112-29-8

Basic information

• Product Name: 1-Bromodecane
• Synonyms: 1-Bromodecane ,98%;10-Bromodecane;BroMine decane;1-BroModecane, 98% 500GR;1-BROMODECANE FOR SYNTHESIS 250 ML;ColesevelaM IMpurity (1-BroModecane);BroMinationof n-decane;The broMinationof n-decane
• CAS NO: 112-29-8
• Molecular Formula: C₁₀H₂₁Br
• Molecular Weight: 221.18
• EINECS: 203-955-3
• Product Categories: Bromine Compounds;Alkyl Bromides;Monofunctional & alpha,omega-Bifunctional Alkanes;Monofunctional Alkanes;Alkyl;Building Blocks;Chemical Synthesis;Halogenated Hydrocarbons;Organic Building Blocks;ALKYL BROMIDE
• Mol File: 112-29-8.mol
• Article Data: 32

Chemical Properties

• Melting Point: -29.6 °C
• Boiling Point: 238 °C(lit.)
• Flash Point: 202 °F
• Appearance: Clear colorless to slightly yellow/Liquid
• Density: 1.066 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.0572mmHg at 25°C
• Refractive Index: n20/D 1.456(lit.)
• Storage Temp.: Store below +30°C.
• Water Solubility: SLIGHTLY SOLUBLE
• Stability: Stable. Combustible. Incompatible with strong oxidizing agents, strong bases.
• BRN: 1735227
• CAS DataBase Reference: 1-Bromodecane(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Bromodecane(112-29-8)
• EPA Substance Registry System: 1-Bromodecane(112-29-8)

Safety Data

• Statements: 36/37/38
• Safety Statements: 23-24/25
• RIDADR: 2810
• WGK Germany: 3
• RTECS: HD6850000
• F: 8
• TSCA: Yes
• HazardClass: 6.1
• Hazardous Substances Data: 112-29-8(Hazardous Substances Data)

Usage

Chemical Properties

Colorless to light yellow liqui

Uses

Different sources of media describe the Uses of 112-29-8 differently. You can refer to the following data:
1. 1-Bromodecane is used to produce decanal. It is also used in organic synthesis.
2. 1-Bromodecane was used in the synthesis of ferrocene containing hexacatenar metallomesogen.

General Description

1-Bromodecane participates in alkylation of pentaerythritol and introduces two lipophilic groups in pentaerythritol. It reacts with 1,2-dimethylimidazole to yield 1-decyl-2,3-dimethylimidazolium bromide.

Purification Methods

Shake the it with H2SO4, wash with H2O, dry with K2CO3, and fractionally distil it. [Beilstein 1 IV 470.]

InChI:InChI=1/C10H21Br/c1-2-3-4-5-6-7-8-9-10-11/h2-10H2,1H3

Upstream product

• 112-30-1 1-Decanol 
• 1034-39-5 dibromotriphenylphosphorane 
• 41233-29-8 methanesulfonic acid decyl ester 
• 333-88-0 decyl trifluoroacetate 
• 98750-95-9 (decylselenonyl)benzene 
• 4101-68-2 1,10-dibromodecane 
• 558-13-4 carbon tetrabromide 
• 693-58-3 1-Bromononane 
• 62871-09-4 10-bromodec-1-ene 
• 112-17-4 n-decyl acetate 
• 604-69-3 β-D-glucose pentaacetate 
• 124-18-5 decane 
• 77899-13-9 cis-1-bromo-dec-4-ene 
• 7433-78-5 cis-5-decene 

Downstream Products

• 2534-65-8 N-decyl-pyridinium bromide 
• 63207-02-3 4-decyl-piperazine-1-carboxylic acid ethyl ester 
• 64183-49-9 octadec-7-yne 
• 7387-27-1 decyl-(2,4-dinitro-phenyl)-sulfide 
• 55792-68-2 N-(4-(decyloxy)phenyl)acetamide 
• 22438-39-7 1-(methylthio)decane 
• 13910-18-4 (n-decylthio)benzene 
• 765-03-7 1-dodecyne 
• 101437-89-2 decyl-(2,4-dichloro-phenyl)-ether 
• 2244-07-7 undecanenitrile 
• 124-18-5 decane 
• 10496-18-1 didecyl disulfide 
• 334-56-5 1-fluorodecane 
• 143-10-2 decylthiol 

Relevant articles and documents

Aliphatic bromination with tetrabromomethane on immobilized copper complexes

New catalytic systems with supported bromine- and chlorine-containing copper complexes for selective bromination of alkanes with tetrabromomethane have been proposed. Introduction of donor additives (e.g., low-molecular-weight alcohols) into the reaction increases the activity and stability of these catalysts. The kinetic features of the processes have been investigated. It has been shown that the dependences of the yield of bromodecanes on temperature and concentration of donor additives are both nonmonotonic in character.

Regiodivergent Conversion of Alkenes to Branched or Linear Alkylpyridines

Herein we report a practical protocol for the visible-light-induced regiodivergent radical hydropyridylation of unactivated alkenes using pyridinium salts. This approach provides a unified synthetic platform to control the regioselectivity of the synthesis of linear or branched C4-alkylated pyridines. A remarkable selectivity switch from the anti-Markovnikov to the Markovnikov product can be achieved by the addition of tetrabutylammonium bromide. The versatility of this protocol is further demonstrated based on the late-stage functionalization in pharmaceuticals.

METHOD FOR PRODUCING REDUCED HALIDE COMPOUND HAVING UNDERGONE REDUCTION OF CARBON-CARBON UNSATURATED BOND

A halide compound having one or more carbon-carbon unsaturated bonds is catalytically reduced with substantially no dehalogenation to produce a reduced halide compound in which at least one of the one or more unsaturated bonds is reduced. Specifically provided is a method for producing a reduced halide compound including steps of: reacting a nickel compound, a zinc compound, and a borohydride compound in a solvent to obtain a reduction catalyst; and subjecting a halide compound having one or more carbon-carbon unsaturated bonds to catalytic reduction in the presence of the reduction catalyst to reduce at least one of the one or more carbon-carbon unsaturated bonds to thereby obtain a reduced halide compound.