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Cupric hydroxide

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Name

Cupric hydroxide

EINECS 243-815-9
CAS No. 20427-59-2 Density 3.37 g/cm3
PSA 40.46000 LogP -0.35610
Solubility N/A Melting Point 160oC
Formula Cu.(OH)2 Boiling Point 100 °C at 760 mmHg
Molecular Weight 97.5607 Flash Point N/A
Transport Information UN 3262 Appearance Blue powder
Safety 26-36 Risk Codes 22-37/38-41
Molecular Structure Molecular Structure of 20427-59-2 (Copper(II) hydroxide) Hazard Symbols HarmfulXn
Synonyms

Bactecide;Blue Shield;Blue Shield DF;Champ;Champ DP;Champ Dry Prill;Champ FormulaII;Champion 50 WP;Comac Parasol;Copper dihydroxide;Copperhydroxide;Copper(2+) hydroxide;Copper(II) hydroxide;Copper(II) hydroxide(Cu(OH)2);Cupravit Blue;Cupravit blau;Cupric hydroxide(Cu(OH)2);Cuzin;Funguran OH;GX 306062E;KOP Hydroxide;KOP Hydroxide WP;Kocide;Kocide 101;Kocide 101PM;Kocide 2000;Kocide 3000;Kocide Bordeaux;Kocide DF;Kocide LF;Kocide SD;Kuprablau;Nu-Cop;SPU 02310F0OD;SPU 02540F;SPU 02690F;Spin Out FP;Wetcol;

Article Data 428

Cupric hydroxide History

Copper(II) hydroxide has been known since copper smelting began around 5000 BCE although the alchemists were probably the first to manufacture it. This was easily done by mixing solutions of lye and blue vitriol, both chemicals which were known in antiquity.
It was produced on an industrial scale during the 17th and 18th centuries for use in pigments such as blue verditer and Bremen green. These pigments were used in ceramics and painting.

Cupric hydroxide Consensus Reports

Copper and its compounds are on the Community Right-To-Know List. Reported in EPA TSCA Inventory.

Cupric hydroxide Standards and Recommendations

ACGIH TLV: TWA (fume) 0.2 mg/m3; (dust, mist) 1 mg(Cu)/m3

Cupric hydroxide Specification

The Copper hydroxide is an organic compound with the formula Cu.(OH)2. The IUPAC name of this chemical is copper dihydroxide. With the CAS registry number 20427-59-2, it is also named as Kupfer(2+)dihydroxid. The product's category is Inorganics. Besides, it is a blue powder, which should be stored at temperature of 0 - 6 °C. It is used as raw material of copper, mordant, rayon, paint, and also used as a fungicide and anti-fouling paint composition.

Physical properties about Copper hydroxide are: (1)ACD/LogP: -1.38; (2)ACD/LogD (pH 5.5): -1.38; (3)ACD/LogD (pH 7.4): -1.38; (4)ACD/BCF (pH 5.5): 1; (5)ACD/BCF (pH 7.4): 1; (6)#H bond acceptors: 1; (7)#H bond donors: 2; (8)Polar Surface Area: 20.23 Å2; (9)Enthalpy of Vaporization: 40.65 kJ/mol; (10)Boiling Point: 100 °C at 760 mmHg; (11)Vapour Pressure: 24.5 mmHg at 25°C.

Preparation: this chemical can be prepared by Copper sulfate and sodium hydroxide. Chemical reaction equation is as follows:
CuSO4+2NaOH→Cu(OH)2+Na2SO4

When you are using this chemical, please be cautious about it as the following:
It is harmful if swallowed and risk of serious damage to eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Besides, this chemical is irritating to respiratory system and skin. When you are using it, wear suitable suitable protective clothing.

You can still convert the following datas into molecular structure:
(1)SMILES: [Cu+2].[OH-].[OH-]
(2)InChI: InChI=1/Cu.2H2O/h;2*1H2/q+2;;/p-2
(3)InChIKey: JJLJMEJHUUYSSY-NUQVWONBAH
(4)Std. InChI: InChI=1S/Cu.2H2O/h;2*1H2/q+2;;/p-2
(5)Std. InChIKey: JJLJMEJHUUYSSY-UHFFFAOYSA-L

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
duck LD50 oral > 5gm/kg (5000mg/kg)   Pesticide Manual. Vol. 9, Pg. 184, 1991.
mammal (species unspecified) LC50 inhalation > 2gm/m3 (2000mg/m3)   Pesticide Manual. Vol. 9, Pg. 184, 1991.
quail LD50 oral 3400mg/kg (3400mg/kg)   Pesticide Manual. Vol. 9, Pg. 184, 1991.
rabbit LD50 skin > 3160mg/kg (3160mg/kg)   Pesticide Manual. Vol. 9, Pg. 184, 1991.
rat LD50 oral 1gm/kg (1000mg/kg)   Farm Chemicals Handbook. Vol. -, Pg. C81, 1991.

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