3704-44-7Relevant articles and documents
METHOD FOR PREPARING AN ORGANO-FUNCTIONAL SILANE
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Paragraph 0028, (2014/05/24)
A process includes reacting an organometallic cuprate and a silicon precursor in the presence of a solvent. The process produces a reaction product including an organo-functional silane.
Photolysis of tris(trimethylsilyl)silane: Trapping of sisyl radicals
Mohamed, Mustafa,Brook, Michael A.
, p. 1357 - 1362 (2007/10/03)
The photolysis of tris(trimethylsilyl)silane (TTMSS) was studied in the absence and in the presence of added trapping agents such as alkenes and alcohols. It was found that, unlike the case with pyrolysis, silyl radicals rather than silylenes are produced
Pulse Technique Pyrolysis of some Arylsilanes and Their Thermal Reactions with Aliphatic and Aromatic Alcohols Over Ni-Y-Zeolite
Ramadan, N. A.,Abo-Elenin, O. M.,Badawi, A. M.
, p. 27 - 36 (2007/10/02)
p-Tolyltrimethylsilane and phenyltrimethylsilane were subjected in the gas phase to pyrolysis and thermolysis reactions with alcohols and phenols at different temperatures over Ni Y-zeolite using a pulse catalytic technique.The obtained alkoxy- and phenoxy-trimethylsilanes with other side products were identified by gas liquid chromatographic analysis.The yield in each case varied with the reaction temperature.The highest yield was obtained at 250 deg C.The different pathways of these thermolysis reactions are discussed and the results are assigned.