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Conditions | Yield |
---|---|
With potassium carbonate In acetone at 20℃; for 3h; | 99% |
With potassium carbonate In acetone at 20℃; for 3h; | 99% |
Stage #1: phenol With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 0.5h; Stage #2: ethyl bromoacetate In N,N-dimethyl-formamide at 60℃; for 3h; | 94% |
methyl phenyl carbonate
tetrabutyl phosphonium bromide
chloroacetic acid ethyl ester
phenoxyacetic acid ethyl ester
Conditions | Yield |
---|---|
96% |
Conditions | Yield |
---|---|
With cesium fluoride In acetonitrile for 1.5h; Heating; | 94% |
Conditions | Yield |
---|---|
With sulfuric acid for 14h; Reflux; | 92% |
sulfuric acid; silica gel In diethyl ether for 0.333333h; Heating; | 88% |
With tris(2-methoxyphenyl)bismuthine In benzene for 12h; Heating; | 75% |
Conditions | Yield |
---|---|
With copper(I) trifluoromethanesulfonate benzene; 6-[(R)-1-(1-naphthyl)ethyl]-3,9-ditosyl-3,6,9,15-tetraazabicyclo[9,3,1]pentadeca-1(15),11,13-triene In 1,2-dichloro-ethane at 20℃; for 18h; Inert atmosphere; Schlenk technique; | 90% |
methyltrioxorhenium(VII) In benzene for 48h; Ambient temperature; | 87% |
With [(Zr6(μ3-O)8(OH)2(H2O)10)2(Ir(tetrakis(4-carboxyphenyl)porphyrin)Cl)3]*8(C6H5COOH)*4DMF In dichloromethane at 20℃; for 0.166667h; Catalytic behavior; | 56% |
Conditions | Yield |
---|---|
With potassium carbonate In acetonitrile | 88.7% |
With potassium carbonate In acetone for 10h; Reflux; | 80% |
With potassium carbonate In acetone Reflux; | 80% |
Conditions | Yield |
---|---|
With N,N-dimethyl-formamide dimethyl acetal at 45℃; for 3h; | 85% |
Conditions | Yield |
---|---|
With 1,3-diazido-propane In neat (no solvent) at 20℃; for 0.333333h; | 77% |
triphenyl phosphite
4-chlorobenzaldehyde
ethyl bromoacetate
A
phenoxyacetic acid ethyl ester
B
ethyl (E)-3-(4-chlorophenyl)prop-2-enoate
Conditions | Yield |
---|---|
With 18-crown-6 ether; dibutyl telluride; potassium carbonate In toluene at 80℃; | A 69% B 68 % Chromat. |
Conditions | Yield |
---|---|
With potassium carbonate In acetone for 16h; Reflux; | 67% |
Molecular Formula: C10H12O3
Molar mass: 180.2 g/mol
EINECS: 219-867-3
Density: 1.082 g/cm3
Flash Point: 97.4 °C
Index of Refraction: 1.495
Boiling Point: 248.2 °C at 760 mmHg
Vapour Pressure: 0.0246 mmHg at 25°C
Appearance: Clear yellow liquid
Product categories: Carbonyl Compounds;Miscellaneous;Esters
Structure of Ethyl phenoxyacetate (2555-49-9):
XLogP3-AA: 1.8
H-Bond Donor: 0
H-Bond Acceptor: 3
Systematic Name: Ethyl 2-phenoxyacetate
SMILES: O=C(OCC)COc1ccccc1
InChI: InChI=1/C10H12O3/c1-2-12-10(11)8-13-9-6-4-3-5-7-9/h3-7H,2,8H2,1H3
InChIKey: MGZFVSUXQXCEHM-UHFFFAOYAX
Std. InChI: InChI=1S/C10H12O3/c1-2-12-10(11)8-13-9-6-4-3-5-7-9/h3-7H,2,8H2,1H3
Std. InChIKey: MGZFVSUXQXCEHM-UHFFFAOYSA-N
Carcinogenicity of Ethyl phenoxyacetate (2555-49-9) hasn't been listed as a carcinogen by NTP, IARC,ACGIH, or CA Prop 65. And its toxicological properties have not been fully investigated.
Safety Statements:
24: Avoid contact with skin
25: Avoid contact with eyes
Ethyl phenoxyacetate (2555-49-9) also can be called Acetic acid, phenoxy-, ethyl ester ; Phenoxyacetic acid ethyl ester .It is hazardous,so the first aid measures and others should be known.Such as: When on the skin: first,should flush skin with plenty of water immediatelyfor at least 15 minutes while removing contaminated clothing. Secondly,Get shoesmedical aid . Or in the eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids.Then get medical aid soon.While ,it's Inhaled: Remove from exposure and move to fresh air immediately.Give artificial respiration while not breathing. When breathing is difficult, give oxygen. And as soon as to get medical aid. Then you have the ingesting of the product : Wash mouth out with water,and get medical aid immediately.
In addition, Ethyl phenoxyacetate (2555-49-9) can be stable under normal temperature and pressure conditions.It is not compatible with strong oxidizing agents, strong bases, and you must not take it incompatible materials.And also prevent it to broken down into hazardous decomposition products: carbon dioxide, carbon monoxide.