Tetrahedron Letters p. 5081 - 5084 (1985)
Update date:2022-09-26
Topics:
Busfield, Ken W.
Jenkins, Ian D.
Thang, San H.
Rizzardo, Ezio
Solomon, David H.
95 percent of the reaction of t-butoxy radicals with norbornadiene occurs by radical addition followed by rearrangement to nortricyclyl and 7-t-butoxynorbornenyl products; the remainder includes a novel radical rearragement involving a 1,3-H shift and some radical abstraction observed for the first time.
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