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2-Methoxyimidazoline is a white powder chemical compound known for its multifunctional properties. It is particularly useful in the field of proteomics, where it serves as a lysine-specific label that enhances the overall sequence coverage obtained in peptide mapping experiments. This is achieved by increasing the ionization efficiencies of lysine-terminated tryptic fragments. Additionally, it acts as a labeling reagent for enhanced protein characterization with mass spectrometry and contains approximately 1% ethyleneurea.

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  • 28118-54-9 Structure
  • Basic information

    1. Product Name: 2-Methoxyimidazoline
    2. Synonyms: 2-METHOXY-4,5-DIHYDRO-1H-IMIDAZOLE;4,5-DIHYDRO-2-METHOXY-1H-IMIDAZOLE;4,5-Dihydro-2-methoxy-1H-imidazole, (Solution in Dichloromethane - Approx. 7%-contains approx. 1% ethyleneurea);2-Methoxy-Imidazoline;4,5-Dihydro-2-methoxy-1H-imidazole, (Solution in Dichloromethane);4,5-Dihydro-2-Methoxy-1H-iMidazole, (30-40% solution in DichloroMethane)
    3. CAS NO:28118-54-9
    4. Molecular Formula: C4H8N2O
    5. Molecular Weight: 100.12
    6. EINECS: N/A
    7. Product Categories: Labeling and Diagnostics Reagents
    8. Mol File: 28118-54-9.mol
  • Chemical Properties

    1. Melting Point: 70-72 °C
    2. Boiling Point: 255.492 °C at 760 mmHg
    3. Flash Point: 108.318 °C
    4. Appearance: White powder
    5. Density: 1.207 g/cm3
    6. Refractive Index: 1.562
    7. Storage Temp.: -20°C Freezer
    8. Solubility: N/A
    9. PKA: 8.53±0.40(Predicted)
    10. CAS DataBase Reference: 2-Methoxyimidazoline(CAS DataBase Reference)
    11. NIST Chemistry Reference: 2-Methoxyimidazoline(28118-54-9)
    12. EPA Substance Registry System: 2-Methoxyimidazoline(28118-54-9)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 28118-54-9(Hazardous Substances Data)

28118-54-9 Usage

Uses

Used in Proteomics Studies:
2-Methoxyimidazoline is used as a lysine-specific label for improving the sequence coverage in peptide mapping experiments. It is particularly beneficial in this application because it increases the ionization efficiencies of lysine-terminated tryptic fragments, leading to more accurate and comprehensive results.
Used in Mass Spectrometry:
2-Methoxyimidazoline is used as a labeling reagent for enhanced protein characterization in mass spectrometry. Its presence allows for better differentiation and identification of proteins, making it a valuable tool in the analysis and study of proteins and their structures.
Used in Pharmaceutical and Chemical Industries:
As a white powder chemical compound, 2-Methoxyimidazoline can also be utilized in various pharmaceutical and chemical applications. Its specific properties and reactivity make it a potential candidate for the development of new drugs, chemical processes, or as an intermediate in the synthesis of other compounds.

Synthesis Reference(s)

Synthetic Communications, 26, p. 3241, 1996 DOI: 10.1080/00397919608004633

Check Digit Verification of cas no

The CAS Registry Mumber 28118-54-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 2,8,1,1 and 8 respectively; the second part has 2 digits, 5 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 28118-54:
(7*2)+(6*8)+(5*1)+(4*1)+(3*8)+(2*5)+(1*4)=109
109 % 10 = 9
So 28118-54-9 is a valid CAS Registry Number.
InChI:InChI=1/C6H7NO3S/c1-5-2-6(4-7-3-5)11(8,9)10/h2-4H,1H3,(H,8,9,10)

28118-54-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name 4,5-Dihydro-2-methoxy-1H-imidazole

1.2 Other means of identification

Product number -
Other names 2-Methoxy-4,5-dihydro-1H-imidazole

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:28118-54-9 SDS

28118-54-9Downstream Products

28118-54-9Relevant articles and documents

Ozonation of thioamide containing heterocycles. A new general and selective procedure for the synthesis of C-2 substituted heteroazole derivatives

Saladino, Raffaele,Crestini, Claudia,Occhionero, Francesca,Nicoletti, Rosario

, p. 3241 - 3251 (2007/10/03)

2-Mercaptoheteroazoles readily react with ozone in the presence of nucleophiles and under mild experimental conditions to form several C-2 substituted heterazoles.

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