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Conditions | Yield |
---|---|
With potassium hexamethylsilazane In neat liquid at 30℃; for 2h; Schlenk technique; Inert atmosphere; chemoselective reaction; | 99% |
With chlorine[2-(4,5-dihydro-1H-imidazol-2-yl)-6-methoxypyridine](pentamethylcyclopentadienyl)iridium(III) chloride In tetrahydrofuran at 20℃; for 8h; Schlenk technique; chemoselective reaction; | 90% |
With air; hydrido(triphenylphosphine)copper(I) hexamer In benzene for 1.5h; Ambient temperature; | 76% |
Conditions | Yield |
---|---|
In benzene-d6 at 20℃; for 24h; Cooling with liquid nitrogen; Sealed tube; Inert atmosphere; | A n/a B 97% C 74% |
Conditions | Yield |
---|---|
In benzene-d6 at 20℃; for 2h; Cooling with liquid nitrogen; Sealed tube; Inert atmosphere; | 95% |
methanol
sodium methylate
diphenylsilyl dichloride
dimethoxy(diphenyl)silane
Conditions | Yield |
---|---|
In diethyl ether at 40℃; for 4h; Time; Temperature; Inert atmosphere; | 94.16% |
Conditions | Yield |
---|---|
In methanol; diethyl ether at 40℃; for 4h; Temperature; Concentration; Solvent; Inert atmosphere; | 94.16% |
Conditions | Yield |
---|---|
In diethyl ether at 40℃; for 3.5h; Inert atmosphere; | 78.3% |
tetrabutyl phosphonium bromide
diphenylsilyl dichloride
dimethoxy(diphenyl)silane
Conditions | Yield |
---|---|
In sulfolane | 78% |
tetramethylorthosilicate
[diphenylmanganese]
A
phenyl trimethylsiloxane
B
dimethoxy(diphenyl)silane
Conditions | Yield |
---|---|
In toluene at 80℃; for 2h; Inert atmosphere; Schlenk technique; | A 12% B 77% |
tetramethylorthosilicate
A
phenyl trimethylsiloxane
B
dimethoxy(diphenyl)silane
Conditions | Yield |
---|---|
In toluene at 80℃; for 2h; Inert atmosphere; Schlenk technique; | A 12% B 77% |
Conditions | Yield |
---|---|
Stage #1: methanol; benzene With pyridine; tetrachlorosilane for 0.333333h; cooling; Stage #2: at 70 - 80℃; for 5h; | 71% |
The Benzene,1,1'-(dimethoxysilylene)bis-, with the CAS registry number 6843-66-9, has the IUPAC name of dimethoxy(diphenyl)silane. For being a kind of colorless clear liquid, it is sensitive to moisture, with the product categories including Dialkoxysilanes; Functional Materials; Si (Classes of Silicon Compounds); Silane Coupling Agents; Silane Coupling Agents (Intermediates); Si-O Compounds; Phenyl Silanes. As to its usage, it is usually applied in the propylene polymerization reaction.
The characteristics of this chemical are as follows: (1)ACD/LogP: 3.86; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 3.86; (4)ACD/LogD (pH 7.4): 3.86; (5)ACD/BCF (pH 5.5): 502.98; (6)ACD/BCF (pH 7.4): 502.98; (7)ACD/KOC (pH 5.5): 2987.93; (8)ACD/KOC (pH 7.4): 2987.93; (9)#H bond acceptors: 2; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 4; (12)Polar Surface Area: 18.46; (13)Index of Refraction: 1.543; (14)Molar Refractivity: 72.95 cm3; (15)Molar Volume: 231.3 cm3; (16)Polarizability: 28.92 ×10-24 cm3; (17)Surface Tension: 33.8 dyne/cm; (18)Density: 1.05 g/cm3; (19)Flash Point: 159.1 °C; (20)Enthalpy of Vaporization: 50.46 kJ/mol; (21)Boiling Point: 286.6 °C at 760 mmHg; (22)Vapour Pressure: 0.00451 mmHg at 25°C; (23)Exact Mass: 244.091956; (24)MonoIsotopic Mass: 244.091956; (25)Topological Polar Surface Area: 18.5; (26)Heavy Atom Count: 17; (27)Complexity: 196; (28)Covalently-Bonded Unit Count: 1.
When you are dealing with this chemical, you should be cautious. This is a irritating to skin and may cause inflammation to the skin or other mucous membranes, so you should wear suitable gloves. After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer).
In addition, you could convert the following datas into the molecular structure:
(1)Canonical SMILES: CO[Si](C1=CC=CC=C1)(C2=CC=CC=C2)OC
(2)InChI: InChI=1S/C14H16O2Si/c1-15-17(16-2,13-9-5-3-6-10-13)14-11-7-4-8-12-14/h3-12H,1-2H3
(3)InChIKey: AHUXYBVKTIBBJW-UHFFFAOYSA-N
Below are the toxicity information of this chemical:
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
rat | LC | inhalation | > 42mg/m3/4H (42mg/m3) | National Technical Information Service. Vol. OTS0539962, |