3845-63-4

Basic information

• Product Name: 3,4-dimethylphenyl benzoate
• Synonyms: Benzoic acid, 3,4-dimethylphenyl ester; phenol, 3,4-dimethyl-, benzoate
• CAS NO: 3845-63-4
• Molecular Formula: C₁₅H₁₄O₂
• Molecular Weight: 226.2705
• Mol File: 3845-63-4.mol

Chemical Properties

• Boiling Point: 322.1°C at 760 mmHg
• Flash Point: 132.7°C
• Density: 1.101g/cm³
• Vapor Pressure: 0.000286mmHg at 25°C
• Refractive Index: 1.571
• CAS DataBase Reference: 3,4-dimethylphenyl benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: 3,4-dimethylphenyl benzoate(3845-63-4)
• EPA Substance Registry System: 3,4-dimethylphenyl benzoate(3845-63-4)

Safety Data

• Hazardous Substances Data: 3845-63-4(Hazardous Substances Data)

Usage

Uses

Used in Fragrance Industry:
3,4-dimethylphenyl benzoate is used as a fragrance ingredient for its sweet, floral odor, contributing to the overall scent profile of various consumer products.
Used in Perfume Production:
3,4-dimethylphenyl benzoate is used as a key component in the production of perfumes, enhancing their aromatic properties and creating a pleasant scent experience.
Used in Cosmetics and Personal Care Products:
3,4-dimethylphenyl benzoate is used in cosmetics and personal care products to provide a pleasant fragrance, making the products more appealing to users.
Used in Flavoring Food and Beverages:
3,4-dimethylphenyl benzoate is used as a flavoring agent in food and beverages, imparting a sweet and floral taste to enhance the overall flavor profile.
Used in Solvent Applications:
Due to its solubility in organic solvents, 3,4-dimethylphenyl benzoate can be used in various solvent applications, such as in the formulation of cleaning agents or as a carrier for other chemical compounds.

Upstream product

• 95-65-8 3,4-Dimethylphenol 
• 201230-82-2 carbon monoxide 
• 59-88-1 phenylhydrazine hydrochloride 
• 55499-43-9 3,4-dimethyl phenylboronic acid 
• 65-85-0 benzoic acid 
• 95-47-6 o-xylene 
• 94-36-0 dibenzoyl peroxide 
• 98-88-4 benzoyl chloride 

Downstream Products

• 4072-14-4 (4,5-dimethyl-2-hydroxyphenyl)(phenyl)methanone 
• 78119-71-8 benzoate of α,α,α',α'-tetrabromo-3,4-xylenol 
• 196494-43-6 2-benzoyloxy-4,5-dimethylnitrobenzene 
• 78119-73-0 Benzoic acid 6,7-dicyano-naphthalen-2-yl ester 
• 78119-74-1 Benzoic acid 1,3-dioxo-2-phenyl-2,3-dihydro-1H-benzo[f]isoindol-6-yl ester 
• 6623-41-2 2-amino-4,5-dimethylphenol 
• 18087-10-0 4,5-dimethyl-2-nitrophenol 
• 196494-54-9 3-(2-hydroxy-4,5-dimethylphenylamino)-1,1,4,4-tetramethyltetralin-2-one 
• 78119-81-0 6-Hydroxy-2-phenyl-benzo[f]isoindole-1,3-dione 
• 130200-58-7 7-hydroxynaphthalene-2-carbonitrile 
• 52927-22-7 6-cyano-2-naphthol 

Relevant articles and documents

Palladium-Catalyzed Oxidative Carbonylation of Aryl Hydrazines with CO and O2 at Atmospheric Pressure

Palladium-catalyzed aerobic oxidative aminocarbonylation and alkoxycarbonylation reactions with aryl hydrazines as coupling partners have been developed. The oxidative carbonylation of aryl hydrazines proceeded smoothly at atmospheric pressure CO, employi

Metal-free synthesis of aryl esters by coupling aryl carboxylic acids and aryl boronic acids

A facile synthesis of aryl esters is developed by coupling aryl carboxylic acids and aryl boronic acids in the presence of PhI(OAc)2 and carbonyl diimidazole. A wide range of functional groups were tolerant to the metal-free reaction condition that led to the desired products in good yields.

Visible-light-triggered direct benzoyloxylation of electron-rich arenes at room temperature without chelation assistance

A RuII photocatalytic method was developed for the direct mono-benzoyloxylation of electron-rich aromatic and heteroaromatic systems even with an excess amount of benzoyl peroxide. The reaction was conducted at room temperature under visible light. The direct ArC-H benzoyloxylations occur without the assistance of any directing groups and can also tolerate various functional groups that have already shown diverse reactivities in transition-metal catalysis.

The synthesis of reduced phenoxazines as potential chain-breaking antioxidants

Routes to potential chain-breaking antioxidants, based upon phenoxazines, have been studied and a new synthesis of 1,2,3,4,4a,10a-hexahydro-10H-phenoxazines from trans-2-[N-(2-hydroxyphenyl)amino]cyclohexanols has been developed using a Mitsunobu reaction to form the oxazine ring.

REGIOSELECTIVITY OF COMPLEXATIONS OF SUBSTITUTED PHENYL BENZOATES AND PHENYL PHENYLACETATES WITH Cr(CO)6

Selectivity of complexation of substituted phenyl benzoates is very low.In most cases, comparable yields of both regioisomeric complexes are isolated.Exception is 4-chlorophenyl ester, where benzoic acid moiety is complexed nearly exclusively.Very high regioselectivity of complexation was observed with substituted phenyl phenylacetates.The substituent of substituted phenols has not any effect on the complexation, and only phenylacetic acid moiety is complexed.This observation supports the recently proposed mechanism of the catalytic activity of the esters at arene complexation.