HYDROBORATION D'AMINES INSATUREES. IX. ROLE D'UNE LIAISON PIV-N SUR LA COMPLEXATION AZOTE-BORE LORS DE LA REACTION D'HYDROBORATION D'AMINES N-ALLYLIQUES

Article abstract of DOI:10.1016/0022-328X(85)87408-8

The amino group of N-allylic amines which is protected by a phosphorylated grouping hinders nitrogen-boron coordination and allows normal addition of the boron hydrides.The hydroboration-oxidation reaction of phosphorated N-allylic amines, by appropriate hydroboration agents, lead to N-phosphorated 3-aminopropanols with very good yields.