Bulletin of the Chemical Society of Japan p. 322 - 329 (1995)
Update date:2022-08-05
Topics:
Kohno, Yasushi
Narasaka, Koichi
The oxidation of α-tributylstannyl alkanoates with tetrabutylammonium hexanitratocerate(IV) generates α-radicals of the alkanoates by eliminating the stannylium ion.The thus-formed radicals react with various electron-rich olefinic compounds, such as silyl enol ethers, giving addition products in good yield.This method formally achieves selective cross coupling between alkanoates and ketones.
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