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RARECHEM AL BI 0212 is a chemical compound that is primarily used in various industrial applications. Although the detailed information such as its chemical structure, properties, potential health hazards, or environmental impact is not publicly available, it is important to handle this chemical following appropriate safety guidelines to protect workers and the environment.

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  • 19064-14-3 Structure
  • Basic information

    1. Product Name: RARECHEM AL BI 0212
    2. Synonyms: RARECHEM AL BI 0212;ETHYL 2,6-DIFLUOROBENZOATE;2,6-Difluorobenzoic acid, ethyl ester
    3. CAS NO:19064-14-3
    4. Molecular Formula: C9H8F2O2
    5. Molecular Weight: 186.16
    6. EINECS: 943-621-0
    7. Product Categories: N/A
    8. Mol File: 19064-14-3.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: 228 °C at 760 mmHg
    3. Flash Point: 89.2 °C
    4. Appearance: /
    5. Density: 1.222 g/cm3
    6. Vapor Pressure: 0.075mmHg at 25°C
    7. Refractive Index: 1.472
    8. Storage Temp.: Sealed in dry,Room Temperature
    9. Solubility: N/A
    10. CAS DataBase Reference: RARECHEM AL BI 0212(CAS DataBase Reference)
    11. NIST Chemistry Reference: RARECHEM AL BI 0212(19064-14-3)
    12. EPA Substance Registry System: RARECHEM AL BI 0212(19064-14-3)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 19064-14-3(Hazardous Substances Data)

19064-14-3 Usage

Uses

Since the specific applications of RARECHEM AL BI 0212 are not provided in the materials, it is not possible to list its uses in different industries or as different application types. However, it is important to note that the chemical should be used responsibly, and precautionary information, safe handling, use, storage, and disposal instructions should be available on the product's Material Safety Data Sheet (MSDS), provided by the manufacturer or supplier.

Check Digit Verification of cas no

The CAS Registry Mumber 19064-14-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,9,0,6 and 4 respectively; the second part has 2 digits, 1 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 19064-14:
(7*1)+(6*9)+(5*0)+(4*6)+(3*4)+(2*1)+(1*4)=103
103 % 10 = 3
So 19064-14-3 is a valid CAS Registry Number.
InChI:InChI=1/C9H8F2O2/c1-2-13-9(12)8-6(10)4-3-5-7(8)11/h3-5H,2H2,1H3

19064-14-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name Ethyl 2,6-difluorobenzoate

1.2 Other means of identification

Product number -
Other names ethyl 2,6-difluorobenzoate,ethyl ester

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:19064-14-3 SDS

19064-14-3Relevant articles and documents

Nickel-Catalyzed Esterification of Amides Under Mild Conditions

Li, Jun-Fei,Wang, Yao-Fang,Wu, Yuan-Yuan,Liu, Wen-Jing,Wang, Jun-Wen

, p. 874 - 880 (2019/11/13)

Abstract: The use of ligands to adjust the catalytic activity of the catalyst for esterification of amides is challenge in organic chemistry. In this paper, Nickel(II)-NHC-catalyzed the esterification reaction between N,N-di-Boc amide and alcohols at room temperature have been demonstrated. The imidazolium salt bearing a hydroxyl functionalized side arm showed high effective catalytic activity in the activation of the amide N–C bond in air atmosphere. Graphic Abstract: [Figure not available: see fulltext.].

Noncovalent Interactions in Ir-Catalyzed C-H Activation: L-Shaped Ligand for Para-Selective Borylation of Aromatic Esters

Hoque, Md Emdadul,Bisht, Ranjana,Haldar, Chabush,Chattopadhyay, Buddhadeb

supporting information, p. 7745 - 7748 (2017/06/21)

An efficient strategy for the para-selective borylation of aromatic esters is described. For achieving high para-selectivity, a new catalytic system has been developed modifying the core structure of the bipyridine. It has been proposed that the L-shaped ligand is essential to recognize the functionality of the oxygen atom of the ester carbonyl group via noncovalent interaction, which provides an unprecedented controlling factor for para-selective C-H activation/borylation.

Practical and economic lithiations of functionalized arenes and heteroarenes using Cy2NLi in the presence of Mg, Zn or La halides in a continuous flow

Becker, Matthias R.,Ganiek, Maximilian A.,Knochel, Paul

, p. 6649 - 6653 (2015/10/28)

The economic amide base lithium dicyclohexylamide (Cy2NLi) allows fast and convenient (40 s, 0°C) in situ trapping flow metalations of a broad range of functionalized arenes, heteroarenes and acrylate derivatives in the presence of various meta

Facile preparation of aromatic esters from aromatic bromides with ethyl formate or DMF and molecular iodine via aryllithium

Ushijima, Sousuke,Moriyama, Katsuhiko,Togo, Hideo

experimental part, p. 4701 - 4709 (2012/07/28)

Various aromatic bromides were treated with n-BuLi and subsequently with ethyl formate, followed by the reaction with ethanol and molecular iodine in the presence of K2CO3 to provide the corresponding aromatic ethyl esters in good yields. Moreover, aromatic bromides could be transformed into the corresponding aromatic methyl esters in good yields by the treatment with n-BuLi and subsequently with DMF, followed by the reaction with methanol, molecular iodine, and K2CO3. Some aromatics could be also converted into the corresponding aromatic esters in good yields by the treatment with n-BuLi, and subsequently with ethyl formate or DMF, followed by the reaction with molecular iodine and K2CO3. The present reactions offer a novel route for the transition-metal-free, carbon-monoxide-free, and therefore environmentally benign one-pot conversion of aromatic bromides and aromatics into aromatic esters.

The importance of the ortho effect in the solvolyses of 2,6-difluorobenzoyl chloride

Park, Kyoung-Ho,Kevill, Dennis N.

experimental part, p. 267 - 270 (2012/06/30)

The ortho effect of the chloro substituents in 2,6-dichlorobenzoyl chloride sufficiently hindered attack on the acyl carbon such that an ionization mechanism was observed over the full range of solvents studied. We now compare this behavior with that of 2,6-difluorobenzoyl chloride. The smaller fluoro substituents allow the dominant pathway to be addition-elimination (association-dissociation) in all solvents except those rich in fluoroalcohol, where ionization is dominant. Ranges of operation for both mechanisms had previously been observed for the parent benzoyl chloride but with a wider ionization range than for the 2,6-difluoro derivative. This indicates that, relative to the parent, the electronic destabilizing influence of the fluorines on acyl cation formation outweighs the steric retardation to attack because of the presence of the two ortho-fluorine atoms. An extended (two-term) Grunwald-Winstein equation treatment of the solvolyses of 2,6-difluorobenzoyl chloride is reported. Copyright

Quinoxaline biphenyl angiotensin II inhibitors

-

, (2008/06/13)

Angiotensin II inhibition is exhibited by STR1 wherein: X is --CH2 -- or O; R is hydrogen, alkyl, aryl, cycloalkyl, aralkyl, or cycloalkylalkyl; R1 and R2 are each independently O or absent; R3 is hydrogen, alkyl, alkenyl, alkoxy, cycloalkyl, aryl, aralkyl, cycloalkylalkyl, halo, haloalkyl, or haloalkoxy; R4 is hydrogen, alkyl, alkenyl, alkoxy, aryl, cycloalkyl, aralkyl, cycloalkylalkyl, --R8 --OH, or --R8 CO2 R9 ; and the remaining symbols are as defined in the specification.

Quinoxaline N-oxide containing potent angiotensin II receptor antagonists: Synthesis, biological properties, and structure-activity relationships

Kyoung Soon Kim,Qian,Bird,Dickinson,Moreland,Schaeffer,Waldron,Delaney,Weller,Miller

, p. 2335 - 2342 (2007/10/02)

A series of novel quinoxaline heterocycle containing angiotensin II receptor antagonist analogs were prepared. This heterocycle was coupled to the biphenyl moiety via an oxygen atom linker instead of a carbon atom. Many of these analogs exhibit very poten

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