- Tebbe Olefination
-
Tebbe Olefination (Methylenation)
F. N. Tebbe et al., J. Am. Chem. Soc. 100, 3611 (1978); S. H. Pine et al., ibid. 102, 3270 (1980).
Exchange of the oxygen atom of a carbonyl function for the methylene group of the proposed titanium carbene complex (the Tebbe reagent) to yield terminal alkenes:
Comparative study with Wittig reaction, q.v.: S. H. Pines et al., Synthesis 1991, 165. Reviews: K. A. Brown-Wensley et al., Pure Appl. Chem. 55, 1733-1744 (1983); S. E. Kelly, Comp. Org. Syn. 1, 743-746 (1991); S. H. Pines, Org. React. 43, 1-91 (1993). Cf. Peterson Reaction.
Prev: Meyer Reaction
Next: Merrifield Solid-Phase Peptide Synthesis - 【Back】【Close 】【Print】【Add to favorite 】
- Related information
-
Health and Chemical more >
-
Hot Products
- 45457-73-6 Piperidinium, 1-methylene-
- 103-49-1 Dibenzylamine
- 124172-53-8 Formamide, N,N-1,6-hexanediylbisN-(2,2,6,6-tetramethyl-4-piperidinyl)-
- 4719-04-4 Hexahydro-1,3,5-tris(hydroxyethyl)-s-triazine
- 103041-38-9 Ethyl 3-(pyridin-2-ylamino)propanoate
- 63316-33-6 dipotassium 3,3'-sulphonylbis(benzenesulphonate)
- 90462-19-4 Cellulose, 6-carboxy, acetate butanoate
- 79455-30-4 Nicaraven
- 68583-75-5 2,5-Furandione, dihydro-, polybutenyl derivs., reaction products with tetraethylenepentamine
- 626223-27-6 2,5-Di-tert-butylpyrazolo[1,5-a]pyrimidin-7-amine
- 657-27-2 L-Lysine hydrochloride
- 1445-45-0 Trimethyl orthoacetate