- Retropinacol Rearrangement
-
Retropinacol Rearrangement
N. Zelinsky, J. Zelikow, Ber. 34, 3249 (1901).
Conversion of an alcohol to the rearranged olefin on treatment with acid:
Application to sterols: W. F. Johns, J. Org. Chem. 26, 4583 (1961); L. M. Harrison, P. V. Fennessey, J. Steroid. Biochem. 36, 407 (1990); to cyclohexanols: W. Hueckel, S. K. Gupte, Ann. 685, 105 (1965). In conjunction with ring expansion: T. Kimura et al., J. Org. Chem. 43, 1247 (1978). Cf. Nametkin Rearrangement; Wagner-Meerwein Rearrangement.
Prev: Reverdin Reaction
Next: Retro-Diels-Alder Reaction - 【Back】【Close 】【Print】【Add to favorite 】
-
Health and Chemical more >
-
Hot Products
- 87862-25-7 3-IODOBENZYL-GUANIDINE HEMISULFATE
- 76778-22-8 GBR 12935 dihydrochloride
- 104810-48-2 Tinuvin-1130
- 69056-38-8 4(3H)-Pteridinone,2-amino-6-[(1R,2S)-1,2-dihydroxypropyl]-5,6,7,8-tetrahydro-, hydrochloride(1:2), (6R)-
- 85888-37-5 Hexanediamide,N1,N6-di-(9Z)-9-octadecen-1-yl-
- 400073-95-2 methyl 4-[2-(4-chlorophenyl)acetyl]-1H-pyrrole-2-carboxylate
- 100-10-7 4-Dimethylaminobenzaldehyde
- 6552-57-4 ETHYLENE-D4 OXIDE
- 7735-57-1 2-Oxobenzo[d][1,3]oxathiol-5-yl benzoate
- 1187944-95-1 3,3'-Biindolizine, 1,1'-bis(4-methylphenyl)-
- 54959-35-2 potassium [[N,N'-ethylenebis[N-(carboxymethyl)glycinato]](4-)-N,N',O,O',ON,ON']ferrate(1-)
- 91526-18-0 1,3-Dioxol-2-one, 4-(hydroxymethyl)-5-methyl-