5936-98-1

Basic information

• Product Name: (TRICHLOROMETHYL)TRIMETHYLSILANE
• Synonyms: (TRICHLOROMETHYL)TRIMETHYLSILANE;Trimethyl(trichloromethyl)silane;Silane, trimethyl(trichloromethyl)-;(Trichloromethyl)trimethylsilane, (Trimethylsilyl)trichloromethane;(Trimethylsilyl)trichloromethane
• CAS NO: 5936-98-1
• Molecular Formula: C₄H₉Cl₃Si
• Molecular Weight: 191.56
• Mol File: 5936-98-1.mol
• Article Data: 5

Chemical Properties

• Melting Point: 129-132°C
• Boiling Point: 146-156 °C(Press: 749 Torr)
• Appearance: /
• Density: 1.164±0.06 g/cm3(Predicted)
• Storage Temp.: 2-8°C
• CAS DataBase Reference: (TRICHLOROMETHYL)TRIMETHYLSILANE(CAS DataBase Reference)
• NIST Chemistry Reference: (TRICHLOROMETHYL)TRIMETHYLSILANE(5936-98-1)
• EPA Substance Registry System: (TRICHLOROMETHYL)TRIMETHYLSILANE(5936-98-1)

Safety Data

• Safety Statements: 22-24/25
• Hazardous Substances Data: 5936-98-1(Hazardous Substances Data)

Usage

Purification Methods

It distils at atmospheric pressure without decomposition and readily sublimes at 70o/10mm. It has one peak in the 1H NMR spectrum (CH2Cl2) : 0.38. [Speier J Am Chem Soc 73 824 1951, Hergott & Simchen Synthesis 626 1980, Beilstein 4 IV 3892.]

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 67-66-3 chloroform 
• 7782-50-5 chlorine 
• 2344-80-1 Chloromethyltrimethylsilane 
• 56-23-5 tetrachloromethane 
• 75-07-0 acetaldehyde 
• 100-52-7 benzaldehyde 

Downstream Products

• 85695-26-7 [2,2,2-trichloro-1-(4-trimethylsiloxyphenyl)ethoxy]trimethylsilane 
• 358720-84-0 trimethyl(1,1,1-trichloro-4-phenylbutan-2-yloxy)silane 
• 351536-12-4 [(E)-1,1,1-trichloro-4-phenylbut-3-en-2-yloxy]trimethylsilane 
• 90347-44-7 1,1,1-trichloro-2-phenylpropan-2-ol 
• 54034-90-1 1,1,1-trichloro-2-phenyl-2-(trimethylsiloxy)ethane 
• 54034-89-8 [2,2,2-trichloro-1-(4-methoxyphenyl)ethoxy]trimethylsilane 
• 325810-04-6 Au(CCl₃)(P(C₆H₁₁)3) 
• 72800-48-7 1,1,1-trichloro-4-methyl-3-penten-2-ol 
• 67246-11-1 (1’,1’,1’-trichloro-3’-nitropropan-2’-yl)benzene 

Relevant articles and documents

POLYMETHYLATION OF ORGANOCHLOROSILANES

Polychloromethylation of Me3SiCl, Me2PhSiCl, Me2SiCl2, and MePhSiCl2 in the system magnesium-chloroform-THF has been studies under mild conditions (in the temperature renge 60 -65 deg C), and a scheme of formation of the main and by-products has been proposed.

BINARY TRIAMIDOPHOSPHITE-HALOFORM SYSTEM AS A NEW SOURCE OF TRIHALOMETHANIDE IONS

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EINTOPFSYNTHESE TRICHLOROMETHYLSUBSTITUIERTER ALKOHOLE

A new one-pot synthesis of alcohols RCH(OH)CCl3 starting from CCl4, Me3SiCl, Mg and aldehydes RCHO is described.