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Ferric Benzoate is the ferric salt form of benzoate. Ferric benzoate has certain anti-corrosion properties. For example, it can be used as a novel steel corrosion inhibitor pigment for protective paint films. Ferric benzoate has been found particularly useful in providing intense, black permanent fingerprint records when used with the aforementioned metal complexing compounds

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  • 14534-87-3 Structure
  • Basic information

    1. Product Name: FERRIC BENZOATE
    2. Synonyms: Tribenzoic acid iron(III) salt;Benzoicacid,iron(3+)salt;benzoicacid,iron(3++)salt;irontribenzoate;IRON (III) BENZOATE;FERRIC BENZOATE
    3. CAS NO:14534-87-3
    4. Molecular Formula: 2C7H5O2*Fe
    5. Molecular Weight: 419.19
    6. EINECS: 238-566-8
    7. Product Categories: N/A
    8. Mol File: 14534-87-3.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: 249.3°Cat760mmHg
    3. Flash Point: 111.4°C
    4. Appearance: /
    5. Density: g/cm3
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: FERRIC BENZOATE(CAS DataBase Reference)
    10. NIST Chemistry Reference: FERRIC BENZOATE(14534-87-3)
    11. EPA Substance Registry System: FERRIC BENZOATE(14534-87-3)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 14534-87-3(Hazardous Substances Data)

14534-87-3 Usage

Sources

DD Buerkley, NP Sweeny, DN Vivona US Patent 4,232,083, 1980 Google Patents Blustein, G., et al. Corrosion Science 49.11(2007):4202-4231. Amo, B. Del, et al. Colloids & Surfaces A Physicochemical & Engineering Aspects 324.1(2008):58-64. Blustein, Guillermo, et al. Información Tecnológica 17.3(2006):189-196.

Check Digit Verification of cas no

The CAS Registry Mumber 14534-87-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,4,5,3 and 4 respectively; the second part has 2 digits, 8 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 14534-87:
(7*1)+(6*4)+(5*5)+(4*3)+(3*4)+(2*8)+(1*7)=103
103 % 10 = 3
So 14534-87-3 is a valid CAS Registry Number.
InChI:InChI=1/C7H6O2.Fe/c8-7(9)6-4-2-1-3-5-6;/h1-5H,(H,8,9);/q;+3/p-1

14534-87-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name iron(3+),tribenzoate

1.2 Other means of identification

Product number -
Other names Iron tribenzoate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:14534-87-3 SDS

14534-87-3Downstream Products

14534-87-3Relevant articles and documents

Effect of solvent nature on the reaction of metallic iron with benzoic acid in a bead mill

Ivanov,Grechushnikov

, p. 597 - 602 (2008)

Results of an experimental study of the influence exerted by the solvent nature on the reaction rate, achieved degree of acid expenditure, selectivity with respect to salts of iron(II) and (III), and phase state of the reaction mixture in a single-stage reaction of iron with benzoic acid and atmospheric oxygen in the presence of a stimulating iodine additive are presented.

Benzoato Complexes of Iron and Cobalt. Synthesis and Properties of Fe3(C6H5COO)4(acac)2, Fe(C6H5COO)2 and Co(C6H5COO)2, Crystal Structure of Fe3(C6H5COO)4(acac)2 and Co(C6H5COO)2

Spohn, Martin,Straehle, Joachim

, p. 540 - 546 (2007/10/02)

The reaction of iron(III) acetylacetonate with molten benzoic acid yields Fe(C6H5COO)2 (2) besides small amounts of Fe3(C6H5COO)4(acac)2 (1), whereas cobalt (III) acetylacetonate or cobalt(II) carbonate quantitatively yield Co(C6H5COO)2 (3).Complex 1 forms triclinic red crystals with the space group P and the lattice constants a = 1016.0(3) pm, b = 1099.9(2) pm,c = 969.8(2) pm, α = 92.68(2) deg, β = 105.67(2) deg, γ = 117.57(2) deg, Z = 1. 3 is obtained as monoclinic violet needles with the space group C2/c and the lattice constants a = 1739.2(4) pm, b = 1413.8(3) pm, c = 1045.3(3) pm, β = 96.26(2) deg, Z = 8. 3 consists of polymeric chains with a zigzag arrangement of the cobalt atoms (Co-Co = 314.5 pm) and an octahedral coordination for Co 1 and (4 + 2)-coordination for Co 2.The benzoato ligands act differently.One benzoate group functions as bridging ligand between adjacent metal atoms, the other acts as a four-dentate ligand by chelating one cobalt atom and bridging its neighbours.Complex 2 was not obtained in form of single crystals, but its properties as well as its IR and Moessbauer spectra suggest a similar structure as for 3.Complex 1 is also polymeric, the chain of iron atoms is nearly linear.The acetylacetonate ligand acts chelating and bridging as a four-dentate ligand, whereas the benzoate anion is only bridging neighbouring Fe atoms.The Fe atoms exhibit octahedral and trigonal bipyramidal coordination. - Keywords: Tetrabenzoato Diacetylacetonato Triiron(II), Dibenzoato Iron(II), Dibenzoato Cobalt(II), Synthesis, Crystal Structure

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