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 Boyle's law
  • Boyle's law
  • Boyle's law is one of many gas laws and a special case of the ideal gas law. Boyle's law describes the inversely proportional relationship between the absolute pressure and volume of a gas, if the temperature is kept constant within a closed system. The law was named after chemist and physicist Robert Boyle, who published the original law in 1662.

    The mathematical equation for Boyle's law is: 

    where: p denotes the pressure of the system. V denotes the volume of the gas. k is a constant value representative of the pressure and volume of the system.

    So long as temperature remains constant the same amount of energy given to the system persists throughout its operation and therefore, theoretically, the value of k will remain constant. However, due to the derivation of pressure as perpendicular applied force and the probabilistic likelihood of collisions with other particles through collision theory, the application of force to a surface may not be infinitely constant for such values of k.

    Forcing the volume V of the fixed quantity of gas to increase, keeping the gas at the initially measured temperature, the pressure p must decrease proportionally. Conversely, reducing the volume of the gas increases the pressure.

    Boyle's law is used to predict the result of introducing a change, in volume and pressure only, to the initial state of a fixed quantity of gas. The before and after volumes and pressures of the fixed amount of gas, where the before and after temperatures are the same (heating or cooling will be required to meet this condition), are related by the equation:

    Boyle's law, Charles's law, and Gay-Lussac's law form the combined gas law. The three gas laws in combination with Avogadro's law can be generalized by the ideal gas law.


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