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 Reducing agent
  • Reducing agent
  • A reducing agent (also called a reductant or reducer) is the element or compound in a reduction-oxidation (redox) reaction that donates an electron to another species; however, since the reducer loses an electron we say it is "oxidized". This means that there must be an "oxidizer"; because if any chemical is an electron donor (reducer), another must be an electron recipient (oxidizer). Thus reducers are "oxidized" and oxidizers are "reduced". The reducing agent in this reaction is ferrocyanide ([Fe(CN)6]4−). It donates an electron, becoming oxidized to ferricyanide ([Fe(CN)6]3−), simultaneously the oxidizer chlorine is reduced to chloride.

    2 [Fe(CN)6]4- + Cl2 → 2 [Fe(CN)6]3- + 2 Cl-

    Common reducing agents

    aluminium hydride (LiAlH4)
    Nascent
    amalgam
    (NaBH4)
    Compounds containing the Sn2+ ion, such as tin(II) chloride
    Sulfite compounds
    (Wolff-Kishner reduction)
    -mercury amalgam (Zn(Hg)) (Clemmensen reduction)
    Diisobutylaluminum hydride (DIBAH)
    Lindlar catalyst
    (C2H2O4)
    (HCOOH)

    Phosphites, hypophosphites and
    () – used in biochemistry labs to avoid S-S bonds
    Compounds containing the Fe2+ ion, such as iron(II) sulfate

    Several common reducing agents and their products

    Agent Product
    Hydrogen H+, H2O
    Metals metal ions
    CO2 carbon dioxide  
    Hydrocarbons CO2 carbon dioxide, H2O


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