CAS No.75-31-0,Isopropylamine Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	75-31-0
Name:	Isopropylamine
Article Data:	211

Formula:	C₃H₉N
Molecular Weight:	59.1112
Synonyms:	2-Propanamine;1-Methylethylamine;2-Aminopropane;2-Isopropylamine;2-Propylamine;Monoisopropylamine;NSC 62775;Propan-2-ylamine;sec-Propylamine;
EINECS:	200-860-9
Density:	0.719 g/cm³
Melting Point:	-101 °C
Boiling Point:	30.9 °C at 760 mmHg
Flash Point:	?26°F
Solubility:	soluble in water
Appearance:	colourless liquid
Hazard Symbols:	F+,Xi
Risk Codes:	12-36/37/38
Safety:	16-26-29
Transport Information:	UN 1221 3/PG 1
PSA:	26.02000
LogP:	1.05380

Synthetic route

: 79-46-9
2-nitropropane

: 75-31-0
isopropylamine

Conditions

Conditions	Yield
With hydrogen In methanol; water at 140℃; under 30003 Torr; for 24h; Sealed tube; Autoclave;	97%
With [Zn(BH4)2(py)] In tetrahydrofuran for 0.8h; Heating;	94%
With poly(p-aminostyrene)-palladium(II); hydrogen In N,N-dimethyl-formamide at 70℃; under 760 Torr; for 6h;	91%

: 67-56-1
methanol

: Cp*Mo(CO)2(κ2-N,Si-iPrHNSiPh2)

A: Cp*(CO)2Mo(μ-OMe)(μ-H)Mo(CO)2Cp*

B: 6843-66-9
dimethoxy(diphenyl)silane

C: 75-31-0
isopropylamine

Conditions

Conditions	Yield
In benzene-d6 at 20℃; for 24h; Cooling with liquid nitrogen; Sealed tube; Inert atmosphere;	A n/a B 97% C 74%

...Expand

: 67-64-1
acetone

: 75-31-0
isopropylamine

Conditions

Conditions	Yield
With ammonia; hydrogen at 153℃; under 760.051 Torr; Reagent/catalyst;	90.69%
With ammonia; nickel at 100℃; under 36775.4 - 55163.1 Torr; Hydrogenation;
With platinum on silica; ammonia at 240℃; Hydrogenation;

: 79-46-9
2-nitropropane

A: 75-31-0
isopropylamine

B: 5080-22-8
N-isopropylhydroxyamine

Conditions

Conditions	Yield
With hydrogen In para-xylene; isopropyl alcohol at 25℃; under 760.051 Torr; for 4h;	A 9% B 88%

: 4128-37-4
1,3-diisopropylurea

: 18522-92-4
sodium p-toluenesulfonamide

A: 5673-38-1
N-(isopropylcarbamoyl)-4-methylbenzenesulfonamide

B: 75-31-0
isopropylamine

Conditions

Conditions	Yield
at 170℃; for 5h; Product distribution; other time;;	A 78.2% B n/a
at 170℃; for 5h;	A 78.2% B n/a

...Expand

: 127-06-0
acetone oxime

: 75-31-0
isopropylamine

Conditions

Conditions	Yield
With ammonium formate; zinc In methanol for 0.05h; Heating;	70%
With nickel Hydrogenation.unter verschiedenen Bedingungen;
With aluminium amalgam

: 10475-45-3
bis(isopropylamino)phenylborane

A: (C6H5)BN(C3H7)

B: 75-31-0
isopropylamine

Conditions

Conditions	Yield
	A n/a B 65%
	A n/a B 65%

: 67-63-0
isopropyl alcohol

A: 75-31-0
isopropylamine

B: 108-18-9
diisopropylamine

C: 67-64-1
acetone

Conditions

Conditions	Yield
With ammonia; hydrogen at 160℃; under 760.051 Torr; for 0.5h; Catalytic behavior; Reagent/catalyst; Flow reactor; Inert atmosphere;	A 59.9% B n/a C n/a
With nitrogen; ammonia; hydrogen at 170℃; Concentration; Time; Reagent/catalyst;

...Expand

: 63465-11-2
Bis-(trifluormethyl)-bis-(trifluormethoxy)-sulfuran

: 75-04-7
ethylamine

A: 353-50-4
Carbonyl fluoride

B: 65756-36-7
hydrogen fluoride ethylamine

C: 75-31-0
isopropylamine

Conditions

Conditions	Yield
-78°C, 0.5 h;	A n/a B n/a C 56%

...Expand

: 67-56-1
methanol

: Cp*Mo(CO)2(κ2-N,Si-iPrHNSiPh2)

A: methoxydiphenyl(isopropyl-amino)silane

B: Cp*(CO)2Mo(μ-OMe)(μ-H)Mo(CO)2Cp*

C: 6843-66-9
dimethoxy(diphenyl)silane

D: 75-31-0
isopropylamine

Conditions

Conditions	Yield
In benzene-d6 at 20℃; for 4h; Cooling with liquid nitrogen; Sealed tube; Inert atmosphere;	A 11% B 34% C 36% D 48%

...Expand

Raw Materials

107-10-8

996-30-5

62-57-7

765-30-0

Downstream Products

108-18-9

395-01-7

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Chemistry

Structure of Isopropylamine (CAS NO.75-31-0):

IUPAC Name: propan-2-amine
Empirical Formula: C₃H₉N
Molecular Weight: 59.1103
Index of Refraction: 1.389
Molar Refractivity: 19.44 cm³
Molar Volume: 82.1 cm³
Polarizability: 7.7×10^-24cm³
Surface Tension: 22 dyne/cm
Density: 0.719 g/cm³
Enthalpy of Vaporization: 27.83 kJ/mol
Melting Point: -101 °C
Boiling Point: 30.9 °C at 760 mmHg
Vapour Pressure: 608 mmHg at 25°C
storage temp: 2-8°C
Water Solubility: soluble
Sensitive: Air Sensitive
Physical Appearance: colourless liquid
Stability: Stable. Extremely flammable - note low boiling point and low flash point. Readily forms explosive mixtures with air. Incompatible with strong oxidizing agents, acids, acid chlorides, acid anhydrides, perchloryl fluoride.

Uses

Isopropylamine (CAS NO.75-31-0) is an organic compound, an amine.The main uses of isopropylamine are as the salt component to Glyphosate acid for weed prevention .

Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
guinea pig	LD50	oral	2700mg/kg (2700mg/kg)		Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 45(3), Pg. 79, 1980.
mammal (species unspecified)	LC50	inhalation	1800mg/m3 (1800mg/m3)		Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. Vol. 14, Pg. 80, 1975.
mammal (species unspecified)	LD50	unreported	500mg/kg (500mg/kg)		Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. Vol. 14, Pg. 80, 1975.
mouse	LCLo	inhalation	7000ppm/40M (7000ppm)		Shell Chemical Company. Unpublished Report. Vol. -, Pg. 7, 1961.
mouse	LD50	oral	2200mg/kg (2200mg/kg)		Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 45(3), Pg. 79, 1980.
rabbit	LD50	oral	3200mg/kg (3200mg/kg)	GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA" SKIN AND APPENDAGES (SKIN): HAIR: OTHER	Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 45(3), Pg. 79, 1980.
rabbit	LD50	skin	380mg/kg (380mg/kg)		Interagency Collaborative Group on Environmental Carcinogenesis, National Cancer Institute, Memorandum, June 17, 1974Vol. 17JUN1974,
rat	LC50	inhalation	4000ppm/4H (4000ppm)		Interagency Collaborative Group on Environmental Carcinogenesis, National Cancer Institute, Memorandum, June 17, 1974Vol. 17JUN1974,
rat	LD50	oral	111mg/kg (111mg/kg)	BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) LUNGS, THORAX, OR RESPIRATION: DYSPNEA GASTROINTESTINAL: OTHER CHANGES	National Technical Information Service. Vol. OTS0542011,
rat	LDLo	intraperitoneal	50mg/kg (50mg/kg)		Farmakologiya i Toksikologiya Vol. 31, Pg. 238, 1968.

Consensus Reports

Isopropylamine (CAS NO.75-31-0) can be obtained by aminating isopropyl alcohol with ammonia in presence of a nickel/copper or similar catalyst:

(CH₃)₂CHOH + NH₃ → (CH₃)₂CHNH₂ + H₂O

Safety Profile

Hazard Codes: Highly F+, Irritant Xi
Risk Statements: 12-36/37/38
R12:Extremely flammable.
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 16-26-29
S16:Keep away from sources of ignition.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S29:Do not empty into drains.
RIDADR: UN 1221 3/PG 1
WGK Germany: 1
RTECS: NT8400000
F: 34
HazardClass: 3
PackingGroup: I

Specification

Isopropylamine , its cas register number is 75-31-0. It also can be called 1-Methylethylamine ; 2-Amino-propaan ; 2-Amino-propano ; 2-Aminopropan ; 2-Aminopropane ; Isopropilamina ; Isopropylamine ; Monoisopropylamine ; Propanal, 2-amino- ; Propane, 2-amino- ; sec-Propylamine .