CAS No.75-03-6,Ethyl iodide Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	75-03-6
Name:	Ethyl iodide
Article Data:	308

Formula:	C₂H₅I
Molecular Weight:	155.966
Synonyms:	AI3-28593;Ethyl iodide;Ethyljodid;Hydriodic ether;Jodethan;Monoiodoethane;NSC 8825;
EINECS:	200-833-1
Density:	1.94 g/cm³
Melting Point:	-108 °C
Boiling Point:	72.8 °C at 760 mmHg
Flash Point:	21.1 °C
Solubility:	4 g/L in water at 20 °C
Appearance:	Colorless to yellow liquid
Hazard Symbols:	Xn,T
Risk Codes:	20-36/37/38-42/43-10-23/24/25
Safety:	23-26-45-16-36/37/39-27
PSA:	0.00000
LogP:	1.44130

Synthetic route

: [CoEt(dimethylglyoximate(1-))2(pyridine)]

: 7553-56-2
iodine

A: iodobisdimethylglyoximepyridine cobalt(III)

B: 75-03-6
ethyl iodide

Conditions

Conditions	Yield
In tetrachloromethane Kinetics; Irradiation (UV/VIS); Kinetics of the reaction of Co(C2H5)(H3CCNOHONCCH3)2(C5H5N) with I2 under irradiation with light at 517 nm is investigated.; MeI and CoI(H3CCNOHONCCH3)2(C5H5N) are the products.;	A n/a B 100%

...Expand

: [CoEt(dimethylglyoximate(1-))2(pyridine)]

: 75-03-6
ethyl iodide

Conditions

Conditions	Yield
With iodine In acetonitrile Kinetics; byproducts: {Co(bis(dimethylglyoximato))py(I)}; one-electron oxidn. of Co complex by I2 at 298 K; monitored by (1)H-NMR and UV spect. (361 nm);	100%

: ethyl 4-(diethoxyphosphorylmethyl)-5-(iodomethyl)furan-3-carboxylate

: 122-52-1
triethyl phosphite

A: 78-38-6
ethylphosphonic acid diethyl ester

B: ethyl 4,5-bis-(diethoxyphosphorylmethyl)furan-3-carboxylate

C: 75-03-6
ethyl iodide

Conditions

Conditions	Yield
at 90 - 170℃; for 0.166667h; Arbuzov Reaction;	A n/a B 98% C n/a

...Expand

: 122-52-1
triethyl phosphite

: 74-88-4
methyl iodide

A: 683-08-9
Diethyl methylphosphonate

B: 75-03-6
ethyl iodide

Conditions

Conditions	Yield
at 130℃; for 0.0833333h; Michaelis-Arbuzov reaction; microwave irradiation;	A 97% B n/a

...Expand

: cis-{(C2H5)2Co(2,2'-bipyridine)2}(ClO4)

A: 74-84-0
ethane

B: 74-85-1
ethene

C: 75-03-6
ethyl iodide

D: 106-97-8
n-butane

Conditions

Conditions	Yield
With iodine In acetonitrile Kinetics; byproducts: I3(1-), {(C2H5)Co(2,2'-bipyridine)2I}(1+); one-electron oxidn. of cis-Co complex by I2 at 298 K; monitored by (1)H-NMR and UV spect. (361 nm);	A <1 B <1 C 97% D 3.2%

...Expand

: 107-25-5
methoxyethene

: 107-19-7
propargyl alcohol

A: 38987-67-6
3-(1-methoxy-ethoxy)-propyne

B: 75-03-6
ethyl iodide

Conditions

Conditions	Yield
With toluene-4-sulfonic acid	A 96% B n/a

...Expand

: 591-50-4
iodobenzene

: 122-52-1
triethyl phosphite

A: 1754-49-0
diethyl phenylphosphonate

B: 75-03-6
ethyl iodide

Conditions

Conditions	Yield
tetrakis(triethylphosphite)nickel(0) at 160℃;	A 94% B n/a
at 160℃; Mechanism; var. catalysts, var. temp.;

...Expand

: 20502-50-5
diethyl phosphoriodidite

: 7020-81-7
N-(propylidene)-tert-butylamine

A: 75-03-6
ethyl iodide

B: 1,4-di-tert-butyl-2-ethoxy-3,5-diethyl-1,4,2-diazaphospholidine 2-oxide

Conditions

Conditions	Yield
In diethyl ether for 2h; Ambient temperature;	A n/a B 92%

...Expand

: 16029-98-4
trimethylsilyl iodide

: 141-78-6
ethyl acetate

A: 2754-27-0
trimethylsilyl acetate

B: 75-03-6
ethyl iodide

Conditions

Conditions	Yield
at 100℃; for 0.5h; Mechanism; Product distribution;	A n/a B 92%

...Expand

: 45817-37-6
4-vinylbenzyl iodide

: 122-52-1
triethyl phosphite

A: 726-61-4
[(4-ethenylphenyl)methyl]phosphonic acid diethyl ester

B: 75-03-6
ethyl iodide

Conditions

Conditions	Yield
at 20℃; for 6h;	A 91% B n/a

...Expand

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Consensus Reports

Reported in EPA TSCA Inventory.

Specification

The Ethane, iodo-, with the CAS registry number 75-03-6, is also known as Monoiodoethane. Its EINECS number is 200-833-1. This chemical's molecular formula is C₂H₅I and molecular weight is 155.97. What's more, its systematic name is iodoethane. Its classification code is Mutation data. Ethyl iodide is very good with alkylation reactions. It is used as organic reagents and pharmaceutical intermediates. It is also used as the hydrogen radical promoter. It should be sealed and stored in a cool, ventilated and dry place. Moreover, it should be protected from light, heat and fire.

Physical properties of Ethane, iodo- are: (1)ACD/LogP: 2.03; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 2.03; (4)ACD/LogD (pH 7.4): 2.03; (5)ACD/BCF (pH 5.5): 20.48; (6)ACD/BCF (pH 7.4): 20.48; (7)ACD/KOC (pH 5.5): 302.23; (8)ACD/KOC (pH 7.4): 302.23; (9)Index of Refraction: 1.516; (10)Molar Refractivity: 24.28 cm³; (11)Molar Volume: 80.3 cm³; (12)Polarizability: 9.62×10^-24cm³; (13)Surface Tension: 28.5 dyne/cm; (14)Density: 1.94 g/cm³; (15)Flash Point: 21.1 °C; (16)Enthalpy of Vaporization: 29.44 kJ/mol; (17)Boiling Point: 72.8 °C at 760 mmHg; (18)Vapour Pressure: 128 mmHg at 25°C.

Preparation: this chemical can be prepared by ethanol and PI₃ by heating and reflux.

2P + 3I₂→ 2PI₃

3C₂H₅OH + PI₃ →3CH₃CH₂I + H₃PO₄

Uses of Ethane, iodo-: it can be used to produce 1-ethyl-3-nitro-2-phenyl-indole by heating. It will need reagent Na and solvent ethanol with the reaction time of 2 hours. The yield is about 59%.

Ethane, iodo- can be used to produce 1-ethyl-3-nitro-2-phenyl-indole by heating

When you are using this chemical, please be cautious about it as the following:
This chemical is flammable, so you should keep it away from sources of ignition - No smoking. It is harmful by inhalation. It is toxic by inhalation, in contact with skin and if swallowed. It is irritating to eyes, respiratory system and skin. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. You must not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer). You should take off immediately all contaminated clothing. When using it, you need wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, you must seek medical advice immediately (show the label where possible).

You can still convert the following datas into molecular structure:
(1)InChI: InChI=1S/C2H5I/c1-2-3/h2H2,1H3
(2)InChIKey: HVTICUPFWKNHNG-UHFFFAOYSA-N
(3)Canonical SMILES: CCI

The toxicity data is as follows:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
guinea pig	LD50	intraperitoneal	322mg/kg (322mg/kg)		"Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 68, 1982.
mouse	LD50	intraperitoneal	560mg/kg (560mg/kg)		"Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 68, 1982.
mouse	LD50	subcutaneous	1gm/kg (1000mg/kg)	PERIPHERAL NERVE AND SENSATION: FLACCID PARALYSIS WITHOUT ANESTHESIA (USUALLY NEUROMUSCULAR BLOCKAGE) LUNGS, THORAX, OR RESPIRATION: RESPIRATORY STIMULATION LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES	Japanese Journal of Pharmacology. Vol. 3, Pg. 99, 1954.
rabbit	LDLo	oral	300mg/kg (300mg/kg)		"Patty's Industrial Hygiene and Toxicology," 3rd rev. ed., Clayton, G.D., and F.E. Clayton, eds., New York, John Wiley & Sons, Inc., 1978-82. Vol. 3 originally pub. in 1979; pub. as 2n rev. ed. in 1985.Vol. 2B, Pg. 3487, 1981.
rat	LC50	inhalation	65gm/m³/30M (65000mg/m³)		Fiziologicheski Aktivnye Veshchestva. Physiologically Active Substances. Vol. 7, Pg. 35, 1975.
rat	LD50	intraperitoneal	330mg/kg (330mg/kg)		"Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 68, 1982.