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1413732-47-4

(2,2'-bipyridine)Cu(SCF3) is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 8-[(trifluoromethyl)sulfanyl]-7λ ,9λ -diaza-8-cupratricyclo[7.4.0.02, ]trideca-1(13),2(7),3,5,9,11-hexaene-7,9-bis(ylium)

    Cas No: 1413732-47-4

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  • 1413732-47-4 Structure

  • Basic information

    1. Product Name: (2,2'-bipyridine)Cu(SCF3)
    2. Synonyms: (2,2'-bipyridine)Cu(SCF3);Trifluoromethylthiolato(2,2-bipyridine)copper(I), 97%
    3. CAS NO:1413732-47-4
    4. Molecular Formula: C11H8CuF3N2S
    5. Molecular Weight: 321.81
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 1413732-47-4.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: red/crystal
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: under inert gas (nitrogen or Argon) at 2–8 °C
    8. Solubility: N/A
    9. Sensitive: air sensitive, moisture sensitiv
    10. CAS DataBase Reference: (2,2'-bipyridine)Cu(SCF3)(CAS DataBase Reference)
    11. NIST Chemistry Reference: (2,2'-bipyridine)Cu(SCF3)(1413732-47-4)
    12. EPA Substance Registry System: (2,2'-bipyridine)Cu(SCF3)(1413732-47-4)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: 21/22-36/38
    3. Safety Statements: 26-36/37-60
    4. WGK Germany:
    5. RTECS:
    6. TSCA: No
    7. HazardClass: N/A
    8. PackingGroup: N/A
    9. Hazardous Substances Data: 1413732-47-4(Hazardous Substances Data)

1413732-47-4 Usage

Uses

Novel, air-stable copper reagent for trifluoromethylthiolation of aryl halides.

Check Digit Verification of cas no

The CAS Registry Mumber 1413732-47-4 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,4,1,3,7,3 and 2 respectively; the second part has 2 digits, 4 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 1413732-47:
(9*1)+(8*4)+(7*1)+(6*3)+(5*7)+(4*3)+(3*2)+(2*4)+(1*7)=134
134 % 10 = 4
So 1413732-47-4 is a valid CAS Registry Number.

1413732-47-4Relevant articles and documents

Cu-mediated oxidative trifluoromethylthiolation of arylboronic acids with (bpy)CuSCF3

Zhao, Mingzhu,Zhao, Xiaoming,Zheng, Purui,Tian, Yawei

, p. 73 - 79 (2017/01/17)

An efficient trifluoromethylthiolation reaction of arylboronic acids with (bpy)CuSCF3in the presence of oxygen at room temperature is described. This method produces a variety of aryl trifluoromethylthioether derivatives in good to high yield. The mechanism of this trifluoromethylthiolation is discussed as well.

Triphenylphosphine-Mediated Deoxygenative Reduction of CF3SO2Na and Its Application for Trifluoromethylthiolation of Aryl Iodides

Yang, Yi,Xu, Long,Yu, Siqi,Liu, Xiaoqiang,Zhang, Yu,Vicic, David A.

supporting information, p. 858 - 863 (2016/01/16)

We report herein a practical method for taming Langlois' reagent CF3SO2Na to generate CuSCF3 by a triphenylphospine-mediated deoxygenative reduction process. This chemistry highlights a novel utilization of the inherent CF3S skeleton of Langlois' reagent as a CF3S feedstock under mild conditions. The CuSCF3 intermediate generated by this protocol can react with a wide array of supporting ligands to furnish several air-stable [LCu(SCF3)] complexes as valuable trifluoromethylthiolating agents. In addition, the CuSCF3 intermediate can be directly employed for the trifluoromethylthiolation of (hetero)aryl iodides with operational simplicity and atomic efficiency. Efficient synthesis! A low cost method for the generation of CuSCF3 by a triphenylphospine-mediated deoxygenative reduction of Langlois' reagent (CF3SO2Na) has been developed (see scheme). This method can be applied for the convenient synthesis of a wide array of ligated and air-stable CuSCF3 complexes. Additionally, the CuSCF3 complexes generated in situ by this protocol were found to trifluoromethylthiolate (hetero)aryl iodides with high efficiency.

Development of Multigram Scale Synthesis of Trifluoromethylthiolating Reagent: (bpy)CuSCF3

Zhang, Yunxiao,Gan, Kangji,Weng, Zhiqiang

, p. 799 - 802 (2016/05/19)

A practical and reproducible procedure for the efficient preparation of (bpy)CuSCF3 (1), a copper reagent for trifluoromethylthiolation reaction, is reported. All reaction parameters were optimized, and reagent 1 was synthesized in 26 g scale.

PESTICIDALLY ACTIVE POLYCYCLIC DERIVATIVES WITH SULFUR CONTAINING SUBSTITUENTS

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Page/Page column 47, (2016/07/27)

Compounds of formula (I), wherein the substituents are as defined in claim 1, and the agrochemically acceptable salts salts, stereoisomers, enantiomers, tautomers and N-oxides of those compounds, can be used as insecticides and can be prepared in a manner known per se.

An air-stable copper reagent for nucleophilic trifluoromethylthiolation of aryl halides

Weng, Zhiqiang,He, Weiming,Chen, Chaohuang,Lee, Richmond,Tan, Davin,Lai, Zhiping,Kong, Dedao,Yuan, Yaofeng,Huang, Kuo-Wei

supporting information, p. 1548 - 1552 (2013/03/13)

A series of copper(I) trifluoromethyl thiolate complexes have been synthesized from the reaction of CuF2 with Me3SiCF 3 and S8 (see scheme; Cu red, F green, N blue, S yellow). These air-stable complexes serve as reagents for the efficient conversion of a wide range of aryl halides into the corresponding aryl trifluoromethyl thioethers in excellent yields. Copyright

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