Chemistry Letters p. 1351 - 1354 (1983)
Update date:2022-08-02
Topics:
Takikawa, Yuji
Shimada, Kazuaki
Matsumoto, Hisaya
Nucleophilic attack of thiols on phenylacetylene (1) in liquid ammonia at room temperature gave the corresponding Z-isomer of styryl sulfides in high yield stereoselectively.Reaction of 1 with Na2S also proceeded selectively to give Z,Z-distyryl sulfide (12).On the other hand, reaction with NaSH gave 12 besides E,Z-isomer as a minor product.
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