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1113-78-6

TRI-SEC-BUTYLBORANE is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 1113-78-6 Structure

  • Basic information

    1. Product Name: TRI-SEC-BUTYLBORANE
    2. Synonyms: TRI-SEC-BUTYLBORANE;tri-sec-butylborane,tsbb;Tri-sec-butylborane solution;TRI-SEC-BUTYLBORANE, 1.0M SOLUTION IN TE TRAHYDROFURAN;Tri(1-methylpropyl)borane;Tris(1-methylpropyl)borane;Tris(sec-butyl)borane;Tri-sec-butylboron
    3. CAS NO:1113-78-6
    4. Molecular Formula: C12H27B
    5. Molecular Weight: 182.15
    6. EINECS: 214-209-1
    7. Product Categories: Boranes;Reduction;Synthetic Reagents
    8. Mol File: 1113-78-6.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: 212.1 °C at 760 mmHg
    3. Flash Point: 1 °F
    4. Appearance: Colorless to light yellow transparent liquid
    5. Density: 0.799 g/mL at 25 °C
    6. Vapor Pressure: 0.256mmHg at 25°C
    7. Refractive Index: 1.403
    8. Storage Temp.: N/A
    9. Solubility: N/A
    10. CAS DataBase Reference: TRI-SEC-BUTYLBORANE(CAS DataBase Reference)
    11. NIST Chemistry Reference: TRI-SEC-BUTYLBORANE(1113-78-6)
    12. EPA Substance Registry System: TRI-SEC-BUTYLBORANE(1113-78-6)

  • Safety Data

    1. Hazard Codes: F,Xn,C
    2. Statements: 11-19-22-36/37/38-40-37-34
    3. Safety Statements: 16-26-36/37/39-45
    4. RIDADR: UN 1993 3/PG 2
    5. WGK Germany: 1
    6. RTECS:
    7. HazardClass: 4.2
    8. PackingGroup: I
    9. Hazardous Substances Data: 1113-78-6(Hazardous Substances Data)

1113-78-6 Usage

Chemical Properties

Colorless liquid

Check Digit Verification of cas no

The CAS Registry Mumber 1113-78-6 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,1,1 and 3 respectively; the second part has 2 digits, 7 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 1113-78:
(6*1)+(5*1)+(4*1)+(3*3)+(2*7)+(1*8)=46
46 % 10 = 6
So 1113-78-6 is a valid CAS Registry Number.
InChI:InChI=1/C12H27B/c1-7-10(4)13(11(5)8-2)12(6)9-3/h10-12H,7-9H2,1-6H3

1113-78-6 Well-known Company Product Price

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  • CAS number
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  • Detail

  • Aldrich

  • (178969)  Tri-sec-butylboranesolution  1.0 M in THF

  • 1113-78-6

  • 178969-100ML

  • 1,539.72CNY

  • Detail

1113-78-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name Tris(1-methylpropyl)borane

1.2 Other means of identification

Product number -
Other names tri(butan-2-yl)borane

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1113-78-6 SDS

1113-78-6Relevant articles and documents

Pd-catalyzed three-component reaction of 3-(Pinacolatoboryl)ally acetates, aldehydes, and organoboranes: A new entry to stereoselective synthesis of (Z)- anti -homoallylic alcohols

Horino, Yoshikazu,Aimono, Ataru,Abe, Hitoshi

supporting information, p. 2824 - 2827 (2015/06/16)

The Pd-catalyzed three-component reaction of 3-(pinacolatoboryl)allyl acetates, aldehydes, and organoboranes is described. The reaction is initiated by the formation of an allylic gem-palladium/boryl intermediate, which then undergoes allylation of aldehydes by allylboronates followed by a coupling reaction of in situ generated (Z)-vinylpalladium acetates with organoboranes to provide the (Z)-anti-homoallylic alcohols with high levels of diastereoselectivity and alkene stereocontrol.

Preparation and Properties of, and Reactions with Metal-Containing Heterocycles, LX. - Investigations on the Preparation and Structure of Phosphidomolybdates

Lindner, Ekkehard,Staengle, Michael,Hiller, Wolfgang,Fawzi, Riad

, p. 1421 - 1426 (2007/10/02)

Substitution of CO in HCO (1) = (η5-C5H5)Mo(CO)2> by the secondary phosphanes R2PH results in the formation of the hydrido complexes HPR2H (2a-c) a), C6H11 (b), C6H5 (c)>.Reaction of 2a-c with Li affords the lithium salts LiPR2H> (3a-c) with elimination of H2.Only 3a, c react with n-BuLi to give the phosphidomolybdates Li2PR2> (4a,c).These are also obtained in a straightforward way from 2a, c and n-BuLi.Upon the action of the dihalometal complexes X2 on 4c, the phosphido-bridged heterobimetallic complexes -μ-PR2- = Fe(CO)4 (5c), Ru(CO)4 (6c), (η5-C5H5)CoCO (7c)> are obtained.According to an X-ray structural analysis. 5a crystallizes in the monoclinic space group P21/n with Z = 4.

Preparation of new bis(dialkylamino)phosphine species via reduction of bis(dialkylamino)halophosphines

Snow, Sarah S.,Jiang, De-Xiang,Parry, Robert W.

, p. 1460 - 1463 (2008/10/08)

Four new bis(dialkylamino)phosphine species, (Me2N)2PH, CH3NCH2CH2N(CH3)PH, (CO)3Ni[(Me2N)2PH], and (CO)3Ni-[CH3NCH2CH2N(CH 3)PH], have easily been prepared in good yields through reduction of corresponding bis(dialkylamino)-halophosphines by lithium tri-sec-butylborohydride. The preparation and characterization of these compounds are discussed. An improved synthesis for obtaining quantitative yields of (CO)3NiL [L = Me2NPF2, (Me2N)2PF, CH3NCH2CH2N(CH3)PF] is also described.

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