18006-25-2

Basic information

• Product Name: 3-O-Benzyl-5,6-di-O-acetyl-1,2-O-isopropylidene-a-D-glucofuranose
• Synonyms: 3-O-Benzyl-5,6-di-O-acetyl-1,2-O-isoproylidene-a-D-glucofuranose;3-O-Benzyl-5,6-di-O-acetyl-1,2-O-isopropylidene-α-D-glucofuranose;Nsc67057;1,2-O-(1-Methylethylidene)-3-O-(phenylMethyl)-α-D-glucofuranose Diacetate
• CAS NO: 18006-25-2
• Molecular Formula: C₂₀H₂₆O₈
• Molecular Weight: 0
• Product Categories: 13C & 2H Sugars;Carbohydrates & Derivatives
• Mol File: 18006-25-2.mol

Chemical Properties

• Boiling Point: 480.2°C at 760 mmHg
• Flash Point: 208°C
• Appearance: /
• Density: 1.25g/cm³
• Vapor Pressure: 2.22E-09mmHg at 25°C
• Refractive Index: 1.533
• CAS DataBase Reference: 3-O-Benzyl-5,6-di-O-acetyl-1,2-O-isopropylidene-a-D-glucofuranose(CAS DataBase Reference)
• NIST Chemistry Reference: 3-O-Benzyl-5,6-di-O-acetyl-1,2-O-isopropylidene-a-D-glucofuranose(18006-25-2)
• EPA Substance Registry System: 3-O-Benzyl-5,6-di-O-acetyl-1,2-O-isopropylidene-a-D-glucofuranose(18006-25-2)

Safety Data

• Hazardous Substances Data: 18006-25-2(Hazardous Substances Data)

Usage

Uses

Used in Organic Synthesis:
3-O-Benzyl-5,6-di-O-acetyl-1,2-O-isopropylidene-a-D-glucofuranose is used as a building block for the synthesis of more complex molecules, leveraging its unique structure to create a variety of chemical entities.
Used in Pharmaceutical Research:
In the pharmaceutical industry, 3-O-Benzyl-5,6-di-O-acetyl-1,2-O-isopropylidene-a-D-glucofuranose is utilized as a protecting group for hydroxyl functional groups in carbohydrate chemistry, facilitating the development of new drug candidates and enhancing the synthesis process.
Used in Chemical Industry:
3-O-Benzyl-5,6-di-O-acetyl-1,2-O-isopropylidene-a-D-glucofuranose is employed in the chemical industry for its versatility in creating diverse applications, contributing to the advancement of chemical processes and products.

InChI:InChI=1/C20H26O8/c1-12(21)23-11-15(25-13(2)22)16-17(24-10-14-8-6-5-7-9-14)18-19(26-16)28-20(3,4)27-18/h5-9,15-19H,10-11H2,1-4H3

Upstream product

• 18685-18-2 3-O-benzyl-1,2-5,6-O-diisopropylidene-α-D-glucofuranose 
• 18549-40-1 1,2-O-isopropylidene-α-D-glucofuranose 
• 22529-61-9 (1R)-1-((3aR,6S,6aR)-6-(benzyloxy)-2,2-dimethyltetrahydrofuro(2,3-d)(1,3)dioxol-5-yl)ethane-1,2-diol 
• 108-24-7 acetic anhydride 
• 582-52-5 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 106221-10-7 Acetic acid (R)-1-((3aR,5R,6S,6aR)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-but-3-enyl ester 
• 106221-02-7 [(Z)-3-((3aR,5R,6S,6aR)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-allyl]-trimethyl-silane 
• 106221-07-2 (R)-1-((3aR,5R,6S,6aR)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-prop-2-en-1-ol 
• 23558-05-6 3-O-benzyl-1,2-O-isopropylidene-1,5-D-xylo-dialdofuranose 
• 50-99-7 D-glucose 
• 100-39-0 benzyl bromide 
• 64656-76-4 Natrium-Verbindung der O¹,O²;O⁵,O⁶-Diisopropyliden-α-D-glucofuranose 

Downstream Products

• 22529-61-9 (1R)-1-((3aR,6S,6aR)-6-(benzyloxy)-2,2-dimethyltetrahydrofuro(2,3-d)(1,3)dioxol-5-yl)ethane-1,2-diol 
• 39798-98-6 O³-benzyl-O¹,O²-isopropylidene-O⁵,O⁶-dimethyl-α-D-glucofuranose 
• 1218918-94-5 acetic acid (1R,2R,3R,4S,5S)-2-acetoxy-1-(5-allyl-3-benzyloxy-4-hydroxy-tetrahydrofuran-2-yl)-ethyl ester 
• 35781-78-3 5,6-anhydro-3-O-benzyl-1,2-O-isopropylidene-α-D-glucofuranose 
• 22331-18-6 O³-benzyl-O¹,O²-isopropylidene-O⁵,O⁶-bis-(toluene-4-sulfonyl)-α-D-glucofuranose 
• 18006-29-6 O⁶-benzoyl-O³-benzyl-O¹,O²-isopropylidene-O⁵-(toluene-4-sulfonyl)-α-D-glucofuranose 
• 22331-19-7 3-O-benzyl-1,2-O-isopropylidene-5,6-di-O-mesyl-α-D-glucofuranose 
• 42926-89-6 1,2-O-isopropylidene-3-O-benzyl-α-D-glucofuranose 
• 781657-62-3 phenyl 2,4,6-tri-O-acetyl-1-thio-α/β-L-idopyranose 
• 781657-65-6 Acetic acid (2R,4aS,7R,8S,8aR)-8-benzyloxy-2-phenyl-6-phenylsulfanyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester 
• 781657-64-5 (2R,4aS,7R,8R,8aR)-8-Benzyloxy-2-phenyl-6-phenylsulfanyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol 
• 781657-63-4 phenyl 3-O-benzyl-1-thio-L-idopyranoside 
• 37776-17-3 5,6-anhydro-3-O-benzyl-1,2-O-isopropylidene-β-L-idofuranose 
• 118711-49-2 1,2,4,6-tetra-O-acetyl-3-O-benzyl-L-idopyranoside 

Relevant articles and documents

SYNTHESIS OF SOME L-IDOSE DERIVATIVES

The synthesis of 3-O-benzyl and 3-O-mesyl-1,2-O-isopropylidene-β-L-idofuranose has been effected on the basis of the intramolecular nucleophilic exchange of a mesyloxy group at C5 in derivatives of 1,2-O-isopropylidene-α-D-glucofuranose.It has

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Two suitable methods for the synthesis of the heparin degradation product 2,5-anyhydro-3-O-(α-L-ido-pyranosyluronate)-D-mannitol hexa O-sulfate are reported. The synthesis pathways start from D-glucose and D-glucosamine.

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