37592-20-4Relevant articles and documents
Spreading of benquitrione droplets on superhydrophobic leaves through pillar[5]arene-based host-guest chemistry
Song, Qianqian,Mei, Longcan,Zhang, Xujie,Xu, Pingping,Dhinakaran, Manivannan Kalavathi,Li, Haibing,Yang, Guangfu
, p. 7593 - 7596 (2020)
Spreading of agricultural sprays on plant surfaces is a significant task as it helps decrease pesticide usage and thereby reduces the risk of environmental pollution. Here, we report a method of increasing the spreading of herbicide benquitrione droplets
Annulated oxa-cage frameworks via Claisen rearrangement and ring-closing metathesis
Kotha, Sambasivarao,Cheekatla, Subba Rao,Chaurasia, Usha Nandan
, (2020)
In our quest to design high-density fuels, we report a variety of structurally interesting new annulated oxa-cage frameworks. Here, we investigated a linear synthetic sequence, which relies on reductive C–C bond cleavage and ring-closing metathesis as key
Design and synthesis of novel propellanes by using claisen rearrangement and ring-closing metathesis as the key steps
Kotha, Sambasivarao,Dipak, Mirtunjay Kumar
, p. 4446 - 4450 (2006)
Novel hexacyclic caged compounds are prepared by a combination of Claisen rearrangement and ring-closing metathesis (RCM). Additionally, a Grignard reaction in conjugation with RCM produced intricate hexacyclic caged molecules.
Macroscopic Responsive Liquid Quantum Dots Constructed via Pillar[5]arene-Based Host-Guest Interactions
Ma, Junkai,Shi, Fangdan,Tian, Demei,Li, Haibing
, p. 13805 - 13809 (2016)
Liquid quantum dots (QDs) have been used as a fluorescent films sensor. Constructing a macroscopic, responsive, liquid QD system for lysine (Lys) is a challenging task. To achieve a selective macroscopic response towards Lys, herein we present a new strat
Ring-Closing Metathesis Approach to Cage Propellanes Containing Oxepane and Tetrahydrofuran Hybrid System
Kotha, Sambasivarao,Cheekatla, Subba Rao,Mhatre, Darshan S.
, p. 5339 - 5350 (2017)
The preparation of a variety of structurally interesting oxygenated cage compounds involving atom-economic processes such as Claisen rearrangement, Diels-Alder reaction, [2+2] photocycloaddition, and ring-closing metathesis (RCM) as key steps is reported.
Facile construction of a double network cross-linked luminescent supramolecular elastomer by hydrosilylation and pillar[5]arene host-guest recognition
Feng, Shengyu,Fu, Rong,Liu, Shaojie,Xu, Xing-Dong,Zhang, Junying
, p. 6719 - 6722 (2020)
Reticulated copolymer host pillar[5]arene cross-linked with poly(dimethylsiloxane) (PDMS) was synthesized for the facile construction of a double network cross-linked elastomer upon noncovalently cross-linking with tetraphenyethylene (TPE)-based tetratopi
Palladium-catalyzed anti-Markovnikov oxidative acetalization of activated olefins with iron(iii) sulphate as the reoxidant
Fernandes, Rodney A.,Kumar, Praveen,Yadav, Sandhya S.
, p. 427 - 443 (2022/01/20)
This paper discloses the efficient palladium-catalyzed anti-Markovnikov oxidative acetalization of activated terminal olefins with iron(iii) sulfate as the reoxidant. This methodology requires mild reaction conditions and shows high regioselectivity toward anti-Markovnikov products and compatibility with a wide range of functional groups. Iron(iii) sulphate was the sole reoxidant used in this method. Various olefins like vinylarenes, aryl-allylethers, aryl or benzyl acrylates and homoallylic alcohols all reacted well providing anti-Markovnikov acetals, some of which represent orthogonally functionalized 1,3- and 1,4-dioxygenated compounds.
Nickel-catalyzed deallylation of aryl allyl ethers with hydrosilanes
Ding, Guangni,Fan, Sijie,Wang, Jingyang,Wang, Yu,Wu, Xiaoyu,Xie, Xiaomin,Yang, Liqun,Zhang, Zhaoguo
supporting information, (2021/09/28)
An efficient and mild catalytic deallylation method of aryl allyl ethers is developed, with commercially available Ni(COD)2 as catalyst precursor, simple substituted bipyridine as ligand and air-stable hydrosilanes. The process is compatible with a variety of functional groups and the desired phenol products can be obtained with excellent yields and selectivity. Besides, by detection or isolation of key intermediates, mechanism studies confirm that the deallylation undergoes η3-allylnickel intermediate pathway.
Investigating the microwave-accelerated Claisen rearrangement of allyl aryl ethers: Scope of the catalysts, solvents, temperatures, and substrates
Hui, Zi,Jiang, Songwei,Qi, Xiang,Ye, Xiang-Yang,Xie, Tian
supporting information, (2020/05/18)
The microwave-accelerated Claisen rearrangement of allyl aryl ethers was investigated, in order to gain insight into the scope of the catalysts, solvents, temperatures, and substrates. Among the catalysts examined, phosphomolybdic acid (PMA) was found to greatly accelerate the reaction in NMP, at temperatures ranging from 220 to 300 °C. This method was found to be useful for preparing several intermediates previously reported in the literature using precious metal catalysts such as Au(I), Ag(I), and Pt(II). Additionally, substrates bearing bromo and nitro groups on the aryl portion required careful tailoring of the reaction conditions to avoid complex product profiles.
Enantioselective Construction of Si-Stereogenic Center via Rhodium-Catalyzed Intermolecular Hydrosilylation of Alkene
He, Tao,Liu, Li-Chuan,Ma, Wen-Peng,Li, Bin,Zhang, Qing-Wei,He, Wei
supporting information, p. 17011 - 17015 (2020/11/30)
Catalytic, enantioselective synthesis of stereogenic silicon compounds remains a challenge. Herein, we report a rhodium-catalyzed regio- and enantio-selective intermolecular hydrosilylation of alkene with prochiral dihydrosilane. This new method features a simple catalytic system, mild reaction conditions and a wide functional group tolerance.
