22731-83-5

Basic information

• Product Name: Sulfoximine,S,S-diphenyl-
• Synonyms: Diphenylsulfoximine; Diphenylsulfoximide; NSC 172172; S,S-Diphenylsulfoximide;S,S-Diphenylsulfoximine
• CAS NO: 22731-83-5
• Molecular Formula: C12H11 N O S
• Molecular Weight: 217.291
• Mol File: 22731-83-5.mol
• Article Data: 42

Chemical Properties

• CAS DataBase Reference: Sulfoximine,S,S-diphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Sulfoximine,S,S-diphenyl-(22731-83-5)
• EPA Substance Registry System: Sulfoximine,S,S-diphenyl-(22731-83-5)

Safety Data

• Hazardous Substances Data: 22731-83-5(Hazardous Substances Data)

Upstream product

• 108-98-5 thiophenol 
• 143885-03-4 isopropyloxy(diphenyl)-λ⁶-sulfanenitrile 
• 143885-02-3 propyloxy(diphenyl)-λ⁶-sulfanenitrile 
• 212077-64-0 neopentyloxy(diphenyl)-λ⁶-sulfanenitrile 
• 67248-39-9 fluoro(diphenyl)-λ⁶-sulfanenitrile 
• 90-04-0 2-methoxy-phenylamine 
• 106-49-0 p-toluidine 
• 106-47-8 4-chloro-aniline 
• 108-42-9 3-chloro-aniline 
• 95-51-2 o-chloroaniline 
• 70975-35-8 S,S-diphenyl-N-chlorosulfoximine 
• 110-83-8 cyclohexene 
• 91378-37-9 S,S-diphenyl-(N-p-tolylfulfinyl)sulfoximine 
• 100-61-8 N-methylaniline 

Downstream Products

• 30035-35-9 C₂₂H₂₄N₂OS 
• 945-51-7 1,1'-sulfinylbisbenzene 
• 56410-24-3 N,N'-bis(p-toluenesulfonyl)hydroxylamine 
• 62419-04-9 bis(4-methylphenylsulfonyl)amino 4-methylbenzenesulfonate 
• 477350-30-4 N-phenyl-S,S-diphenylsulfoximine 
• 1374007-24-5 N-(4-methoxyphenyl)-S,S-diphenylsulfoximine 
• 1584154-66-4 (benzhydrylimino)diphenyl-λ⁶-sulfanone 
• 1608153-05-4 N-(2-pyridinylphenyl)-S,S-diphenylsulfoximine 
• 1638134-00-5 N-(11-undecyl)-S,S-diphenylsulfoximine 
• 1638134-02-7 N-(2-nitrobenzyl)-S,S-diphenylsulfoximine 
• 25827-12-7 N-(N’,N’-diethylamino)-S,S-diphenylsulfoximine 
• 40473-68-5 N-(oxodiphenyl-λ⁶-sulfaneylidene)cyanamide 
• 70355-70-3 N-acetyl-S,S-diphenylsulfoximine 
• 54755-72-5 N-methyl-S,S-diphenylsulfoximine 

Relevant articles and documents

Rhodium(iii)-catalyzed cascade C-H functionalization/annulation of sulfoximines with iodonium ylides for the synthesis of cyclohexanone-1,2-benzothiazines

A highly efficient Rh(iii)-catalyzed cascade C-H activation/annulation of sulfoximines with iodonium ylides under metal-oxidant-free conditions has been reported. The fused cyclohexanone-1,2-benzothiazine scaffold is readily achieved with a one-pot proces

Electrochemical Oxidative Syntheses of NH-Sulfoximines, NH-Sulfonimidamides and Dibenzothiazines via Anodically Generated Hypervalent Iodine Intermediates

Herein, we report a general method for the synthesis of NH-sulfoximines and NH-sulfonimidamides through direct electrochemical oxidative catalysis involving an iodoarene(I)/iodoarene(III) redox couple. In addition, dibenzothiazines can be synthesized from [1,1′-biaryl]-2-sulfides under standard conditions. Notably, only a catalytic amount of iodoarene is required for the generation in situ of an active hypervalent iodine catalyst, which avoids the need for an excess of a hypervalent iodine reagent relative to conventional approaches. Moreover, this protocol features broad substrate scope and wide functional group tolerance, delivering the target compounds with good-to-excellent yields even for a scale of more than 10 g.

Sulfoximines Assisted Rh(III)-Catalyzed C-H Activation/Annulation Cascade to Synthesize Highly Fused Indeno-1,2-benzothiazines

A facile access to highly fused tetracyclic indeno-1,2-benzothiazines has been established via a Rh(III)-catalyzed C-H bond activation and intramolecular annulation cascade between sulfoximides and all-carbon diazo indandiones. This strategy is characterized by the fact that the diazo coupling partners do not require preactivation, along with its high efficiency, broad substrate generality, and facile transformation. Particularly, the highly conjugated tetracyclic products demonstrate good optical properties and can easily enter cells to emit bright fluorescence for live cell imaging.