636-13-5

Basic information

• Product Name: MANGANESE BENZOATE
• Synonyms: MANGANESE(II) BENZOATE TETRAHYDRATE;MANGANESE BENZOATE;benzoicacid,manganese(2++)salt;manganese dibenzoate;Bisbenzoic acid manganese(II) salt;Dibenzoic acid manganese(II) salt;Manganese Benzoate Tetrahydrate
• CAS NO: 636-13-5
• Molecular Formula: C₁₄H₁₀MnO₄
• Molecular Weight: 297.16
• EINECS: 211-251-2
• Mol File: 636-13-5.mol
• Article Data: 7

Chemical Properties

• Melting Point: 216 °C
• Appearance: /
• CAS DataBase Reference: MANGANESE BENZOATE(CAS DataBase Reference)
• NIST Chemistry Reference: MANGANESE BENZOATE(636-13-5)
• EPA Substance Registry System: MANGANESE BENZOATE(636-13-5)

Safety Data

• Hazardous Substances Data: 636-13-5(Hazardous Substances Data)

Usage

Description

Manganese benzoate is a chemical compound consisting of manganese and benzoate ions, known for its high thermal stability and low solubility in water. It is commonly utilized in various industries due to its unique properties.
Used in Organic Synthesis:
Manganese benzoate is used as a catalyst in organic synthesis for facilitating chemical reactions, enhancing the efficiency and selectivity of the processes.
Used in Porcelain and Ceramics Industry:
Manganese benzoate is used as a coloring agent in porcelain and ceramics, providing a stable and vibrant coloration to these materials.
Used in Pharmaceutical Industry:
Manganese benzoate is studied for its potential applications in pharmaceuticals, particularly in cancer treatment, due to its possible anticancer properties.
Used in Antioxidant Formulations:
Manganese benzoate is considered for use as an antioxidant, which can help prevent oxidative damage in various applications.
Used in Plastics Production:
Manganese benzoate is used in the production of plastics, contributing to the development of materials with improved properties.
Used in Textile Industry:
Manganese benzoate is utilized in the textile industry, where it can enhance the colorfastness and quality of fabrics.
Used in Rubber Industry:
Manganese benzoate is employed in the production of rubber, where it can improve the durability and performance of rubber products.

InChI:InChI=1/2C7H6O2.Mn.4H2O/c2*8-7(9)6-4-2-1-3-5-6;;;;;/h2*1-5H,(H,8,9);;4*1H2/q;;+2;;;;/p-2

Upstream product

• 532-32-1 sodium benzoate 
• 638-38-0 manganese(II) acetate 
• 65-85-0 benzoic acid 
• 16397-91-4 manganese(II) 
• 93-58-3 benzoic acid methyl ester 
• 7439-96-5 manganese 
• 7553-56-2 iodine 
• 75-05-8 acetonitrile 

Downstream Products

• 1313-13-9 manganese(IV) oxide 
• 92-53-5 4-Phenylmorpholine 

Relevant articles and documents

Trinuclear Complexes Derived from R/S Schiff Bases – Chiral Single-Molecule Magnets

The employment of enantiomerically pure Schiff bases in manganese chemistry is revealed to be an excellent method to obtain chiral single-molecule magnets and has allowed the characterization of several pairs of enantiomers, for which the magnetic properties were investigated. The reported systems consist of MnIII–MnII–MnIIIlinear trimers or MnIII3cations in a triangular arrangement including the first example of a μ3-Cl bridge in an isolated manganese triangle.

Synthesis, crystal structure and magnetic properties of two coordination polymers with 4-(4-carboxyphenyl)-4,2′:6′,4″-terpyridine ligand

MnII and CoII salts reacting with 4-(4-carboxyphenyl)-4,2′:6′,4″-terpyridine (4-Hcptpy) in DMF/H2O afford two complexes, [Mn(4-cptpy)(DMF)(H2O) 2]n·n(4-cptpy)·nDMF (1) and [Co(4-cptpy)2(H2O)2]n (2). Complex 1 is a 1D ribbon coordination polymer assembled by Mn2 dimer and tridentate 4-cptpy ligand. The guest 4-cptpy anion is embedded in 3D supramolecular architecture with strong hydrogen bonds. Complex 2 is a 1D linear chain coordination polymer with quadrangled pores. The complex 1 releases H2O and DMF in 87-150 C, and the anhydrous [Mn(4-cptpy)] n·n(4-cptpy) remains thermally stable until 403 C. Variable temperature magnetic susceptibility study in 2-300 K proves that a weak antiferromagnetic interaction exists in the (μ-O2CR) 2Mn2 core.

Manganese clusters derived from 2-pyridylcyanoxime: New topologies and a large spin ground state in pyridyloximate chemistry

Series of manganese clusters derived from 2-pyridylcyanoxime with Mn 3II (1), Mn4II (2a, b), Mn II4MnIII4 (3), MnII 2MnIII6MnIV2 (4) and MnII3MnIII6MnIV (5) cores have been characterized. Dc magnetic measurements reveal antiferromagnetic coupling for 1-4 and dominant ferromagnetic interactions for 5 which shows the largest ground state reported to date in pyridyloximate chemistry (S = 14).