133409-72-0

Basic information

• Product Name: (E)-Methyl-2-(2-broMoMethylphenyl)-2-MethoxyiMinoacetate
• Synonyms: (E)-Methyl-2-(2-broMoMethylphenyl)-2-MethoxyiMinoacetate;Methyl-2-(2-broMoMethylphenyl)-2-MethoxyiMinoacetate;Benzeneacetic acid, 2-(broMoMethyl)-a-(MethoxyiMino)-, Methyl ester, (aE)-;(E)-2-bromomethyl-α-methoxyimino phenylacetate;(E)-Methyl 2-(methoxyimino)-2-[2-(bromomethyl)phenyl]acetate;(E)-2-[2-(Bromomethyl)phenyl]-2-(methoxyimino)acetic Acid Methyl Ester;(alphaE)-2-Bromomethyl-alpha-(methoxyimino)phenyl-acetic acid methyl ester
• CAS NO: 133409-72-0
• Molecular Formula: C₁₁H₁₂BrNO₃
• Molecular Weight: 286.12188
• EINECS: -0
• Mol File: 133409-72-0.mol

Chemical Properties

• Melting Point: 45-48 °C
• Boiling Point: 343.7±44.0 °C(Predicted)
• Appearance: /
• Density: 1.38±0.1 g/cm3(Predicted)
• Solubility: DCM, Ethyl Acetate
• CAS DataBase Reference: (E)-Methyl-2-(2-broMoMethylphenyl)-2-MethoxyiMinoacetate(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-Methyl-2-(2-broMoMethylphenyl)-2-MethoxyiMinoacetate(133409-72-0)
• EPA Substance Registry System: (E)-Methyl-2-(2-broMoMethylphenyl)-2-MethoxyiMinoacetate(133409-72-0)

Safety Data

• Hazardous Substances Data: 133409-72-0(Hazardous Substances Data)

Upstream product

• 120974-97-2 methyl-(E)-2-(2-tolyl)-2-methoxyiminoacetate 
• 178240-01-2 methyl (E)-2-hydroxyimino-2-o-tolylacetate 
• 2028-34-4 o-toluene-diazonium chloride 
• 34241-39-9 azobisisobutyronitrile 
• 94-36-0 dibenzoyl peroxide 
• 67-56-1 methanol 
• 149728-96-1 isochroman-3,4-dione 4-(O-methyl-oxime) 
• 577-16-2 2-Methylacetophenone 
• 932-31-0 ortho-tolylmagnesium bromide 
• 529-20-4 2-methylphenyl aldehyde 
• 85589-34-0 2-hydroxy-2-(2-methylphenyl)acetonitrile 
• 95-53-4 o-toluidine 
• 22364-68-7 2-tolylmethylnitrile 
• 178983-50-1 2-methyl-a-cyanobenzoxime potassium 

Downstream Products

• 156581-14-5 methyl (2E)-2-[2-[(1,3-dioxoisoindolin-2-yl)oxymethyl]phenyl]-2-methoxyiminoacetate 
• 936320-71-7 C₁₁H₁₂N₄O₃ 

Relevant articles and documents

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The invention belongs to the technical field of fine chemical engineering, and particularly relates to a green synthetic method of kresoxim-methyl. The method comprises the following steps: carrying out nitrous nitrification by using 2-methylbenzyl cyanide as an initial raw material, carrying out methylation, carrying out hydrolytic methylation or hydrolytic esterification, carrying out bromination and carrying out an etherification reaction to obtain the high-content kresoxim-methyl. The method provided by the invention has a short reaction period, a high conversion rate, and excellent product quality, changes the defect that high-concentration hydrochloric acid gas is used for preparation in a traditional process, and has the advantages of simple operation steps, simple equipment, low energy consumption, a short period, high productivity and environmental protection.

AN IMPROVED PROCESS FOR THE PREPARATION OF TRIFLOXYSTROBIN

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