Phenyldichlorophosphine (CAS NO.: ), with other names as Phosphonous dichloride, phenyl-, could be produced through the following synthetic routes.

In an all-glass apparatus consisting of a 1-l. three-necked flask equipped with a long-stem thermometer, a rubber-sealed mechanical stirrer, and a suitable condenser are placed 165 g. (1.2 moles) of phosphorus trichloride, 23.4 g. (0.3 mole) of benzene, and 53 g. (0.4 mole) of anhydrous aluminum chloride. The mixture is stirred continuously and heated. As the temperature increases, the mixture becomes a homogeneous yellow solution and begins to reflux. After 2 hours, the reaction mixture is heated under reflux as vigorously as possible. At the end of the third hour, the evolution of hydrogen chloride has almost ceased. The heat source is removed, and, while the mixture is still hot, 62 g. (0.4 mole) of phosphorus oxychloride is added gradually from a dropping funnel. The granular precipitate of aluminum chloride-phosphorus oxychloride complex settles rapidly. After the apparatus is disassembled, 6–8 petroleum ether extractions of 100 ml. each are performed to remove phenyldichlorophosphine and the unreacted starting materials from the reaction flask. The residue is transferred to a Büchner funnel and washed with several small portions of petroleum ether, and the combined extracts and washings are concentrated under reduced pressure. Crude phenyldichlorophosphine is removed by distilling to dryness under reduced pressure and is purified by fractionating through a satisfactory column. The product distils at 68–70°/1 mm. (90–92°/10 mm.), n²⁵D 1.5962, and weighs 38.5–42 g. (72–78%).