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Diacetylene

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Name

Diacetylene

EINECS 207-303-9
CAS No. 460-12-8 Density 0.806g/cm3
PSA 0.00000 LogP 0.25280
Solubility 1g/L(25 oC) Melting Point -35.99°C
Formula C4H2 Boiling Point 10.3°Cat760mmHg
Molecular Weight 50.0599 Flash Point °C
Transport Information N/A Appearance gas
Safety A dangerous explosive. Polymerizes violently above 0°C. Arsenic pentafluoride catalyzes explosive polymerization. Reaction with silver nitrate forms a very explosive friction-sensitive product. When heated to decomposition it emits acrid smoke and fumes. Risk Codes N/A
Molecular Structure Molecular Structure of 460-12-8 (Diacetylene) Hazard Symbols N/A
Synonyms

Butadiyne(8CI); Biacetylene; Biethynyl; Diacetylene

Article Data 138

Diacetylene Synthetic route

821-10-3

1,4-Dichloro-2-butyne

460-12-8

Butadiyne

Conditions
ConditionsYield
With potassium hydroxide In dimethyl sulfoxide at 70 - 75℃; into -78 deg C cooling trap;93%
With potassium hydroxide In tetrahydrofuran; water; dimethyl sulfoxide at 95℃; for 0.25h;90%
With potassium hydroxide Dehydrochlorination;50%
65032-27-1

ethynylmagnesium chloride

460-12-8

Butadiyne

Conditions
ConditionsYield
With 1,2-dichloro-ethane; manganese(ll) chloride In tetrahydrofuran at 25℃; for 12h; Inert atmosphere;67.5%
584-12-3

2-bromofuran

A

460-12-8

Butadiyne

B

74-86-2

acetylene

Conditions
ConditionsYield
Zersetzung durch Ultraschall;
5929-72-6

2,7-dimethyl-octa-3,5-diyne-2,7-diol

A

460-12-8

Butadiyne

B

67-64-1

acetone

Conditions
ConditionsYield
With calcium hydroxide at 125 - 130℃;
With barium dihydroxide at 125 - 130℃;
With potassium carbonate at 125 - 130℃;
513-35-9

2-methyl-but-2-ene

460-12-8

Butadiyne

Conditions
ConditionsYield
bei der Einw. dunkler elektrischer Entladungen;
101-84-8

diphenylether

A

460-12-8

Butadiyne

B

74-85-1

ethene

Conditions
ConditionsYield
at 970 - 1170℃; Pyrolysis;
34557-54-5

methane

460-12-8

Butadiyne

Conditions
ConditionsYield
bei der Funkenentladung;
74-84-0

ethane

460-12-8

Butadiyne

Conditions
ConditionsYield
bei der pyrogenen Spaltung im Lichtbogen;
1529-68-6

1,2,3,4-tetrabromobutane

460-12-8

Butadiyne

Conditions
ConditionsYield
With potassium hydroxide
36678-47-4

1,2-dibromo-buta-1,3-diene

460-12-8

Butadiyne

Conditions
ConditionsYield
With potassium hydroxide

Diacetylene Chemical Properties

IUPAC Name: Buta-1,3-diyne
The MF of Diacetylene (CAS NO.460-12-8) is C4H2.

                           
The MW of Diacetylene (CAS NO.460-12-8) is 50.05868.
Synonyms of Diacetylene (CAS NO.460-12-8): 1,3-Butadiin ; 1,3-Butadiyne ; Biacetylene ; Biethynyl ; Butadiyne
Stability: Stability Highly flammable
Index of Refraction: 1.436
Boiling Point: 10.3 °C
Melting Point: -10 °C  
Density: 0.806 g/ml  
Appearance: gas
EINECS: 207-303-9

Diacetylene Uses

  Diacetylene (CAS NO.460-12-8) is used in organic synthesis.This product is an unsaturated aliphatic hydrocarbons, with a simple asphyxiation and weak narcotic effect.

Diacetylene Safety Profile

A dangerous explosive. Polymerizes violently above 0°C. Arsenic pentafluoride catalyzes explosive polymerization. Reaction with silver nitrate forms a very explosive friction-sensitive product. When heated to decomposition it emits acrid smoke and fumes.Safety information of Diacetylene (CAS NO.460-12-8):
RIDADR  3161
HazardClass  2.1

Diacetylene Specification

 Diacetylene has been identified in the atmosphere of Titan and in the protoplanetary nebula CRL 618 by its characteristic vibrational modes. The molecule is most likely to have formed in Titan's atmosphere by a reaction between acetylene and the ethynyl radical C2H, which is produced when acetylene undergoes photolysis. This radical can in turn attack the triple bond in acetylene and react efficiently even at cold temperatures.
 Diacetylene, with the formula C4H2, is a highly unsaturated hydrocarbon that contains one single bond and two triple bonds. It is the first in the series of polyynes.

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