21324-40-3Relevant articles and documents
Highly Dynamic Coordination Behavior of Pn Ligand Complexes towards "naked" Cu+ Cations
Fleischmann, Martin,Welsch, Stefan,Peresypkina, Eugenia V.,Virovets, Alexander V.,Scheer, Manfred
, p. 14332 - 14336 (2015)
Reactions of Cu+ containing the weakly coordinating anion [Al{OC(CF3)3}4]- with the polyphosphorus complexes [{CpMo(CO)2}2(μ,η2:η2-P2)] (A), [CpM(CO)2(η3-P3)] (M=Cr(B1), Mo (B2)), and [CpFe(η5-P5)] (C) are presented. The X-ray structures of the products revealed mononuclear (4) and dinuclear (1, 2, 3) CuI complexes, as well as the one-dimensional coordination polymer (5 a) containing an unprecedented [Cu2(C)3]2+ paddle-wheel building block. All products are readily soluble in CH2Cl2 and exhibit fast dynamic coordination behavior in solution indicated by variable temperature 31P{1H}NMR spectroscopy.
Wizansky, Abigail R.,Rauch, Paul E.,Disalvo, Francis J.
, p. 203 - 207 (1989)
Preparation of lithium hexafluorophosphate from LiF and P in fluorine atmosphere
Kim, Jae-Ho,Nagahara, Kazushi,Yonezawa, Susumu,Takashima, Masayuki
, p. 884 - 885 (2004)
Pure lithium hexafluorophosphate (LiPF6) has been successfully prepared by the reaction between the elemental fluorine and the equi-molar mixture of LiF and P (F2 direct method). The product was pure enough to be used as an electrolyte salt of lithium secondary battery. Especially, the stepwise introducing of fluorine gas into a reaction system was effective to prepare LiPF6 in a high yield. The results of Rietveld refinement of XRD data revealed that the structure of LiPF6 was trigonal (R3, Z = 3, a0 = 0.4932(2), c0 = 1.2641 (5) nm, cell volume; 2.663(2) × 10-28 m3). The cell constants of LiPF6 prepared by the F2 direct method were almost the same as those of LiPF6 prepared by the reaction between LiF and PF5 in a liquid anhydrous hydrogen fluoride (L-AHF method).
METHOD FOR PRODUCING LITHIUM HEXAFLUOROPHOSPHATE ETHER COMPLEX
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Paragraph 0033, (2017/07/13)
PROBLEM TO BE SOLVED: To provide a method for producing a lithium hexafluorophosphate carbonate complex by an efficient and simple method in good yield, which solves the problems and can be applied to an electrolyte and the like. SOLUTION: The problems of the present invention can be solved by the method for producing lithium hexafluorophosphate carbonate complex. SELECTED DRAWING: None COPYRIGHT: (C)2017,JPOandINPIT
METHOD FOR PRODUCING LITHIUM HEXAFLUOROPHOSPHATE ETHER COMPLEX AND LITHIUM HEXAFLUOROPHOSPHATE ETHER COMPLEX
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Paragraph 0033, (2017/02/23)
PROBLEM TO BE SOLVED: To provide a method for producing a lithium hexafluorophosphate carbonate complex that can be directly applied to an electrolyte or the like with good yields using an efficient and simple method. SOLUTION: There is provided a method for producing a lithium hexafluorophosphate ether complex that can easily lead to a lithium hexafluorophosphate carbonate complex which can be directly applied to an electrolyte or the like when a primary component of the electrolyte is a carbonate compound. SELECTED DRAWING: None COPYRIGHT: (C)2016,JPOandINPIT