Mn-salen catalyzed asymmetric epoxidation of (±)-3-alkylindene: Reagent-dependent stereoselectivity

DOI: 10.1016/0040-4039(96)00896-9

Source and publish data:

Tetrahedron Letters p. 4533 - 4536 (1996)

Update date:2022-08-04

Topics:

Authors:

Noguchi, Yukiko

Irie, Ryo

Fukuda, Tsutomu

Katsuki, Tsutomu

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Article abstract of DOI:10.1016/0040-4039(96)00896-9

Epoxidation of (±)-3-alkylindenes was examined with various (salen)manganese(III) complexes as catalysts and, from the analysis of the obtained data, it was found that the location and nature of C3- and C3'- substituents of the Mn-catalysts strongly influenced the stereochemistry of the epoxidation.

Full text of DOI:10.1016/0040-4039(96)00896-9

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