- Pechmann Condensation
-
Pechmann Condensation
H. v. Pechmann, C. Duisberg, Ber. 16, 2119 (1883).
Synthesis of coumarins by condensation of phenols with β-keto esters in the presence of Lewis acid catalysts:
Early reviews: S. Sethna, Chem. Rev. 36, 10 (1945); S. Sethna, R. Phadke, Org. React. 7, 1 (1953). T. Kappe, E. Ziegler, Org. Prep. Proced. 1, 61 (1969); T. Kappe, C. Mayer, Synthesis 1981, 524; A. G. Osborne, Tetrahedron 37, 2021 (1981); D. H. Hau et al., Synlett. 1990, 233; T-S. Li et al., J. Chem. Res. 1998, 39. Modified conditions: J. E. T. Corrie, J. Chem. Soc. Perkin Trans. I 1990, 2151; D. H. Hua et al., J. Org. Chem. 57, 399 (1992). Cf. Bischler-Napieralski Reaction; Simonis Chromone Cyclization.
Prev: Pechmann Pyrazole Synthesis
Next: Payne Rearrangement - 【Back】【Close 】【Print】【Add to favorite 】
- Related information
- Acyloin Condensation by Thiazolium Ion Catalysis: Production of 5-Hydroxy-4-octanone
- Thorpe Reaction
- Stobbe Condensation
- Pechmann Pyrazole Synthesis
- Guareschi-Thorpe Condensation
- Erlenmeyer-Plöchl Azlactone and Amino Acid Synthesis
- Emmert Reaction
- Knoevenagel Condensation
- Claisen-Schmidt Condensation
- Darzens Condensation
-
Health and Chemical more >
-
Hot Products
- 25189-83-7 POLYVINYLCAPROLACTAM
- 67892-27-7 Thermomyces verrucosus
- 16038-76-9 lead phosphite
- 3100-04-7 1-Methylcyclopropene
- 7550-45-0 Titanium(IV) chloride
- 67314-98-1 (7aS,12aS)-3,3-Dimethyl-3H,7H-benzofuro[3,2-c]pyrano[3,2-g][1]benzopyran-7a,10(12aH)-diol
- 314036-11-8 2-[(1,1-Dioxo-1,2-benzothiazol-3-yl)amino]phenol
- 1304-56-9 Beryllium oxide
- 338414-92-9 1-(cyclopropylcarbonyl)-9b-phenyl-1,2,3,9b-tetrahydro-5H-imidazo[2,1-a]isoindol-5-one
- 3483-12-3 DL-1,4-Dithiothreitol
- 146340-15-0 Alcohols, C12-14-secondary, .beta.-(2-hydroxyethoxy), ethoxylated
- 14548-60-8 (benzyloxy)methanol