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101-06-4

101-06-4

Identification

Synonyms:Ethanol,2-(dibenzylamino)- (6CI,7CI,8CI);2-(Dibenzylamino)ethanol;2-[Bis(phenylmethyl)amino]ethanol;D Ol;N,N-Dibenzyl-2-aminoethanol;N,N-Dibenzyl-b-aminoethanol;b-(N,N-Dibenzylamino)ethanol;

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Safety information and MSDS view more

  • Signal Word:Danger

  • Hazard Statement:H302 Harmful if swallowedH314 Causes severe skin burns and eye damage H400 Very toxic to aquatic life

  • First-aid measures: General adviceConsult a physician. Show this safety data sheet to the doctor in attendance.If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

  • Fire-fighting measures: Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus for firefighting if necessary.

  • Accidental release measures: Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8. Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Pick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers for disposal.

  • Handling and storage: Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

  • Exposure controls/personal protection:Occupational Exposure limit valuesBiological limit values Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Eye/face protection Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Respiratory protection Wear dust mask when handling large quantities. Thermal hazards

Supplier and reference price view more

  • Manufacture/Brand
  • Product Description
  • Packaging
  • Price
  • Delivery
  • Purchase
  • Manufacture/Brand:TRC
  • Product Description:N,N-Dibenzylethanolamine
  • Packaging:500mg
  • Price:$ 45
  • Delivery:In stock
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  • Manufacture/Brand:TCI Chemical
  • Product Description:N,N-Dibenzyl-2-aminoethanol >98.0%(T)
  • Packaging:500g
  • Price:$ 432
  • Delivery:In stock
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  • Manufacture/Brand:TCI Chemical
  • Product Description:N,N-Dibenzyl-2-aminoethanol >98.0%(T)
  • Packaging:25g
  • Price:$ 88
  • Delivery:In stock
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  • Manufacture/Brand:SynQuest Laboratories
  • Product Description:2-(Dibenzylamino)ethan-1-ol 98%
  • Packaging:25 g
  • Price:$ 114
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  • Manufacture/Brand:Oakwood
  • Product Description:N,N-Dibenzyl-2-aminoethanol
  • Packaging:25g
  • Price:$ 75
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  • Manufacture/Brand:Oakwood
  • Product Description:N,N-Dibenzyl-2-aminoethanol
  • Packaging:5g
  • Price:$ 25
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  • Manufacture/Brand:Oakwood
  • Product Description:N,N-Dibenzyl-2-aminoethanol
  • Packaging:100g
  • Price:$ 210
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  • Manufacture/Brand:Oakwood
  • Product Description:N,N-Dibenzyl-2-aminoethanol
  • Packaging:1g
  • Price:$ 12
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  • Manufacture/Brand:Matrix Scientific
  • Product Description:N,N-Dibenzylethanolamine 95%
  • Packaging:25g
  • Price:$ 103
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  • Manufacture/Brand:Matrix Scientific
  • Product Description:N,N-Dibenzylethanolamine 95%
  • Packaging:100g
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Relevant articles and documentsAll total 39 Articles be found

KOt-Bu-promoted selective ring-opening N-alkylation of 2-oxazolines to access 2-aminoethyl acetates and N-substituted thiazolidinones

Li, Bin,Lin, Qiao,Zhang, Shiling

, p. 492 - 501 (2020)

An efficient and simple KOt-Bu-promoted selective ring-opening N-alkylation of 2-methyl-2-oxazoline or 2-(methylthio)-4,5-dihydrothiazole with benzyl halides under basic conditions is described for the first time. The method provides a convenient and practical pathway for the synthesis of versatile 2-aminoethyl acetates and N-substituted thiazolidinones with good functional group tolerance and selectivity. KOt-Bu not only plays an important role to promote this ring-opening N-alkylation, but also acts as an oxygen donor.

GAS TREATING SOLUTIONS CONTAINING IMIDAZOLE-AMINE COMPOUNDS AND METHODS OF MAKING THE SAME

-

Paragraph 0202, (2021/12/03)

Systems comprising a composition where an imidazole is tethered to an amine and a solvent are described herein. Methods of their preparation and use are also described herein. The methods of using the systems include the reduction of volatile compounds from gas streams and a liquid stream.

Hydrogen-Borrowing Alkylation of 1,2-Amino Alcohols in the Synthesis of Enantioenriched γ-Aminobutyric Acids

Hall, Christopher J. J.,Goundry, William R. F.,Donohoe, Timothy J.

supporting information, p. 6981 - 6985 (2021/03/01)

For the first time we have been able to employ enantiopure 1,2-amino alcohols derived from abundant amino acids in C?C bond-forming hydrogen-borrowing alkylation reactions. These reactions are facilitated by the use of the aryl ketone Ph*COMe. Racemisation of the amine stereocentre during alkylation can be prevented by the use of sub-stoichiometric base and protection of the nitrogen with a sterically hindered triphenylmethane (trityl) or benzyl group. The Ph* and trityl groups are readily cleaved in one pot to give γ-aminobutyric acid (GABA) products as their HCl salts without further purification. Both steps may be performed in sequence without isolation of the hydrogen-borrowing intermediate, removing the need for column chromatography.

Process route upstream and downstream products

Process route

O-acetyl-N,N-dibenzylethanolamine
19520-88-8

O-acetyl-N,N-dibenzylethanolamine

N,N-dibenzyl-2-aminoethanol
101-06-4

N,N-dibenzyl-2-aminoethanol

Conditions
Conditions Yield
With potassium carbonate; In methanol; at 20 ℃; for 24h;
88%
With potassium carbonate; In methanol; for 0.5h; Ambient temperature;
benzyl chloride
100-44-7

benzyl chloride

ethanolamine
141-43-5

ethanolamine

N,N-dibenzyl-2-aminoethanol
101-06-4

N,N-dibenzyl-2-aminoethanol

Conditions
Conditions Yield
With potassium carbonate; In ethanol; for 16h; Heating / reflux;
83%
With potassium carbonate; In ethanol; for 36h; Reflux;
69%
With potassium carbonate; In ethanol; for 36h; Reflux;
69%
ethanolamine; With sodium hydroxide; In methanol; water; for 0.5h; Heating / reflux;
benzyl chloride; In methanol; water; Heating / reflux;
54%
ethanolamine; With sodium hydroxide; In methanol; water; for 0.5h; Heating / reflux;
benzyl chloride; In methanol; water; Heating / reflux;
54%
With triethylamine; In ethanol; for 12h; Reflux;
50%
ethanolamine; With sodium hydroxide; potassium carbonate; In methanol; for 0.5h; Heating;
benzyl chloride; In methanol; for 6h; Heating;
43%
With potassium carbonate; benzene;
With sodium hydroxide; benzene;
With triethylamine; In ethanol; Heating;
With potassium carbonate; benzene;
With potassium carbonate; at 20 ℃; for 12h;
benzyl bromide
100-39-0

benzyl bromide

N-Benzylethanolamine
104-63-2

N-Benzylethanolamine

N,N-dibenzyl-2-aminoethanol
101-06-4

N,N-dibenzyl-2-aminoethanol

Conditions
Conditions Yield
With potassium carbonate; In acetonitrile; at 80 ℃; for 1.5h;
100%
With potassium carbonate; In acetonitrile;
benzyl bromide
100-39-0

benzyl bromide

ethanolamine
141-43-5

ethanolamine

N,N-dibenzyl-2-aminoethanol
101-06-4

N,N-dibenzyl-2-aminoethanol

Conditions
Conditions Yield
With potassium carbonate; In acetone; at 20 ℃; for 12h;
90%
With potassium carbonate; In water; for 3h; Heating;
82%
With tetra-(n-butyl)ammonium iodide; potassium carbonate; In acetonitrile; at 20 ℃; for 20h;
79%
ethanolamine; With caesium carbonate; In N,N-dimethyl-formamide; at 25 ℃; for 0.5h;
benzyl bromide; In N,N-dimethyl-formamide; at 25 ℃; for 24h; chemoselective reaction; Microwave irradiation;
71%
With potassium carbonate; In water; for 5h; Reflux;
50%
With potassium carbonate; In acetone; at 20 - 25 ℃; for 16h;
38%
With sodium carbonate; In dichloromethane; water; for 3h; Heating;
With potassium carbonate; In acetonitrile; at 60 ℃; for 6h;
With potassium carbonate; In acetonitrile; at 60 ℃; for 6h;
With tetra-(n-butyl)ammonium iodide; potassium carbonate; In acetonitrile; at 10 ℃; for 20h;
With potassium carbonate; In acetonitrile; at -10 - 50 ℃; for 8h; Reagent/catalyst; Temperature; Large scale;
1920 g
N,N-dibenzylglycine ethyl ester
77385-90-1

N,N-dibenzylglycine ethyl ester

N,N-dibenzyl-2-aminoethanol
101-06-4

N,N-dibenzyl-2-aminoethanol

Conditions
Conditions Yield
With 15-crown-5; (1-(2-(2,3-diisopropyl-1-methylguanidino)ethyl)-3-mesityl-1,3-dihydro-2H-imidazol-2-ylidene)copper(I) chloride; hydrogen; sodium t-butanolate; In 1,4-dioxane; at 60 ℃; for 24h; Inert atmosphere;
77%
With ethanol; potassium tert-butylate; C39H41FeMnN2O5P(1+)*Br(1-); In tert-butyl alcohol; at 100 ℃; for 22h; enantioselective reaction; Inert atmosphere; Schlenk technique;
63%
N,N-dibenzyl-glycine benzyl ester
141483-49-0

N,N-dibenzyl-glycine benzyl ester

N,N-dibenzyl-2-aminoethanol
101-06-4

N,N-dibenzyl-2-aminoethanol

Conditions
Conditions Yield
With lithium aluminium tetrahydride; In tetrahydrofuran; at 20 ℃; for 3h;
85%
With lithium aluminium tetrahydride; In tetrahydrofuran; for 2h; Yield given; Heating;
With lithium aluminium tetrahydride; In diethyl ether; at 0 ℃; Inert atmosphere;
[1,3]-dioxolan-2-one
96-49-1

[1,3]-dioxolan-2-one

dibenzylamine
103-49-1

dibenzylamine

N,N-dibenzyl-2-aminoethanol
101-06-4

N,N-dibenzyl-2-aminoethanol

Conditions
Conditions Yield
With tetra-(n-butyl)ammonium iodide; at 20 - 140 ℃; for 26h;
83%
benzaldehyde
100-52-7

benzaldehyde

ethanolamine
141-43-5

ethanolamine

N,N-dibenzyl-2-aminoethanol
101-06-4

N,N-dibenzyl-2-aminoethanol

Conditions
Conditions Yield
benzaldehyde; ethanolamine; In 1,2-dichloro-ethane; at 25 ℃; for 0.166667h;
With sodium tris(acetoxy)borohydride; In 1,2-dichloro-ethane; at 25 ℃; for 16h;
With water; sodium carbonate; In 1,2-dichloro-ethane;
83%
With sodium tris(acetoxy)borohydride; In 1,2-dichloro-ethane; at 20 ℃;
dibenzylamine
103-49-1

dibenzylamine

N,N-dibenzyl-2-aminoethanol
101-06-4

N,N-dibenzyl-2-aminoethanol

Conditions
Conditions Yield
With water;
In methanol;
at 130 ℃; for 18h; under 3102.97 Torr; Inert atmosphere; Autoclave; Large scale;
benzyl bromide
100-39-0

benzyl bromide

ethanolamine
141-43-5

ethanolamine

α-(Trimethylsilyl)crotyl chloride

α-(Trimethylsilyl)crotyl chloride

N-benzyl-N-(2-hydroxyethyl)-(E)-1-methyl-3-trimethylsilyl-2-propenylamine

N-benzyl-N-(2-hydroxyethyl)-(E)-1-methyl-3-trimethylsilyl-2-propenylamine

N,N-dibenzyl-2-aminoethanol
101-06-4

N,N-dibenzyl-2-aminoethanol

Conditions
Conditions Yield
With Trimethyl borate; In tert-butyl alcohol; for 36h; Heating;
83%

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