18024-69-6Relevant articles and documents
Synthesis, structure and gas-phase reactivity of a silver hydride complex [Ag3{(PPh2)2CH2}3(μ 3-H)(μ3-Cl)]BF4
Zavras, Athanasios,Khairallah, George N.,Connell, Timothy U.,White, Jonathan M.,Edwards, Alison J.,Donnelly, Paul S.,O'Hair, Richard A. J.
, p. 8391 - 8394 (2013)
Mass spectrometry shows the way! MS analysis of silver salts treated with sodium borohydride in the presence of a bis(phosphino) ligand revealed the formation of novel silver hydride nanocluster cations instead of all silver nanocluster cations. This serendipitous discovery prompted the condensed-phase synthesis, isolation, and characterization of [Ag3{(Ph 2P)2CH2}3(μ3-H) (μ3-Cl)]BF4×0.5 CHCl3. Copyright