFBr3 were reacted in a NMR-tube at ambient temp. for 3,75 h; products detected by (19)F- and (11)B-NMR, CBr4 by (13)C-NMR;A 2%
B 7%
C 2%
D 39%
7727-15-3

aluminium bromide

14075-53-7

potassium tetrafluoroborate

10294-33-4

boron tribromide

Conditions
ConditionsYield
30%
30%
856317-96-9

BBr3*Cl3CCOOC2H5

10294-33-4

boron tribromide

Conditions
ConditionsYield
In neat (no solvent) byproducts: Cl3CCOOC2H5; decompn. reaction immediately;25%
14355-29-4

diboron tetrabromide

558-13-4

carbon tetrabromide

10294-33-4

boron tribromide

Conditions
ConditionsYield
Vac.-distn. of B2Br4 to CBr4, heating in an oil-bath (96°C, 5.75 h).; Monitored by (11)B-NMR.;8.6%

boron(III) sulfide

7726-95-6

bromine

10294-33-4

boron tribromide

Conditions
ConditionsYield
heating of B2S3 in Br2 vapour;

Boron tribromide Chemical Properties

MF: BBr3
MW: 250.52
mp : -46 °C(lit.)
bp : -90 °C
density : 2.60 g/mL at 20 °C(lit.)
vapor density : 8.6 (vs air)
vapor pressure : 40 mm Hg ( 14 °C)
Fp : 30 °F
storage temp. : Poison room
color : colorless
Sensitive : Moisture Sensitive 
IUPAC Name: tribromoborane  
Storage temp: Poison room
Sensitive: Moisture Sensitive
Stability: Stable, but reacts violently with water
Appearance: clear to amber liquid with a pungent odour
Product Categories: Inorganics;Piperazine derivates;Deprotecting Reagents;Others;Protection and Derivatization
Synonyms of Boron tribromide (10294-33-4): BBr3 ; Borane,tribromo- ; Boron,tribromo- ; boronbromide(bbr3) ; tribromo-boran ; tribromoborane ; tribromoboron ; tribromo-Boron 
Molecular Structure of Boron tribromide (10294-33-4):

 Boron tribromide (10294-33-4) is commercially available and is a strong Lewis acid. It is an excellent demethylating or dealkylating agent for ethers, often in the production of pharmaceuticals. Additionally, it also finds applications in olefin polymerization and in Friedel-Crafts chemistry as a Lewis acid catalyst. The electronics industry uses boron tribromide as a boron source in pre-deposition processes for doping in the manufacture of semiconductors.

Boron tribromide Uses

 Boron tribromide (10294-33-4) is used as intermingle source in semiconductor silicon; extracting high-purity boron and organic boron compound; a source in optical fibre.

Boron tribromide Production

The first synthesis was done by M. Poggiale in 1846 by reacting boron trioxide with carbon and bromine at high temperatures:
B2O3 + 3 C + 3 Br2 → 2 BBr3 + 3 CO
An improvement of this method was developed by F. W?hler and Deville in 1857. By starting from amorphous boron the reaction temperatures are lower and no carbon monoxide is produced
2 B + 3 Br2 → 2 BBr3 

Boron tribromide Toxicity Data With Reference

RTECS#: CAS# 142-82-5: MI7700000
CAS# 10294-33-4: ED7400000
LD50/LC50: RTECS:
CAS# 142-82-5: Inhalation, rat: LC50 = 103 gm/m3/4H;
RTECS:
CAS# 10294-33-4:.
Carcinogenicity: Heptane (n-) - Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65.
Boron tribromide (10294-33-4)  - Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65.
Other: See actual entry in RTECS for complete information.

Boron tribromide Safety Profile

Hazard Codes:VeryT+CorrosiveCFlammableFDangerousN
Risk Statements: 14-26/28-35-40-62-11-67-65-50/53 
R14: Reacts violently with water
R26/28: Very toxic by inhalation and if swallowed
R35: Causes severe burns
R40: Limited evidence of a carcinogenic effect
R62: Risk of impaired fertility
R11: Highly flammable
R67: Vapours may cause drowsiness and dizziness
R65: Harmful: may cause lung damage if swallowed
R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Safety Statements: 9-26-28-36/37/39-45-23-33-16-62-61-60 
S9: Keep container in a well-ventilated place 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S28: After contact with skin, wash immediately with plenty of soap-suds
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S23: Do not breathe vapour
S33: Take precautionary measures against static discharges
S16: Keep away from sources of ignition
S62: If swallowed, do not induce vomitting; seek medical advice immediately and show this container or label
S61: Avoid release to the environment. Refer to special instructions / safety data sheets
S60: This material and its container must be disposed of as hazardous waste
RIDADR: UN 3390 6.1/PG 1
WGK Germany: 3
RTECS: ED7400000
F: 10-21
HazardClass: 8
PackingGroup: I

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