1113-78-6Relevant articles and documents
Hennion et al.
, p. 5190 (1957)
Pd-catalyzed three-component reaction of 3-(Pinacolatoboryl)ally acetates, aldehydes, and organoboranes: A new entry to stereoselective synthesis of (Z)- anti -homoallylic alcohols
Horino, Yoshikazu,Aimono, Ataru,Abe, Hitoshi
supporting information, p. 2824 - 2827 (2015/06/16)
The Pd-catalyzed three-component reaction of 3-(pinacolatoboryl)allyl acetates, aldehydes, and organoboranes is described. The reaction is initiated by the formation of an allylic gem-palladium/boryl intermediate, which then undergoes allylation of aldehydes by allylboronates followed by a coupling reaction of in situ generated (Z)-vinylpalladium acetates with organoboranes to provide the (Z)-anti-homoallylic alcohols with high levels of diastereoselectivity and alkene stereocontrol.
Protic acid behavior of phosphine-triborane(7)
DePoy, Rosemarie E.,Kodama, Goji
, p. 4077 - 4079 (2008/10/08)
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